Synthesis of a Tweezer—like Bis（Phenylthiapropoxy）calix[4]—arene as a Cation／π Enhanced Sensor for Ion—Selective Electrodes

Two novel 25,27-dihydroxy-26,28-bis(3-phenylthiapropxy)-calix[4]arene(3) and 25,27-dihydroxy-26,28-bis(3-phenylthiapropoxy)-5,11,17,23-tetra-tert-butylcalix[4] arene (4) were synthesized for the evaluation of their ion-selectivity in ion-selective electrodes(ISEs).ISEs based on 3 and 4 as neutral ionophores were prepared,and their selectivity coefficients for Ag^ (lg KAg,M^pot)were investigated against other alkali metal,alkaline-earth metal,aluminum,thallium(Ⅰ）,Lead and some transition metal ions using the separate solution method (SSM).These ISEs showed excellent Ag^ seletivity over most of the interfering cations examined,except for Hg^2 and Fe^2 having relative smaller interference(lg KAg,M^pot≤-2.1).     

Design of Transmission Line for Submillimeter Wave Gyrotron Using Dielectric-Lined Waveguide

The excitation and transmission losses of a dielectric-lined waveguide have been calculated with real, experimentally measured output beams of a submillimeter wave gyrotron. It is shown that for not-so-long transmission lines the coupling losses far exceed the transmission losses in the waveguide.     

高能强子–强子碰撞中喷注性质的蒙特卡洛研究

在喷注“圆锥判定法”的基础上,对高能强子–强子碰撞中产生的喷注(微喷注)的性质进行了蒙特卡洛研究.采用以喷注动量为z轴的“喷注坐标系”,给出了表征喷注性质的各物理量在新坐标系中的分布情况.结果表明,圆锥判定法能够作为一种有效手段来对高能强子–强子碰撞和相对论重离子碰撞中发生的硬和半硬过程开展实验研究.由有喷注事件和无喷注事件的多重数分布可以看到,E_t=2GeV是用圆锥法确定喷注的合理的横能截断值.     

Laser-hole boring into overdense plasmas measured with soft X-Ray laser probing

A laser self-focused channel formation into overdense plasmas was observed using a soft x-ray laser probe system with a grid image refractometry (GIR) technique. 1.053 &mgr;m laser light with a 100 ps pulse duration was focused onto a preformed plasma at an intensity of 2x10(17) W/cm (2). Cross sections of the channel were obtained which show a 30 &mgr;m diameter in overdense plasmas. The channel width in the overdense region was kept narrow as a result of self-focusing. Conically diverging density ridges were also observed along the channel, indicating a Mach cone created by a shock wave due to the supersonic propagation of the channel front.     

CW Operation of a Submillimeter Wave Gyrotron (Gyrotron Fu IV) for High Stability of the Output Frequency

The first cw operation of our submillimeter wave gyrotron (Gyrotron FU IV) using a 12 T superconducting magnet has been successfully carried out. Output power is more than 20 W at a frequency of 301 GHz in the TE₀₃₁ resonant cavity mode. Time-resolved frequency measurement s shows that the frequency fluctuation of the gyrotron output is smaller than 2 MHz. This frequency fluctuation is mainly due to the fluctuation in the output voltage of the power supply.     

Development of frequency tunable, medium power gyrotrons (GyrotronFU series) as submillimeter wave radiation sources

High frequency, medium power gyrotrons (Gyrotron FU series) have been developed at Fukui University as radiation sources covering a broad band from millimeter to submillimeter wave region. They have already been applied to high frequency electron spin resonance and to submillimeter wave scattering in plasma. Many parameters of the gyrotron series could be useful for applications in several new areas. The development and some applications of the Gyrotron FU series are summarized in this paper     

Simulation and measurement of frequency modulation insubmillimeter-wave gyrotron

Frequency modulation of the gyrotron output has been numerically simulated employing the approximation of weakly relativistic, mono-velocity electron beam as well as a quasi-empirical approach. The simulation results are compared to a first experiment in the 300 GHz region performed with a submillimeter-wave gyrotron named “Gyrotron FU IV”. The modulation amplitude of 30 MHz has been achieved by a 120 V modulation of the accelerating voltage resulting in the variation of the relativistic electron mass and in the corresponding modulation of the electron cyclotron frequency. Calculated amplitudes of frequency modulation are in reasonable agreement with the experimental results     

Mode Cooperation in a Submillimeter Wave FU Series Gyrotron

At certain gyrotron operating conditions, mode cooperation instead of mode competition takes place between a fundamental and a second harmonic mode. This means the phase bunching of a gyrating electron beam under the second harmonic operation reduces the starting current for the fundamental operation and increases total output power as well as beam efficiency. Such mode cooperation is observed in experiments and confirmed by computer simulations for submillimeter wave Gyrotron FU II.     

Curing theory of A_f-A_g type free radical polymerization (I)──Distribution function and its invariant property

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