Photon channelling in foams

Experiments by Gittings, Bandyopadhyay and Durian (Europhys. Lett. 65, 414 (2004)) demonstrate that light possesses a higher probability to propagate in the liquid phase of a foam due to total reflection. The authors term this observation photon channelling which we investigate in this article theoretically. We first derive a central relation in the work of Gitting et al. without any free parameters. It links the photon's path-length fraction f in the liquid phase to the liquid fraction ɛ. We then construct two-dimensional Voronoi foams, replace the cell edges by channels to represent the liquid films and simulate photon paths according to the laws of ray optics using transmission and reflection coefficients from Fresnel's formulas. In an exact honeycomb foam, the photons show superdiffusive behavior. It becomes diffusive as soon as disorder is introduced into the foams. The dependence of the diffusion constant on channel width and refractive index is explained by a one-dimensional random-walk model. It contains a photon channelling state that is crucial for the understanding of the numerical results. At the end, we shortly comment on the observation that photon channelling only occurs in a finite range of ɛ.     

The rectilinear distance Weber problem in the presence of a probabilistic line barrier

This paper considers the problem of locating a single facility in the presence of a line barrier that occurs randomly on a given horizontal route on the plane. The objective is to locate this new facility such that the sum of the expected rectilinear distances from the facility to the demand points in the presence of the probabilistic barrier is minimized. Some properties of the problem are reported, a solution algorithm is provided with an example problem, and some future extensions to the problem are discussed.     

High precision delta(17)O isotope measurements of oxygen from silicates and other oxides: method and applications

The use of infrared laser-assisted fluorination to release oxygen from milligram quantities of silicates or other oxide mineral grains is a well-established technique. However, relatively few studies have reported the optimisation of this procedure for oxygen-17 isotope measurements. We describe here details of an analytical system using infrared (10 μm) laser-assisted fluorination, in conjunction with a dual inlet mass spectrometer of high resolving power ( approximately 250) to provide (17)O and (18)O oxygen isotope measurements from 0.5-2 mg of silicates or other oxide mineral grains. Respective precisions (1) of typically 0.08 and 0.04 per thousand are obtained for the complete analytical procedure. Departures from the mass-dependent oxygen isotope fractionation line are quantified by Delta(17)O; our precision (1) of such measurements on individual samples is shown to be +/-0.024 per thousand. In turn, this permits the offset between parallel, mass-dependent fractionation lines to be characterised to substantially greater precision than has been possible hitherto. Application of this system to investigate the (17)O versus (18)O relationship for numerous terrestrial whole-rock and mineral samples, of diverse geological origins and age, indicates that the complete data set may be described by a single, mass-dependent fractionation line of slope 0.5244+/- 0.00038 (standard error). Copyright 1999 John Wiley & Sons, Ltd.     

Copper and iron interactions with angiotensin-converting enzyme inhibitors. A study by fast-atom bombardment tandem mass spectrometry

Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd.     

On the use of the Varignon frame for single facility Weber problems in the presence of convex barriers

This paper presents a new experimental approach to the Weber problem in the presence of convex barriers by using the Varignon frame. The Varignon frame is a mechanical system of strings, weights and a board with holes that has been used to identify an optimal location for the classical Weber problem. We show through analytical results that the same analog can also be used for some of the Weber problems in the presence of barriers. Some examples from the literature are revisited through experiments. Findings are compared to those found in the literature. Practical use of the analog is discussed as it provides rapid solutions, allows for flexibility, and enables one to visualize the problem.     

(Approximate) iterated successive approximations algorithm for sequential decision processes

The paper proves the convergence of (Approximate) Iterated Successive Approximations Algorithm for solving infinite-horizon sequential decision processes satisfying the monotone contraction assumption. At every stage of this algorithm, the value function at hand is used as a terminal reward to determine an (approximately) optimal policy for the one-period problem. This policy is then iterated for a (finite or infinite) number of times and the resulting return function is used as the starting value function for the next stage of the scheme. This method generalizes the standard successive approximations, policy iteration and Denardo’s generalization of the latter.     

A study of some parameters relevant to the response of harwell PMMA dosimeters to gamma and electron irradiation

The effects on the radiation response of Harwell polymethylmethacrylate (PMMA) dosimeters of dose-rate, radiation type, temperature during irradiation and post-irradiation storage, and post-irradiation stability, are of importance to the operators of commercial irradiation facilities.

This paper describes recent studies of the effects of some of these parameters on the radiation response of Harwell Red 4034, Amber 3042, and Gammachrome YR Perspex dosimeters, and provides data on batch to batch variation and shelf-life.     

Mammalian cell viability in electrospun composite nanofiber structures

Incorporation of mammalian cells into nanofibers (cell electrospinning) and multilayered cell-nanofiber structures (cell layering) via electrospinning are promising techniques for tissue engineering applications. We investigate the viability of 3T3-L1 mouse fibroblasts after incorporation into poly(vinyl alcohol) nanofibers and multilayering with poly(caprolactone) nanofibers and analyze the possible factors that affect cell viability. We observe that cells do not survive cell electrospinning but survive cell layering. Assessing the factors involved in cell electrospinning, we find that dehydration and fiber stretching are the main causes of cell death. In cell layering, the choice of solvent is critical, as residual solvent in the electrospun fibers could be detrimental to the cells.     

A Stochastic Competitive Research and Development Race Where “Winner Takes All” with Lower and Upper Bounds

The paper analyzes an environment in which several firms compete over the development of a project. Each firm decides how much to invest in the project while adhering to firm-specific lower and upper investment bounds. The completion time of the project by a firm has exponential distribution with rate that depends linearly on the investment of the firm. The firm that completes the project first collects all its revenues whereas the remaining firms earn nothing. The paper establishes the existence and uniqueness of both the Nash equilibrium and the globally optimal solution, provides explicit representations parametrically in the interest rate, and constructs computationally efficient methods to solve these two problems. It also examines sensitivity of Nash equilibrium to marginal changes in lower and upper bounds.