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Silver thiolate polymers are intercepted to form different structural fragments when reacting with variant solubilizing reagents,which usually serve as the starting point for the preparation of clusters.However,such a process is still far from clear.Herein,we report the controlled synthesis of silver-t-butylthiolate clusters from reactions of polymeric[AgtBu S]n and suitable templates in the presence of solubilizing reagents to offer a detailed look at the mechanism of cluster’s forma... 相似文献
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