Active palladium catalyst supported by bulky diimine ligand catalyzed Suzuki–Miyaura coupling reaction in water under phosphane‐free and low catalyst loading conditions

A new catalytic system based on palladium and bulky diimine ligand for Suzuki–Miyaura coupling reaction of aryl iodides, bromides and chlorides in neat water is described. The desired biphenyl products were obtained in high to excellent yields for aryl iodides and bromides in the presence of low catalyst loading. Air‐stable catalyst has been recycled for the reaction of iodobenzene with phenylboronic acid for five consecutive runs. Copyright © 2014 John Wiley & Sons, Ltd.     

Density and Viscosity for Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate with 2-Propanol,N,N-Dimethylacetamide and N,N-Dimethylformamide at 293.15–323.15 K: Experimental and PC-SAFT Modeling

Journal of Solution Chemistry - For three binary mixtures composed of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF4]) with 2-propanol, N,N?dimethylacetamide (DMA) and...