南极鲍鱼样品中有机氯农药的测定

报道了中国南极长城站周围及某国的一个排污口的鲍鱼样品中有机氯农药的残留量。测定结果显示鲍鱼样品中有机氯农药的含量HCHs为ND－1.87ng/g，DDTs为ND－6.61ng/g干重，有机氯农药的回收率为46％－75％。     

Manipulating surface plasmon waves by transformation optics:Design examples of a beam squeezer,bend,and omnidirectional absorber

We present several design examples of how to apply transformation optics and curved space under coordinate transformation to manipulating the surface plasmon waves in a controlled manner.We demonstrate in detail the design procedure of the plasmonic wave squeezer,in-plane bend and omnidirectional absorber.We show that the approximation method of modifying only the dielectric material of a dielectric-metal surface of the plasmonic device could lead to acceptable performance,which facilitates the fabrication of the device.The functionality of the proposed plasmonic device is verified using three-dimensional full-wave electromagnetic simulations.Aiming at practical realization,we also show the design of a plasmonic in-plane bend and omnidirectional absorber by an alternative transformation scheme,which results in a simple device structure with a tapered isotropic dielectric cladding layer on the top of the metal surface that can be fabricated with existing nanotechnology.     

N-(末端三甲基硅苄基甘氨酸肽链)邻苯二甲酰亚胺的光诱导单电子转移成环反应

以苄基甘氨酸为起始原料合成N-(末端三甲基硅苄基甘氨酸肽链)邻苯二甲酰亚胺(1).1在甲醇溶剂中光照发生单电子转移反应,生成分子内双自由基10,自由基偶合生成环聚甘氨酸肽化合物2.此反应产率好,区域选择性高.所有新化合物结构均经NMR和质谱验证.     

N-(带有不同离去基团的二供电子链)邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应

同时含有末端乙氧基醚支链和末端三甲基硅聚乙氧基醚支链的邻苯二甲酰亚胺衍生物1在高氯酸的甲醇溶液中发生光诱导单电子转移(SET)反应,以很高的反应区域选择性和很好的产率得到由末端三甲基硅聚乙氧基醚链环合构成的环状化合物.所有新化合物均经NMR和EI-MS确定其结构.     

Manipulating surface plasmon waves by transformation optics: Design examples of beam squeezer, bend, and omnidirectional absorber

We present several design examples of how to apply the transformation optics and curved space under coordinate transformation to manipulating the surface plasmon waves in a controlled manner. We demonstrate in detail the design procedure of the plasmonic wave squeezer, in-plane bend and omnidirectional absorber. We show that the approximation method of modifying only the dielectric material of a dielectric-metal surface of the plasmonic device could lead to acceptable performance, which facilitates the fabrication of the device. The functionality of the proposed plasmonic device is verified using three-dimensional full-wave electromagnetic simulations. Aiming at practical realization, we also show the design of plasmonic in-plane bend and omnidirectional absorber by an alternative transformation scheme, which results in simple device structure with a tapered isotropic dielectric cladding layer on the top of the metal surface that can be fabricated with the existing nanotechnology.     

Planar Metamaterial Microwave Absorber for all Wave Polarizations

We present a design for a polarization insensitive metamaterial absorber at 9.5 GHz by utilizing properly arranged resonant unit cells with orthogonal polarization sensitivity. Full-wave electromagnetic simulation demonstrates nearly perfect microwave absorption, which has been verified by experimental measurement with a maximum absorption of about 92% for incident wave with different polarizations. Furthermore, we find such a metamaterial thin absorber could work for a wide incident angle ranging from 0° to 50°with absorption no less than 80° for both the transverse electric mode and transverse magnetic mode.     

邻苯二甲酰二肽的光诱导单电子转移环化反应合成哌嗪酮类化合物

邻苯二甲酰化的二肽(1)在光照下,经过单电子转移形成分子内双自由基(5),自由基(5)分子内耦合成环得到含哌嗪酮的化合物.此反应产率较好,可以成为合成哌嗪酮类化合物的新方法.所有新化合物均经NMR和MS确定其结构.     

基于石墨烯的太赫兹波散射可调谐超表面

设计了一个可调谐的太赫兹超表面,由在随机反射超表面基底中嵌入可偏置的双层石墨烯构成,可以实现对太赫兹波散射特性的动态调控.全波仿真试验结果证实了所预期的超表面散射可调性能.通过增大偏置电压提升石墨烯的费米能级,使得该超表面的太赫兹波散射样式从漫反射逐渐向镜面反射过渡,从而实现散射特性的连续调控,且该超表面具有对电磁波极化角度不敏感的特点.这些特性使得该超表面能很好地融合到变化的环境中,在太赫兹隐身方面具有潜在的应用价值.     

基于场变换的毫米波半波片设计

极化转换是电磁波调控的重要研究方向之一.本文基于场变换理论提出一种宽入射角的宽带毫米波半波片.基于等效媒质理论,该半波片可由亚波长厚度的两种介电常数不同的材料周期性排布后旋转45°得到.通过设计控制两种材料的介电常数、高度比值以及整个半波片的厚度可以在毫米波段实现极化转换的功能,此设计具有低损耗和高转化效率的特点.此半波片能实现横电波与横磁波的相互转换以及圆极化波的相互转换,极化转换-3 dB相对带宽达49%.仿真和实测结果相符,验证了该半波片宽带高效的极化转换效果.在入射角为60°时,极化转换-3 dB带宽依然能够达到36%左右.