| Anion-templated Self-assembly for the Preparation of Silver-t-butylthiolate Clusters |
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| 作者姓名： | 金俊玲 沈扬林 米立伟 谢云鹏 卢兴 |
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| 作者单位： | 1. Henan Key Laboratory of Functional Salt Materials,Center for Advanced Materials Research,Zhongyuan University of Technology;2. College of Materials Engineering,Henan International Joint Laboratory of Rare Earth Composite Materials,Henan University of Engineering;3. State Key Laboratory of Materials Processing and Die & Mould Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology |
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| 基金项目： | supported by the National Natural Science Foundation of China (No. 21771071, 22171094, and 21925104)；;the Key Scientific Research Projects of Universities in Henan Province (No. 21A150060)； |
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| 摘 要： | Silver thiolate polymers are intercepted to form different structural fragments when reacting with variant solubilizing reagents,which usually serve as the starting point for the preparation of clusters.However,such a process is still far from clear.Herein,we report the controlled synthesis of silver-t-butylthiolate clusters from reactions of polymericAgtBu S]n and suitable templates in the presence of solubilizing reagents to offer a detailed look at the mechanism of cluster’s forma...
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