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碳纳米管阵列超双疏性质的发现 总被引:13,自引:0,他引:13
用高温裂解酞菁金属络合物方法制备了几种具有不同形貌的阵列碳纳米管膜 ,并对其超疏水和超双疏性质进行了研究 .对于具有均匀长度和外径的阵列碳纳米管膜 ,文章作者发现 ,在未经任何处理时 ,其表现出超疏水和超亲油性质 ,与水的接触角为 15 8 5± 1 5° ,与油的接触角为 0± 1 0°.经氟化处理后 ,则表现出超双疏性质 ,与水和油的接触角分别为 171± 0 5°和 16 1± 1 0° .对具有类荷叶结构的阵列碳纳米管膜 ,其表面形貌与荷叶的十分接近 ,且在未经任何处理时所表现出的超疏水性也与荷叶的非常接近 ,与水的接触角为 16 6° ,滚动角为 8° .这种超疏水和超双疏性质是由表面的纳米结构以及微米结构和纳米结构的结合产生的 .这一发现为无氟超疏水表面 界面材料的研究提供了新的思路 相似文献
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A series of new silicon-containing poly(p-arylene vinylene)s(PAVs)with anthracene units in the main chain were synthesized by hydrosilylation reaction.The introduction of organosilicon units improved the solubility of the polymers,and theπ-πconjugation of polymeric chains was interrupted.These polymers behaved as blue-green light emitters with their fluorescence maximum at 447—499 nm and quantum yields in the range of 0.28-0.30 in solution. 相似文献
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Adding additives into peroskite precursor solution has been proven as a simple and efficient strategy to improve the quality of peroskite films. In this work, we demonstrate an effective additive strategy to improve the quality of all-inorganic perovskite films by adding a novel silazane additive heptamethyldisilazane (HDMS). The power conversion efficiency (PCE) of the optimized devices is enhanced from 14.55% to 15.31% with an open-circuit voltage over 1.26 V due to the higher quality perovskite films with lower trap density after the incorporation of HDMS. More interestingly, the HDMS devices exhibit superior humidity and thermal stability compared with the control ones. This work provides a simple and efficient strategy to enhance the device performance and stability of all-inorganic perovskite solar cells, which could facilitate its commercialization. 相似文献
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New silicon-containing phenyleneethynylene hybrid oligomers P2, P3, and P4 were synthesized via Sonogashira cross-coupling reactions of ethynyl-terminated silazane monomer N,N′-bis(4-ethynylphenyl)-1,1-diphenylsilazane(M1) and corresponding bis-(4-bromo-phenyl)-ended organosilicon unit containing monomers, respectively. These new oligomers were easily soluble in common solvents. The incorporation of flexible organosilicon units in the oligomers leads to blue-shift in both the UV-Vis absorption and fluorescence emission spectra similarly. The results of differential scanning calorimetry(DSC) indicate that the flexible units relieve the rigidity of oligomeric chain and provide favorable conformation for thermal cross-linking reactions. The oligomers show good thermal and thermal-oxidative stability from the thermogravimetric analysis(TGA), with their decomposition temperature at 10% weight loss(T10%) higher than 400 ?C under both nitrogen and air atmosphere. 相似文献
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各向异性水凝胶在外界的响应刺激下可以具有不同的反应机制与驱动过程. 本文综述了近期基于PNIPAM水凝胶智能响应驱动器的设计方法, 总结了多种各向异性结构对驱动性能的影响, 并对该领域所面临的挑战进行了讨论. 相似文献
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柱状结构阵列碳纳米管膜的超疏水性研究 总被引:14,自引:1,他引:13
浸润性是固体表面的重要性质之一 .决定固体表面的浸润性的两个主要因素中 ,化学性质是内因 ,而几何结构形貌也是不可缺少的重要因素 .通过改变固体表面的粗糙度可以改变其浸润性 [1~ 5] .通常 ,人们用水接触角的大小来衡量固体表面水的浸润性 ,水与固体表面的接触角大于 1 5 相似文献
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