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合成了荧光试剂水杨醛缩邻氨基苯酚,在NH4Cl-NH3·H2O缓冲溶液介质中,铅离子能使其荧光强度增强,荧光增强的程度随铅离子含量的增加而增大.据此建立了测定痕量铅离子的直接荧光分析方法.并研究此试剂与铅荧光反应的最佳条件,在λex/λem=386/502nm处,铅离子含量在0.0-200.0μg·L-1范围内与△F呈良好的线性关系,方法的检出限为1.62μg·L-1.该方法操作简便快速,具有极高的灵敏度.用于蓄电池废水中铅含量的测定,结果与火焰原子吸收光谱法基本一致,效果令人满意. 相似文献
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富氧条件下乙炔选择催化还原NOx 总被引:1,自引:0,他引:1
Acetylene as a reducing agent of metal exchanged HY catalysts, for selective catalytic reduction of NO in the reaction system of 0.16% NO, 0 (C2H2-SCR) was investigated over a series 08% C2H2, and 9.95% O2 (volume percent) in He. 75% of NO conversion to N2 with hydrocarbon efficiency about 1.5 was achieved over a Ce-HY catalyst around 300 ℃. The NO removal level was comparable with that of selective catalytic reduction of NOx by C3H6 reported in literatures, although only one third of the reducing agent in carbon moles was used in the C2H2-SCR of NO. The protons in zeolite were crucial to the C2H2-SCR of NO, and the performance of HY in the reaction was significantly promoted by cerium incorporation into the zeolite. NO2 was proposed to be the intermediate of NO reduction to N2, and the oxidation of NO to NO2 was rate-determining step of the C2H2-SCR of NO over Ce-HY. The suggestion was well supported by the results of the NO oxidation with O2, and the C2H2 consumption under the conditions in the presence or absence of NO. 相似文献
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Based on the general theory of dislocation and kink, we have constructed the three kink models corresponding to the 1/2 (111){011} and 1/2 (111){112} edge dislocations (EDs) in bcc Fe using the molecular dynamics method. We found that the geometric structure of a kink depends on the type of ED and the structural energies of the atom sites in the dislocation core region, as well as the geometric symmetry of the dislocation core and the characteristic of the stacking sequence of atomic plane along the dislocation line. The formation energies and widths of the kinks on the 1/2 (111){011} and 1/2 (111){112} EDs are calculated, the formation energies are 0.05eV and 0.04eV, and widths are 6.02b and 6.51b, respectively (b is the magnitude of the Burgers vector). The small formation energies indicate that the formation of kink in the edge dislocation is very easy in bcc Fe. 相似文献
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利用离散变分方法和DMol方法,研究了P对bcc Fe中[100](010)刃型位错上扭折电子结构的影响,计算了杂质偏聚能、原子间相互作用能、电荷密度及态密度.计算结果表明:微量P引入体系后,电荷发生了重新分布,P原子得到电子,其周围Fe原子失去电子,由于P原子的3p轨道与近邻Fe原子的3d4s4p轨道之间杂化,使P原子与近邻Fe原子间有较强的相互作用,不利于扭折的迁移,使位错运动受阻,有利于材料强度的提高.同时,杂质P原子与基体原子间的成键主要是d,p轨道起作用,使得它们之间的成键有较强的方向性,有可能 相似文献
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Anisotropic elastic properties and ideal uniaxial compressive strength of TiB_2 from first principles calculations 下载免费PDF全文
The structural, anisotropic elastic properties and the ideal compressive and tensile strengths of titanium diboride(TiB_2) were investigated using first-principles calculations based on density functional theory. The stress–strain relationships of TiB_2 under 1010, 1210, and 0001 compressive loads were calculated. Our results showed that the ideal uniaxial compressive strengths are |σ _(1210)| = 142.96 GPa, |σ_(0001)| = 188.75 GPa, and |σ_(1010)| = 245.33 GPa, at strains -0.16,-0.32, and-0.24, respectively. The variational trend is just the opposite to that of the ideal tensile strength withσ 1010 = 44.13 GPa, σ_(0001)= 47.03 GPa, and σ_(1210)= 56.09 GPa, at strains 0.14, 0.28, and 0.22, respectively. Furthermore, it was found that TiB_2 is much stronger under compression than in tension. The ratios of the ideal compressive to tensile strengths are 5.56, 2.55, and 4.01 for crystallographic directions 1010, 1210, and 0001, respectively. The present results are in excellent agreement with the most recent experimental data and should be helpful to the understanding of the compressive property of TiB_2. 相似文献
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Effect of Re on stacking fault nucleation under shear strain in Ni by atomistic simulation 下载免费PDF全文
The effect of Re on stacking fault(SF) nucleation under shear strain in Ni is investigated using the climbing image nudged elastic band method with a Ni–Al–Re embedded-atom-method potential. A parameter(?Eb sf), the activation energy of SF nucleation under shear strain, is introduced to evaluate the effect of Re on SF nucleation under shear strain. Calculation results show that ?Eb sfdecreases with Re addition, which means that SF nucleation under shear strain in Ni may be enhanced by Re. The atomic structure observation shows that the decrease of ?Eb sfmay be due to the expansion of local structure around the Re atom when SF goes through the Re atom. 相似文献
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CO adsorption on small Aun(n=1-7) clusters supported on a reduced rutile TiO2(110) surface:a first-principles study 下载免费PDF全文
CO adsorption on small Au n(n = 1-7) clusters which are supported by a partially reduced rutile TiO 2(110) surface has been investigated by the first-principles method.The low coordinated sites of Au clusters are favorable for CO adsorption.CO-Au n-TiO 2 system displays surface magnetism.There is a strong interaction between the adsorbed CO molecule and the supported Au clusters. 相似文献
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网络环境下基于价值理论的我国消费者购买意愿影响因素研究 总被引:1,自引:0,他引:1
随着网上零售业快速发展,如何提高网络消费者购买意愿已成为人们关注的焦点。论文运用感知价值理论分析了网络消费者购买意愿影响因素,提出了影响网络消费者购买意愿的重要研究假设,构建了网络消费者购买意愿假设模型,采用结构方程模型方法对样本数据进行了定量研究。研究结果揭示了网络消费者的风险态度通过感知利益和感知风险对感知价值的间接影响,而感知价值与购买意愿显著正相关。最后,论文对研究结果进行了讨论,提出了促进我国网上零售业发展的建议. 相似文献