| 邻苯二甲酰二肽的光诱导单电子转移环化反应合成哌嗪酮类化合物 |
| |
| 引用本文： | 谭广慧,魏树权,赵俊明,张鹏,王丙南,郑鹏,刘岩,金英学.邻苯二甲酰二肽的光诱导单电子转移环化反应合成哌嗪酮类化合物[J].影像科学与光化学,2010,28(2):131-136. |
| |
| 作者姓名： | 谭广慧 魏树权 赵俊明 张鹏 王丙南 郑鹏 刘岩 金英学 |
| |
| 作者单位： | 哈尔滨师范大学, 化学化工学院, 黑龙江, 哈尔滨, 150025 |
| |
| 基金项目： | 国家自然科学基金项目，黑龙江省教育厅海外学人科研基金，国家人事部留学人员科技活动项目择优资助 |
| |
| 摘 要： | 邻苯二甲酰化的二肽(1)在光照下,经过单电子转移形成分子内双自由基(5),自由基(5)分子内耦合成环得到含哌嗪酮的化合物.此反应产率较好,可以成为合成哌嗪酮类化合物的新方法.所有新化合物均经NMR和MS确定其结构.
|
| 关 键 词： | 二肽 单电子转移 环化反应 哌嗪酮 |
| 收稿时间： | 2009-11-11 |
Synthesis of Ketonpiprazine from N-phthalimido Dipeptides by Photoinduced Single Electron Transfer |
| |
| TAN Guang-hui,WEI Shu-quan,ZHAO Jun-ming,ZHANG Peng,WANG Bing-nan,ZHENG Peng,LIU Yan,JIN Ying-xue.Synthesis of Ketonpiprazine from N-phthalimido Dipeptides by Photoinduced Single Electron Transfer[J].Imaging Science and Photochemistry,2010,28(2):131-136. |
| |
| Authors: | TAN Guang-hui WEI Shu-quan ZHAO Jun-ming ZHANG Peng WANG Bing-nan ZHENG Peng LIU Yan JIN Ying-xue |
| |
| Institution: | College of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, P. R. China |
| |
| Abstract: | Biradical(5) were formed by photoinduced single electron transfer of N-phthalimido dipeptide(1) under irradiation. The biradical(5) could couple intramolecularly to form cycloproduct(2) containing ketonpiprazine moiety. This good yield reaction could be used as a new synthesis method for ketonpiperazine analogous. The structures of all the new compounds were characterized by MS and NMR spectra. |
| |
| Keywords: | dipeptide single electron transfer(SET) cyclization reaction ketopiprazine |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《影像科学与光化学》浏览原始摘要信息 |
| 点击此处可从《影像科学与光化学》下载免费的PDF全文 |
