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排序方式: 共有691条查询结果,搜索用时 15 毫秒
1.
Leila Torkian Mostafa M. Amini Tayebeh Gorji Omid Sadeghi 《Arabian Journal of Chemistry》2019,12(7):1315-1321
In this study, multiwalled carbon nanotube (MWCNT) was modified by the pyridine group using a silane agent and characterized by infrared spectroscopy (IR), thermal analysis (TG/DTA), and elemental analysis (CHN) and scanning electron microscopy (SEM). The application of this sorbent was investigated in determination of lead ions in aqueous samples, using flame atomic absorption spectrometry (FAAS). Through this study, different parameters such as pH and sample flow rate on adsorption process and eluent concentration, volume and flow rate were optimized. The limit of detection (LOD), the relative standard deviation and the recovery of the method were 2 ng mL?1, 1.3% and 99.7%, respectively. Two standard reference materials (NIST 1571 and NIST 1572) were used to verify accuracy of this method. Finally, the sorbent was successfully applied for extraction and determination of low levels of Pb(II) ions in aqueous samples. 相似文献
2.
In this paper, we study generalized Douglas–Weyl(α, β)-metrics. Suppose that a regular(α, β)-metric F is not of Randers type. We prove that F is a generalized Douglas–Weyl metric with vanishing S-curvature if and only if it is a Berwald metric. Moreover, by ignoring the regularity, if F is not a Berwald metric, then we find a family of almost regular Finsler metrics which is not Douglas nor Weyl. As its application, we show that generalized Douglas–Weyl square metric or Matsumoto metric with isotropic mean Berwald curvature are Berwald metrics. 相似文献
3.
Malekahmadi Omid Kalantar Mahdi Nouri-Khezrabad Mohsen 《Journal of Thermal Analysis and Calorimetry》2021,144(6):2109-2126
Journal of Thermal Analysis and Calorimetry - The hydroxyapatite is one of the biocompatible and insulating bioceramics, while the carbon nanotube has a high thermal conductivity potential. This... 相似文献
4.
Honglei Ling Omid T. Qazvini Shane G. Telfer Jianyong Jin 《Journal of polymer science. Part A, Polymer chemistry》2020,58(18):2619-2624
A series of metalized C-PIM-M (M = Na+, Mg2+, Al3+, PIMs = polymers of intrinsic microporosity) materials were prepared from a carboxyl-functionalized PIM (C-PIMs). The C-PIM-Na exhibited a high CO2 adsorption capacity of 2.44 mmol/g and extreme low CH4 uptake of 0.28 mmol/g at 273 K and 101 kPa among three metallated PIMs. It showed remarkably high CO2/CH4 and CO2/N2 selectivities at both 273 and 293 K due to an advantageous pore-blocking effect of Na+ cation. 相似文献
5.
Parham Dehghan Mina Noroozi Gity Mir Mohamad Sadeghi Mahbod Abrisham Arian Amirkiai Mahyar Panahi-Sarmad 《Journal of polymer science. Part A, Polymer chemistry》2020,58(21):3082-3094
The recent global pandemic and its tremendous effect on the price fluctuations of crude oil illustrates the side effects of petroleum dependency more evident than ever. Over the past decades, both academic and industrial communities spared endless efforts in order to replace petroleum-based materials with bio-derived resources. In the current study, a series of shape memory polymer composites (SMPC's) was synthesized from epoxidized vegetable oils, namely canola oil and castor oil fatty acids (COFA's) as a 100% bio-based polyol and isophorone diisocyanate (IPDI) as an isocyanate using a solvent/catalyst-free method in order to eventuate polyurethanes (PU's). Thereafter, graphene oxide (GO) nanoplatelets were synthesized and embedded in the neat PU in order to overcome the thermomechanical drawbacks of the neat matrix. The chemical structure of the synthesized components, as well as the dispersion and distribution levels of the nanoparticles, was characterized. In the following, thermal and mechanical properties as well as shape memory behavior of the specimens were comprehensively investigated. Likewise, the thermal conductivity was determined. This study proves that synthesized PU's based on vegetable oil polyols, including graphene nanoparticles, exhibit proper thermal and mechanical properties, which make them stand as a potential candidate to compete with traditional petroleum-based SMPC's. 相似文献
6.
Nelaka Govinna Ilin Sadeghi Ayse Asatekin Peggy Cebe 《Journal of Polymer Science.Polymer Physics》2019,57(6):312-322
We report the structure and thermal properties of blends comprising poly(vinylidene fluoride) (PVDF) and a random fluorinated copolymer (FCP) of poly(methyl methacrylate)‐random‐1H,1H,2H,2H‐perfluorodecyl methacrylate, promising membrane materials for oil–water separation. The roles of processing method and copolymer content on structure and properties were studied for fibrous membranes and films with varying compositions. Bead‐free, nonwoven fibrous membranes were obtained by electrospinning. Fiber diameters ranged from 0.4 to 1.9 μm, and thinner fibers were obtained for PVDF content >80%. As copolymer content increased, degree of crystallinity and onset of degradation for each blend decreased. Processing conditions have a greater impact on the crystallographic phase of PVDF than copolymer content. Fibers have polar beta phase; solution‐cast films contain gamma and beta phase; and melt crystallized films form alpha phase. Kwei's model was used to model the glass transition temperatures of the blends. Addition of FCP increases hydrophobicity of the electrospun membranes. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 312–322 相似文献
7.
Nili-Ahmadabadi Mahdi Nematollahi Omid Fatehi Mostafa Cho Dae Seung Kim Kyung Chun 《显形杂志》2020,23(4):591-603
Journal of Visualization - Airfoils are mostly inefficient in their off-design conditions. In order to improve the aerodynamic performance of airfoils in these conditions, using an optimized cavity... 相似文献
8.
Maryam S. Sadeghi Mohammad Reza Moghbeli William A. Goddard III 《Journal of polymer science. Part A, Polymer chemistry》2021,59(7):614-626
We followed the self-assembly of high-molecular weight MePEG- b -PCL (poly(methyl ethylene glycol)-block-poly(ε-caprolactone)) diblock and MePEG- b -PBO- b -PCL (poly(methyl ethylene glycol)-block-poly(1,2-butylene oxide)-block-poly(ε-caprolactone)) into micelles using molecular dynamics simulation with a coarse grain (CG) force field based on quantum mechanics (CGq FF). The triblock polymer included a short poly(1,2-butylene oxide) (PBO) at the hydrophilic-hydrophobic interface of these systems. Keeping the hydrophilic length fixed (MePEG45), we considered 250 chains in which the hydrophobic length changed from PCL44 or PBO6- b -PCL43 to PCL62 or PBO9- b -PCL61. The polymers were solvated in explicit water for 2 μs of simulations at 310.15 K. We found that the longer diblock system undergoes a morphological transition from an intermediate rod-like micelle to a prolate-sphere, while the micelle formed from the longer triblock system is a stable rod-like micelle. The two shorter diblock and triblock systems show similar self-assembly processes, both resulting in slightly prolate-spheres. The dynamics of the self-assembly is quantified in terms of chain radius of gyration, shape anisotropy, and hydration of the micelle cores. The final micelle structures are analyzed in terms of the local density components. We conclude that the CG model accurately describes the molecular mechanisms of self-assembly and the equilibrium micellar structures of hydrophilic and hydrophobic chains, including the quantity of solvent trapped inside the micellar core. 相似文献
9.
Sabbagh Omid Fanaei Mohammad Ali Arjomand Alireza 《Journal of Thermal Analysis and Calorimetry》2021,145(3):851-866
Journal of Thermal Analysis and Calorimetry - A novel NGL/LNG integrated scheme based on C3MR refrigeration system is modeled by using Aspen plus® in this study. The mentioned scheme utilizes... 相似文献
10.
In this article, a multiobjective problem with a feasible set defined by inequality, equality and set constraints is considered, where the objective and constraint functions are locally Lipschitz. Several constraint qualifications are given and the relations between them are analyzed. We establish Kuhn-Tucker and strong Kuhn-Tucker necessary optimality conditions for (weak) quasi e?ciency in terms of the Clarke subdifferential. By using two new classes of generalized convex functions, su?cient conditions for local (weak) quasi e?cient are also provided. Furthermore, we study the Mond-Weir type dual problem and establish weak, strong and converse duality results. 相似文献