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排序方式: 共有41条查询结果,搜索用时 15 毫秒
1.
Masao Kimura Yasuo Takeichi Toshiki Watanabe Yasuhiro Niwa Ken'ichi Kimijima 《Chemical record (New York, N.Y.)》2019,19(7):1462-1468
Macroscopic properties of carbon fiber‐reinforced plastic (CFRP) and environmental barrier coating (EBC), widely used for airplanes, can be deteriorated by local cracks or degradation (“trigger sites”). We have tried to find these trigger sites using x‐ray microscopy (XM), which can provide the 2D or 3D images of the chemical states and microstructures. Crack initiation in CFRP was observed in a non‐destructive manner in multi‐scales (nm‐mm). 3D chemical‐state mapping of Yb in EBC was achieved with high resolution (<50 nm). In addition to XM, in‐situ observations at high temperatures were conducted for obtaining complementary information. X‐ray absorption spectroscopy (XAS) and x‐ray diffraction (XRD) analysis were performed simultaneously up to 1773 K. Dynamic XAS with short time‐resolution (<10 ns) was conducted to investigate changes in the local structure of metal. These approaches can help us identify degradation trigger sites in the materials. 相似文献
2.
Casting a photopolymer solution to form a film, followed by imagewise photoirradiation and subsequent wet development, leads to photolithography. Whereas the wet development is achievable with aqueous alkali, the emission of an organic solvent as a volatile organic compound (VOC) is usually inevitable during the film casting because ingredients of common photopolymers are insoluble in water. We show here a prototype of water‐borne photopolymers dispersed with milled nanoparticles of poorly water‐soluble photoacid generators (PAGs), which undergo solid‐state photolysis to liberate a photoacid to make a poly(vinyl alcohol) film insoluble in water with the aid of an acid‐sensitive crosslinking reagent. The photolysis of onium‐type PAGs is sensitized in the solid state simply by comilling with water‐insoluble sensitizers to extend spectral sensitivity of this kind of photopolymers. Fluorescence quenching measurements revealed that the solid‐state sensitization occurs through exciton migration in sensitizer particles followed by electron transfer to PAG particles.
3.
The first author is on leave from the Department of Mathematics, Chiba Institute of Technology, Narashino 275, Japan 相似文献
4.
Naohiro Murayama Takao Oikawa Takayuki Katto Ken'ichi Nakamura 《Journal of Polymer Science.Polymer Physics》1975,13(5):1033-1047
The piezoelectricity of PVDF thermoelect rets formed with vacuum-coated aluminum electrodes has been investigated in detail. The piezoelectricity depends on the β-form crystal structure of PVDF homopolymer and copolymers. However, the piezoelectricity is not attributed to the stress dependence of the spontaneous polarization of β-form crystals, but rather to the persistent polarization arising from trapped charges. The trapping mechanism is discussed. 相似文献
5.
Kuwamura N Kitano K Hirotsu M Nishioka T Teki Y Santo R Ichimura A Hashimoto H Wright LJ Kinoshita I 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(38):10708-10715
Interchange between the nickel +2 and +3 oxidation states precisely controls the reversible rearrangement of the tris(2-pyridylthio)methanide (tptm) ligand in the organometallic nickel(II) complex [{Ni(μ-Br)-(tptm)}(2)] (2). Oxidation of 2 first gives the corresponding Ni(III) complex [{Ni(μ-Br)(tptm)}(2)][PF(6)](2) (4). However, in solution the tptm ligand in 4 slowly undergoes a rearrangement, in which the N and S atoms of one of the pyridylthiolate arms exchange Ni and C bonding partners, thereby resulting in an "N,S-confused" isomer of tptm in the product, [NiBr(bpttpm)]PF(6) (5; bpttpm= bis(2-pyridylthio)(2-thiopyridinium)-methyl). Reduction of 5 reverses this ligand rearrangement and 2 is reformed quantitatively. The individual steps involved in these unusual ligand rearrangements were investigated by a number of methods, including voltammetric analysis, and a mechanism for this process is proposed. X-ray crystal structure determinations of the key compounds 2, 4 and 5 have been obtained. 相似文献
6.
Tsuguo Yamaoka Nobuko Nakajima Ken'ichi Koseki Yutaka Maruyama 《Journal of polymer science. Part A, Polymer chemistry》1990,28(9):2517-2532
A series of novel photosensitive polybenzoxazole precursors were prepared from polycondensation of 2,2-bis(3,3′-amino-4,4′-hydroxyphenyl)hexafluoropropane with photosensitive dicarboxylic acid chlorides such as p-phenylenediacryloyl chloride and benzophenone-4,4′-dicarboxylic chloride. The precursors are soluble in common organic solvents owing to the presence of perfluoromethyl groups in the chain structure, and insolubilized in the solvents on irradiation with the light. Polybenzoxazole patterns with high resolution as well as high aspect ratio were reproduced by baking the precursor patterns at 300°C. The pattern shrinkage on the conversion to polybenzoxazole was slight. The polybenzoxazole films offered good heat-resistance up to 400°C in addition to good electrical properties. 相似文献
7.
The Grignard coupling of 2,2-dibromo-1-phenyladamantane gave trans-2,2'-bi(1-phenyladamantylidene) (1-Ph). Single-crystal X-ray analysis indicated that 1-Ph has a 23.2 degrees twisted double bond, which is much more distorted than that of parent 2,2'-biadamantylidene (1-H) and that of the ethyl-substituted derivative (1-Et). A cyclic voltammogram showed a reversible electron oxidation wave at 0.87 V vs Fc/Fc(+), which is 0.19 V lower than 1-H, indicating a significant increase in the HOMO energy level due to the distortion. The reaction of 1-Ph with 0.9 equiv of bromine gave an intramolecular Friedel-Crafts alkylation product, while bromination of 1-H and 1-Me has been reported to give a bridged bromonium ion and a rearranged product, 2-(1-methyl-2-adamantylidene)-4-bromotricyclo[5,3,1,0(3.9)]undec-4-ene, respectively. 相似文献
8.
Ken'ichi Ohshika 《Proceedings of the American Mathematical Society》1996,124(3):739-743
Two Kleinian groups and are said to be topologically conjugate when there is a homeomorphism such that . It is conjectured that if two Kleinian groups and are topologically conjugate, one is a quasi-conformal deformation of the other. In this paper generalizing Minsky's result, we shall prove that this conjecture is true when is finitely generated and freely indecomposable, and the injectivity radii of all points of and are bounded below by a positive constant.
9.
Ken'ichi Ohshika 《Transactions of the American Mathematical Society》1998,350(10):3989-4022
Minsky proved that two Kleinian groups and are quasi-conformally conjugate if they are freely indecomposable, the injectivity radii at all points of , are bounded below by a positive constant, and there is a homeomorphism from a topological core of to that of such that and map ending laminations to ending laminations. We generalize this theorem to the case when and are topologically tame but may be freely decomposable under the same assumption on the injectivity radii. As an application, we prove that if a Kleinian group is topologically conjugate to another Kleinian group which is topologically tame and not a free group, and both Kleinian groups satisfy the assumption on the injectivity radii as above, then they are quasi-conformally conjugate.
10.
Masahiro Yoshida Kenji Ishii Ignace Jarrige Tetsu Watanuki Kazutaka Kudo Yoji Koike Ken'ichi Kumagai Nozomu Hiraoka Hirofumi Ishii Ku‐Ding Tsuei Jun'ichiro Mizuki 《Journal of synchrotron radiation》2014,21(1):131-135
A single‐crystal momentum‐resolved resonant inelastic X‐ray scattering (RIXS) experiment under high pressure using an originally designed diamond anvil cell (DAC) is reported. The diamond‐in/diamond‐out geometry was adopted with both the incident and scattered beams passing through a 1 mm‐thick diamond. This enabled us to cover wide momentum space keeping the scattering angle condition near 90°. Elastic and inelastic scattering from the diamond was drastically reduced using a pinhole placed after the DAC. Measurement of the momentum‐resolved RIXS spectra of Sr2.5Ca11.5Cu24O41 at the Cu K‐edge was thus successful. Though the inelastic intensity becomes weaker by two orders than the ambient pressure, RIXS spectra both at the center and the edge of the Brillouin zone were obtained at 3 GPa and low‐energy electronic excitations of the cuprate were found to change with pressure. 相似文献