利用聚合物乳液合成聚甲基丙烯酸甲酯/二氧化硅纳米杂化材料

通过正硅酸乙酯分别在聚甲基丙烯酸甲酯乳液和四氢呋喃溶液中的溶胶－凝胶反应制备出不同的聚甲基丙烯酸甲酯／二氧化硅复合材料。利用扫描电镜、透镜电镜、差热分析和热失重对试样进行了分析。结果表明，利用聚合物乳液可以获得纳米分散的聚甲基丙烯酸甲酯／二氧化硅复合材料，并且在某种程度上其分散尺度小于利用聚合物溶液获得的复合材料。同时，利用聚合物乳液来制备聚甲基丙烯酸甲酯／二氧化硅杂化材料更有利于凝胶过程中二氧化硅网络的形成。     

Quantitative evaluation of space charge effects of laser-cooled three-dimensional ion system on a secular motion period scale

In this paper,we introduce a method of quantitatively evaluating and controlling the space charge effect of a lasercooled three-dimensional(3 D) ion system in a linear Paul trap.The relationship among cooling efficiency,ion quantity,and trapping strength is analyzed quantitatively,and the dynamic space distribution and temporal evolution of the 3 D ion system on a secular motion period time scale in the cooling process are obtained.The ion number influences the eigen-micromotion feature of the ion system.When trapping parameter q is ~ 0.3,relatively ideal cooling efficiency and equilibrium temperature can be obtained.The decrease of axial electrostatic potential is helpful in reducing the micromotion heating effect and the degradation in the total energy.Within a single secular motion period under different cooling conditions,ions transform from the cloud state(each ion disperses throughout the envelope of the ion system) to the liquid state(each ion is concentrated at a specific location in the ion system) and then to the crystal state(each ion is subjected to a fixed motion track).These results are conducive to long-term storage and precise control,motion effect suppression,high-efficiency cooling,and increasing the precision of spectroscopy for a 3 D ion system.     

囚禁状态冷分子离子制备及应用

冷分子离子,尤其是在离子阱中空间囚禁起来的冷分子离子具有空间定域、可长时间存储以及和与环境分离的特性。这些特性使得空间囚禁的冷分子离子在分子光谱精密测量、探测分子离子与中性分子之间的碰撞反应等方面越来越受到人们的重视,并在最近几年得到了快速的发展。文章介绍了冷分子离子的产生方法,及其近几年在精密测量和低温下的碰撞反应等研究领域取得的主要研究成果。     

一般粘弹结构的模态分析

分析了一般粘弹结构特征值问题的特点 ,建立了一般粘弹结构的模态分析方法。与粘弹结构已有的模态分析方法相比 ,该方法通用于更一般的粘弹结构 ,在形式上不涉及粘弹本构关系项 ,并只涉及一种模态向量     

Secular Motion Frequencies of ~9Be~+ Ions and ~(40)Ca~+ Ions in Bi-component Coulomb Crystals

We obtain bi-component Coulomb crystals using laser-cooled ~(40)Ca~+ ions to sympathetically cool ~9Be~+ ions in a linear Paul trap. The shell structures of the bi-component Coulomb crystals are investigated. The secular motion frequencies of the two different ions are determined and compared with those in the single-component Coulomb crystals. In the radial direction, the resonant motion frequencies of the two ionic species shift toward each other due to the strong motion coupling in the ion trap. In the axial direction, the motion frequency of the laser-cooled~(40)Ca~+is impervious to the sympathetically cooled ~9Be~+ ions because the spatially separation of the two different ionic species leads to the weak motion coupling in the axial direction.     

Determining the structural phase transition point from the temperature of ~（40）Ca~＋ Coulomb crystal

We observed the linear-to-zigzag structural phase transition of a ^40Ca^＋ crystal in a homemade linear Paul trap. The values of the total temperature of the ion crystals during the phase transition are derived using the molecular-dynamics（MD） simulation method. A series of simulations revealed that the ratio of the radial to axial secular frequencies has a dependence on the total temperature that obeys different functional forms for linear and zigzag structures, and the transition point occurs where these functions intersect; thus, the critical value of the ratio of secular frequencies that drives the structure phase transition can be derived.