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排序方式: 共有421条查询结果,搜索用时 15 毫秒
1.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
2.
Dr. Goutam Kumar Kole Dr. Julia Merz Dr. Anissa Amar Dr. Bruno Fontaine Dr. Abdou Boucekkine Dr. Jörn Nitsch Sabine Lorenzen Dr. Alexandra Friedrich Dr. Ivo Krummenacher Marta Košćak Prof. Dr. Holger Braunschweig Prof. Dr. Ivo Piantanida Prof. Dr. Jean-François Halet Prof. Dr. Klaus Müller-Buschbaum Prof. Dr. Todd B. Marder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(8):2837-2853
Two N-methylpyridinium compounds and analogous N-protonated salts of 2- and 2,7-substituted 4-pyridyl-pyrene compounds were synthesised and their crystal structures, photophysical properties both in solution and in the solid state, electrochemical and spectroelectrochemical properties were studied. Upon methylation or protonation, the emission maxima are significantly bathochromically shifted compared to the neutral compounds, although the absorption maxima remain almost unchanged. As a result, the cationic compounds show very large apparent Stokes shifts of up to 7200 cm−1. The N-methylpyridinium compounds have a single reduction at ca. −1.5 V vs. Fc/Fc+ in MeCN. While the reduction process was reversible for the 2,7-disubstituted compound, it was irreversible for the mono-substituted one. Experimental findings are complemented by DFT and TD-DFT calculations. Furthermore, the N-methylpyridinium compounds show strong interactions with calf thymus (ct)-DNA, presumably by intercalation, which paves the way for further applications of these multi-functional compounds as potential DNA-bioactive agents. 相似文献
3.
Brahim ABBOU Imane LEBKIRI Hanae OUADDARI Lamya KADIRI Abdelkarim OUASS Amar HABSAOUI Ahmed LEBKIRI El Housseine RIFI 《Turkish Journal of Chemistry》2021,45(2):362
In this work, we study the elimination of three bivalent metal ions (Cd2+, Cu2+, and Pb2+) by adsorption onto natural illitic clay (AM) collected from Marrakech region in Morocco. The characterization of the adsorbent was carried out by X-ray fluorescence, Fourier transform infrared spectroscopy and X-ray diffraction. The influence of physicochemical parameters on the clay adsorption capacity for ions Cd2+, Cu2+, and Pb2+, namely the adsorbent dose, the contact time, the initial pH imposed on the aqueous solution, the initial concentration of the metal solution and the temperature, was studied. The adsorption process is evaluated by different kinetic models such as the pseudo-first-order, pseudo-second-order, and Elovich. The adsorption mechanism was determined by the use of adsorption isotherms such as Langmuir, Freundlich, and Temkin models. Experiments have shown that heavy metals adsorption kinetics onto clay follows the same order, the pseudo-second order. The isotherms of adsorption of metal cations by AM clay are satisfactorily described by the Langmuir model and the maximum adsorption capacities obtained from the natural clay, using the Langmuir isotherm model equation, are 5.25, 13.41, and 15.90 mg/g, respectively for Cd(II), Cu(II), and Pb(II) ions. Adsorption of heavy metals on clay is a spontaneous and endothermic process characterized by a disorder of the medium. The values of ΔH are greater than 40 kJ/mol, which means that the interactions between clay and heavy metals are chemical in nature. 相似文献
4.
Dr. Mohammad Kamal Hossain Dr. Qasem Ahmed Drmosh Amar Kamal Mohamedkhair 《化学:亚洲杂志》2021,16(13):1807-1819
A new route has been developed to design plasmonic pollen grain-like nanostructures (PGNSs) as surface-enhanced Raman scattering (SERS)-active substrate. The nanostructures consisting of silver (Ag) and gold (Au) nanoparticles along with zinc oxide (ZnO) nanoclusters as spacers were found highly SERS-active. The morphology of PGNSs and those obtained in the intermediate stage along with each elemental evolution has been investigated by a high-resolution field emission scanning electron microscopy. The optical band gaps and crystal structure have been identified by UV-vis absorption and X-ray powder diffraction (XRD) measurements, respectively. For PGNSs specimen, three distinct absorption bands related to constituent elements Ag, Au, and ZnO were observed, whereas XRD peaks confirmed the existence of Ag, Au, and ZnO within the composition of PGNSs. SERS-activity of PGNSs was confirmed using Rhodamine 6G (R6G) as Raman-active dyes. Air-cooled solid-state laser kits of 532 nm were used as excitation sources in SERS measurements. SERS enhancement factor was estimated for PGNSs specimen and was found as high as 3.5×106. Finite difference time domain analysis was carried out to correlate the electromagnetic (EM) near-field distributions with the experiment results achieved under this investigation. EM near-field distributions at different planes were extracted for s-, p- and 45° of incident polarizations. EM near-field distributions for such nanostructures as well as current density distributions under different circumstances were demonstrated and plausible scenarios were elucidated given SERS enhancements. Such generic fabrication route as well as correlated investigation is not only indispensable to realize the potential of SERS applications but also unveil the underneath plasmonic characteristics of complex SERS-active nanostructures. 相似文献
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7.
C.E. Satheesh Pushpanathan N. Sathish Kumar P. Raghavendra Kumara Ramasamy Karvembu Amar Hosamani M. Nethaji 《应用有机金属化学》2019,33(10)
Two new half‐sandwich Ru (II)(p‐cymene) complexes ( 1 and 2 ) containing dopamine‐based (N, O) Schiff base ligands ( L 1 H and L 2 H ) were synthesized and characterized by FT‐IR, UV–Visible and 1H & 13C NMR spectral techniques, and elemental analyses. The spectroscopic and analytical data revealed monobasic bidentate coordination of the ligands with Ru ion. The molecular structures of L 1 H , L 2 H and 2 were further confirmed by single crystal X‐ray diffraction study. Complexes 1 and 2 have been employed as catalysts in the transfer hydrogenation of ketones using 2‐propanol as a hydrogen source at 85 °C under base‐free condition. Good to the excellent yield of secondary alcohols, gram scale synthesis, and high TON and TOF made this catalytic system interesting. 相似文献
8.
In this paper we study a four-dimensional linear center. Based on the averaging theory, we investigate the existence of limit cycles of the system. 相似文献
9.
M. Amar D. Andreucci R. Gianni C. Timofte 《Journal of Mathematical Analysis and Applications》2021,493(2):124533
We prove a well-posedness result for two pseudo-parabolic problems, which can be seen as two models for the same electrical conduction phenomenon in heterogeneous media, neglecting the magnetic field. One of the problems is the concentration limit of the other one, when the thickness of the dielectric inclusions goes to zero. The concentrated problem involves a transmission condition through interfaces, which is mediated by a suitable Laplace-Beltrami type equation. 相似文献
10.
Photoisomerisation in Aminoazobenzene‐Substituted Ruthenium(II) Tris(bipyridine) Complexes: Influence of the Conjugation Pathway 下载免费PDF全文
Dr. Anissa Amar Dr. Paul Savel Dr. Huriye Akdas‐Kilig Dr. Claudine Katan Prof. Hacène Meghezzi Prof. Abdou Boucekkine Dr. Jean‐Pierre Malval Dr. Jean‐Luc Fillaut 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8262-8270
Transition‐metal complexes containing stimuli‐responsive systems are attractive for applications in optical devices, photonic memory, photosensing, as well as luminescence imaging. Amongst them, photochromic metal complexes offer the possibility of combining the specific properties of the metal centre and the optical response of the photochromic group. The synthesis, the electrochemical properties and the photophysical characterisation of a series of donor–acceptor azobenzene derivatives that possess bipyridine groups connected to a 4‐dialkylaminoazobenzene moiety through various linkers are presented. DFT and TD‐DFT calculations were performed to complement the experimental findings and contribute to their interpretation. The position and nature of the linker (ethynyl, triazolyl, none) were engineered and shown to induce different electronic coupling between donor and acceptor in ligands and complexes. This in turn led to strong modulations in terms of photoisomerisation of the ligands and complexes. 相似文献