全文获取类型
收费全文 | 304篇 |
免费 | 18篇 |
国内免费 | 4篇 |
专业分类
化学 | 234篇 |
晶体学 | 2篇 |
力学 | 9篇 |
数学 | 38篇 |
物理学 | 43篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 11篇 |
2020年 | 14篇 |
2019年 | 13篇 |
2018年 | 15篇 |
2017年 | 10篇 |
2016年 | 21篇 |
2015年 | 20篇 |
2014年 | 23篇 |
2013年 | 31篇 |
2012年 | 31篇 |
2011年 | 26篇 |
2010年 | 15篇 |
2009年 | 15篇 |
2008年 | 24篇 |
2007年 | 13篇 |
2006年 | 11篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 3篇 |
1999年 | 1篇 |
1994年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有326条查询结果,搜索用时 171 毫秒
1.
Roushan Alireza Hassanjani Omrani Abdollah 《Journal of Thermal Analysis and Calorimetry》2021,144(1):107-118
Journal of Thermal Analysis and Calorimetry - This paper reports the successful synthesis of NaX nanocrystals using an organic, additive-free hydrothermal approach. Then, solution casting was used... 相似文献
2.
Roshanak Hatamvand Mohsen Adeli Abdollah Yari 《Journal of polymer science. Part A, Polymer chemistry》2020,58(19):2784-2791
Boronic acid functionalized materials have gained much attention in both chemistry and biology fields due to their multivalent covalent interactions with cis-diol containing (macro) molecules. The remarkable progress in this field has resulted in the development of their biomedical applications, such as, biosensors and nanocarriers. In this study, the spherical nanoparticles consisting of glycerol and 2,5-thiophenediylbisboronic acid were synthesized by one-pot ring opening copolymerization of a mixture of glycidol and 2,5-thiophenediylbisboronic acid. The synthesized nanoparticles were used for the modification of the glassy carbon electrode and the determination of Guaifenesin. The synthesized polymeric nanoparticles were characterized by different spectroscopic and microscopic methods including UV–vis, IR, NMR, DLS, and SEM. Additionally, the electrochemical behavior of the fabricated electrode toward Guaifenesin was investigated with cyclic voltammetry and electrochemical impedance spectroscopy. 相似文献
3.
An effective one-pot, convenient process for the synthesis of 1- substituted 1H-tetrazoles from triethyl orthoformate, amines, and sodium azide is described using copper (II) doped and immobilized on functionalized magnetic hydrotalcite (Fe3O4/HT-NH2 CuII) as a novel recyclable catalyst. The application of this catalyst allows the synthesis of a variety of tetrazoles in good to excellent yields in water. The new catalyst was characterized using Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), vibration sample magnetometry (VSM) and inductively coupled plasma analysis (ICP-OES). This new procedure offers several advantages such as short operational simplicity, practicability, and applicability to various substrates and the absence of any tedious workup or purification. The loading amount of CuII (doped and immobilized) on functionalized magnetic hydrotalcite was indicated to be 4.66 mmol g−1, obtained from the ICP-OES analysis. Also, the excellent catalytic performance, thermal stability, and separation of the catalyst make it an excellent heterogeneous system and a useful alternative to other heterogeneous catalysts. Also, the catalyst could be magnetically separated and reused six times without significant loss of catalytic activity. 相似文献
4.
Numerical Algorithms - Recently, Axelsson and Salkuyeh in (BIT Numerical Mathematics, 59 (2019) 321–342) proposed the transformed matrix iteration (TMIT) method for solving a certain... 相似文献
5.
Optical Review - Importance of simultaneous measurement of temperature and strain by fiber Bragg grating (FBG) sensors has led to innovation of several renewing techniques. Most of them are based... 相似文献
6.
7.
Zakieh Yousefi Hossein Eshtiagh‐Hosseini Alireza Salimi Janet Soleimannejad 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(5):386-393
In the title compound, [Cu(C7H3N2O4)(C4H5N2)(H2O)], (I), pyridine‐2,6‐dicarboxylate (pydc2−), 2‐aminopyrimidine and aqua ligands coordinate the CuII centre through two N atoms, two carboxylate O atoms and one water O atom, respectively, to give a nominally distorted square‐pyramidal coordination geometry, a common arrangement for copper complexes containing the pydc2− ligand. Because of the presence of Cu...Xbridged contacts (X = N or O) between adjacent molecules in the crystal structures of (I) and three analogous previously reported compounds, and the corresponding uncertainty about the effective coordination number of the CuII centre, density functional theory (DFT) calculations were used to elucidate the degree of covalency in these contacts. The calculated Wiberg and Mayer bond‐order indices reveal that the Cu...O contact can be considered as a coordination bond, whereas the amine group forming a Cu...N contact is not an effective participant in the coordination environment. 相似文献
8.
Abdollah Alhevaz 《代数通讯》2017,45(3):919-923
Ever since the introduction, skew inverse Laurent series rings have kept growing in importance, as researchers characterized their properties (such as Noetherianness, Armendarizness, McCoyness, etc.) in terms of intrinsic properties of the base ring and studied their relations with other fields of mathematics, as for example quantum mechanics theory. The goal of our paper is to study the primeness and semiprimeness of general skew inverse Laurent series rings R((x?1;σ,δ)), where R is an associative ring equipped with an automorphism σ and a σ-derivation δ. 相似文献
9.
10.