First representative of phosphorylated formic acid hydrazides with three P—C bonds: synthesis and addition to the phosphorylated 4-methylenequinones

Russian Chemical Bulletin - Diethylphosphinylmethanehydrazide, the first representative of the phosphorylated formic acid hydrazides with three P—C bonds was obtained, which can exhibit...     

New Reaction of Dimethylformamide with Acrylic Acid

Russian Journal of Organic Chemistry - A new homogeneous reaction of dimethylformamide (DMF) with acrylic acid was studied. The reaction afforded previously unknown...     

Synthesis of Alkylphosphoryl-Containing 4(5)-Arylimidazolin-2-ones

Russian Journal of General Chemistry - The acid-catalyzed reaction of {2-[1-(2,2-dimethoxyethyl)-3-(phenylcarboxamido)]ethyl}phosphonate or diethyl...     

Methods for the synthesis of 1H-pyrazolo[3,4-b]pyridine derivatives

This review covers and summarizes comprehensive data reported within the period from 2017 to 2021 on the synthetic strategies and approaches to 1H-pyrazolo[3,4-b]pyridine derivatives. Methods for the synthesis are systematized according to the method to assemble the pyrazolopyridine system, whereas their advantages and drawbacks are considered.

     

Amplification of shock waves in a bubble-filled liquid with gas concentration gradient

The properties are studied of the propagation of unsteady shock waves in a gas-liquid system of bubble structure in the case when the volume concentration of the gas changes in the direction of motion of the shock wave. It is established that when there is a sufficiently rapid drop in the gas content, an effect of amplification of the shock wave is observed which is due to the deceleration of the medium behind the shock wave. A study is made of the laws of the evolution of long- and short-wave pulsed perturbations in such systems. The authors consider processes of reflection of waves from obstacles and their passage from a gas into a bubble liquid, from a two-phase mixture into a pure liquid. The contribution is determined of nonequilibrium effects to the process of amplification of a wave.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 49–54, January–February, 1988.The authors wish to express gratitude to R. I. Nigmatulin for his interest in the study and for useful discussions.     

Reaction of Sesamol with N-(3,3-Diethoxypropyl)ureas. Synthesis of Diarylpropanes

Russian Journal of Organic Chemistry - An efficient procedure has been developed for the synthesis diarylpropanes containing an urea fragment by acid-catalyzed reaction of...     

Synthesis of 4-(Dibromomethyl)benzaldehyde by Catalytic Debromophosphoryl- and Phosphonyloxylation of 1,4-Bis(dibromomethyl)benzene with Phosphorus(IV) Acid Methyl Esters and Its Properties

A new procedure has been developed for the simultaneous preparation of terephthalaldehyde and 4-(dibromomethyl)benzaldehyde by catalytic debromophosphoryl- and phosphonyloxylation of 1,4-bis- (dibromomethyl)benzene with P(IV) acid methyl esters. The reaction of 4-(dibromomethyl)benzaldehyde with ortho esters in the presence of sulfuric acid gave the corresponding acetals, whereas in the presence of ZnCl₂ terephthalaldehyde bis-acetals were formed. 4-(Dibromomethyl)benzaldehyde and its acetal were converted to methyl 4-(dibromomethyl)- and 4-(dimethoxymethyl)benzoates which were phosphorylated by the action of chlorophosphines, as well as by successive treatment with phosphorus(III) chloride and P(III) esters.