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1.
Xia Li Gang-Hua Deng Rong-Juan Feng Ke Lin Zhen Zhang Yu Ba Zhou Lu Yuan Guo 《中国化学快报》2016,27(4):535-539
The salt effects on molecular orientation at air/liquid methanol interface were investigated by the polarization-dependent sum frequency generation vibrational spectroscopy(SFG-VS). We clarified that the average tilting angle of the methyl group to be u = 308 58 at the air/pure methanol surface assuming a d-function orientational distribution. Upon the addition of 3 mol/L Na I, the methyl group tilts further away from the surface normal with a new u = 418 38. This orientational change does not explain the enhancement of the SFG-VS intensities when adding Na I, implying the number density of the methanol molecules with a net polar ordering in the surface region also changed with the Na I concentrations. These spectroscopic findings shed new light on the salt effects on the surfaces structures of the polar organic solutions. It was also shown that the accurate determination of the bulk refractive indices and Raman depolarization ratios for different salt concentrations is crucial to quantitatively interpret the SFG-VS data. 相似文献
2.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
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4.
YuchengWu YongZhang LideZhang 《中国颗粒学报》2004,2(1):19-24
Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature. 相似文献
5.
SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION 总被引:1,自引:0,他引:1
BifengPan FengGao HongchenGu 《中国颗粒学报》2004,2(6):261-265
A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane. 相似文献
6.
结构静动力屈曲问题研究进展 总被引:19,自引:0,他引:19
近几十年来,结构的静动力屈曲问题一直是力学工作者极为关注的一个前沿课题.本文总结和综述了这一研究领域的几个基本问题:屈曲问题的分类、动态屈曲问题的特点及其特征量;介绍了屈曲问题的处理方法和目前已取得的成果;总结评述了人们关心的热点问题;屈曲问题的模型分析和实验技术、动态屈曲判别准则. 相似文献
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8.
INFLUENCE OF ASIAN DUSTS ON THE PHYSICOCHEMICAL PROPERTIES OF ATMOSPHERIC AEROSOLS IN TAIWAN DISTRICT USING THE PENGHU ISLANDS AS AN EXAMPLE 总被引:1,自引:0,他引:1
Chung-Shin Yuan* Cheng-Chung Sau Ming-Chung Chen Institute of Environmental Engineering Sun Yat-sen University Kaohsiung China 《中国颗粒学报》2004,2(4):144-152
1. Introduction In the early months of each year, Asian dusts transport frequently from Northwest China and Mongolia to the Pa-cific-Rim countries (Kagawa et al., 2001; Uno et al., 2002). It causes significant environmental effects such as ambient air quality deterioration, atmospheric visibility impairment, radiation energy reduction, mineral deposition, and acid rain neutralization (Terada et al., 2002; Zhang & An, 1999). During Asian dust periods, significant increases of atmos-pheric … 相似文献
9.
本文针对四边固定载流矩形薄板,利用Mathieu方程解的稳定性,研究其在电磁场与机械荷载共同作用下的磁弹性稳定性问题。首先在载流薄板的磁弹性非线性运动方程、物理方程、几何方程、洛仑兹力表达式及电动力学方程的基础上,导出了载流薄板在电磁场与机械荷载共同作用下的磁弹性动力稳定方程,然后应用Galer-kin方法将稳定方程整理为Mathieu方程的标准形式,并将薄板的动力稳定性问题归结为对Mathieu方程的求解。利用Mathieu方程的稳定解区域与非稳定解区域的分界,即方程系数λ和η的本征值关系,得出了磁弹性问题失稳临界状态的判别方程。通过具体算例,给出了四边固定载流矩形薄板的磁弹性动力失稳临界状态与相关参量之间的关系曲线,并对计算结果及其变化规律进行了分析讨论。 相似文献
10.
阶梯压电层合梁的波动动力学特性 总被引:2,自引:0,他引:2
采用行波理论系统地研究了压电阶梯梁的自由振动分析以及强迫响应的分析方法. 基于分布
参数理论研究了压电阶梯梁的波传播特性,忽略柔性梁横向剪切和转动惯量的影响,给出了
梁的轴向和横向的简谐波解. 将压电阶梯梁离散化为单元,考虑压电片的刚度和质量的影响,
建立了节点散射模型. 应用位移连续和力平衡条件,推导了节点的波反射和波传递矩阵,在
此基础上,引入波循环矩阵的概念,给出波循环矩阵、波传递系数矩阵的确定方法. 应用波
循环矩阵可以有效地计算结构的固有频率. 另外,应用波传递系数研究了压电陶瓷作动器位
置对其驱动能力的影响. 得出两个主要结论:1)作动器靠近悬臂梁固定端将有较强的驱动
能力,悬臂梁边界反射行波产生弯曲消失波有利于增大压电波的模态传递系数;2)模态传
递系数与固有频率的灵敏度密切相关,波传递系数越大, 对应该处固有频率变化灵敏度越大.
另外,数值算例表明了行波方法比有限元方法具有更高的计算精度. 相似文献