全文获取类型
收费全文 | 19392篇 |
免费 | 3307篇 |
国内免费 | 3520篇 |
专业分类
化学 | 15515篇 |
晶体学 | 346篇 |
力学 | 1102篇 |
综合类 | 249篇 |
数学 | 2117篇 |
物理学 | 6890篇 |
出版年
2024年 | 30篇 |
2023年 | 414篇 |
2022年 | 597篇 |
2021年 | 741篇 |
2020年 | 895篇 |
2019年 | 945篇 |
2018年 | 799篇 |
2017年 | 781篇 |
2016年 | 978篇 |
2015年 | 981篇 |
2014年 | 1208篇 |
2013年 | 1534篇 |
2012年 | 1724篇 |
2011年 | 1795篇 |
2010年 | 1364篇 |
2009年 | 1265篇 |
2008年 | 1393篇 |
2007年 | 1147篇 |
2006年 | 1080篇 |
2005年 | 1001篇 |
2004年 | 813篇 |
2003年 | 688篇 |
2002年 | 681篇 |
2001年 | 631篇 |
2000年 | 433篇 |
1999年 | 379篇 |
1998年 | 278篇 |
1997年 | 219篇 |
1996年 | 242篇 |
1995年 | 200篇 |
1994年 | 190篇 |
1993年 | 161篇 |
1992年 | 126篇 |
1991年 | 128篇 |
1990年 | 84篇 |
1989年 | 65篇 |
1988年 | 50篇 |
1987年 | 47篇 |
1986年 | 33篇 |
1985年 | 38篇 |
1984年 | 15篇 |
1983年 | 16篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1971年 | 1篇 |
1959年 | 4篇 |
1957年 | 4篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Xin Liu Lili Chen Yanfeng Zhao Xianhua Song 《Mathematical Methods in the Applied Sciences》2022,45(1):77-92
In this paper, the problem of the uniform stability for a class of fuzzy fractional-order genetic regulatory networks with random discrete delays, distributed delays, and parameter uncertainties is studied. Although there is a portion of literature on using fixed point theorems to study the stability of fractional neural networks, most of them required the fractional order to be in . However, the case of the fractional-order belonging to has not been discussed. To solve it, this work proposes a novel idea of using fixed point theory to study the stability of fuzzy (0,1) order neural networks, the problem of the uniqueness of the solution of the considered genetic regulatory networks is resolved, and a novel sufficient condition to guarantee the uniform stability of above genetic regulatory networks is also derived. Eventually, an example is given to demonstrate that the obtained result is effective. 相似文献
2.
3.
Photocatalytic CO2 reduction to C1 fuels is considered to be an important way for alleviating increasingly serious energy crisis and environmental pollution. Due to the environment-friendly, simple preparation, easy formation of highly-stable metal-nitrogen(M-Nx) coordination bonds, and suitable band structure, polymeric carbon nitride-based single-atom catalysts(C3N4-based SACs) are expected to become a potential for CO2 reduction under visible-light irradiation. In this review, we summarize the recent advancement on C3N4-based SACs for photocatalytic CO2 reduction to C1 products, including the reaction mechanism for photocatalytic CO2 reduction to C1 products, the structure and synthesis methods of C3N4-based SACs and their applications toward photocatalytic CO2 reduction reaction(CO2RR) for C1 production. The current challenges and future opportunities of C3N4-based SACs for photoreduction of CO2 are also discussed. 相似文献
4.
Jiang Rui-Yang Xin Jia-Wei Cao Cong 《International Journal of Theoretical Physics》2021,60(8):2836-2855
International Journal of Theoretical Physics - Quantum logic gates are the foundation of circuit-based quantum computation and quantum simulation. Multi-qubit quantum controlled gates are of vital... 相似文献
5.
6.
Molecular Diversity - Epidermal growth factor receptor (EGFR) has received widespread attention because it is an important target for anticancer drug design. Mutations in the EGFR, especially the... 相似文献
7.
Yuan Xin Zhang Shuren Zhong Xuanmeng Yuan Hao Song Dongfan Wang Xiaoyu Yu Hanyang Guo Zijian 《中国科学:化学(英文版)》2022,65(10):1978-1984
Science China Chemistry - Oncogenic KRAS reprograms pancreatic ductal adenocarcinoma (PDAC) cells to a state that is awfully resistant to apoptosis. An alternative coping strategy is to trigger a... 相似文献
8.
Dr. Zhe Zhang Dr. Xiaofeng Fang Dr. Zhihe Liu Dr. Haichao Liu Dr. Dandan Chen Prof. Shuqing He Prof. Jie Zheng Prof. Bing Yang Prof. Weiping Qin Prof. Xuanjun Zhang Prof. Changfeng Wu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(9):3720-3727
Fluorescence probes in the NIR-IIa region show drastically improved imaging owing to the reduced photon scattering and autofluorescence in biological tissues. Now, NIR-IIa polymer dots (Pdots) are developed with a dual fluorescence enhancement mechanism. First, the aggregation induced emission of phenothiazine was used to reduce the nonradiative decay pathways of the polymers in condensed states. Second, fluorescence quenching was minimized by different levels of steric hindrance to further boost the fluorescence. The resulting Pdots displayed a fluorescence QY of ca. 1.7 % in aqueous solution, suggesting an enhancement of ca. 21 times in comparison with the original polymer in tetrahydrofuran (THF) solution. Small-animal imaging by using the NIR-IIa Pdots exhibited a remarkable improvement in penetration depth and signal to background ratio, as confirmed by through-skull and through-scalp fluorescent imaging of the cerebral vasculature of live mice. 相似文献
9.
Qi-Jun Li Ya-Jie Ren Qin Xie Min Wu Hua-Xing Feng Li-Mei Zheng Hua-Xin Zhang Jin-Qiao Long Tian-Shun Wang 《应用有机金属化学》2020,34(10):e5813
Two nickel complexes, [Ni(tpen)](ClO4)2.0.5CH3COCH3 ( 1 ) and [Ni(tpbn)](ClO4)2 ( 2 ), of tetrapyridyl ligands N,N,N′,N′-tetrakis(2-pyridyl-methyl)-1,2-ethanediamine (tpen) and N,N,N′,N′-tetrakis(2-pyridyl-methyl)-1,4-butanediamine (tpbn) were prepared and their catalysis for water oxidation reaction (WOR) studied. In 0.1 M phosphate buffer solution (PBS) of pH 8.0, complex 1 is a homogeneous molecular catalyst with an overpotential of ~440 mV and a Faradaic efficiency of 89%. At pH ≥ 9.0, complex 1 degraded gradually during the catalytic process and formed NiOx composite (nickel oxide with general formula NixOyHz) active for WOR. In contrast, complex 2 deteriorated under measured conditions (pH 8.0–12.0) and formed NiOx composite active for WOR. The NiOx composite derived from 1 in 0.1 M PBS at pH 11.0 showed an activity with an overpotential of ~500 mV, a Tafel slope of ~90 mV/decade and a Faradaic efficiency of 97%. Mechanisms were proposed for water oxidation catalyzed by 1 and 2 . This work revealed that the catalytic activity of the nickel complexes was related to the flexibility of the tetrapyridyl ligands and the adaptability of the coordination sphere of the nickel(II) center. 相似文献
10.
You Qin Rongrong Zhou Jian Jin Jing Xie Hao Liu Ping Cai Jun Shu Yahui Zhao Luqi Huang Shuihan Zhang 《Biomedical chromatography : BMC》2020,34(8):e4841
Ophiocordyceps xuefengensis (O. xuefengensis), a new species of caterpillar fungus, has been identified as the sister taxon of Ophiocordyceps sinensis (O. sinensis). The aims of the present study are to evaluate the anticancer activity and to qualitatively analyze the potential bioactive chemical constituents of O. xuefengensis and O. sinensis, comparatively. An MTT assay was used to evaluate the in vitro anticancer activities of different fractions from O. xuefengensis and O. sinensis. The results show that ethyl acetate fractions of O. xuefengensis and O. sinensis have significant in vitro anticancer activity. These two bioactive fractions were analyzed by ultra-performance liquid chromatography–electrospray ionization with quadrupole–time of flight tandem mass spectrometry technology. A total of 82 compounds and 101 compounds were identified or tentatively characterized in the bioactive fractions of O. xuefengensis and O. sinensis, respectively. Among these compounds, 68 existed in both O. xuefengensis and O. sinensis. A total of 67 compounds were reported in O. xuefengensis and 8 compounds were reported in caterpillar fungus for the first time. This is the first detailed comparative analysis of the in vitro anticancer activity and chemical ingredients between O. xuefengensis and O. sinensis. The application of this work will provide reliable fundamental pharmacological substances for the use of O. xuefengensis by Yao people. 相似文献