基于医用纱布负载的二氧化锰纳米颗粒用于亚甲蓝染料的去除

以医用纱布（medical gauze,MG）同时作为模板和还原剂,通过原位氧化还原反应,简便地制备了MG负载的MnO₂纳米颗粒（MnO₂ NPs/MG）,并对其形貌、成分进行表征。结果表明,MnO₂ NPs均匀地分散于MG纤维表面。结合MnO₂纳米材料的吸附性能和MG复合材料的操作便捷性,将MnO₂ NPs/MG进一步应用于亚甲蓝染料的去除。结果表明,在中性条件下,通过简单的浸泡搅拌,MnO₂ NPs/MG对亚甲蓝的去除率可达85.09%,并且可以通过增大吸附材料用量与染料初始浓度的比例提高去除率。等温吸附和动力学研究证明,MnO₂ NPs/MG对亚甲蓝的吸附符合Langmuir吸附等温模型和拟二级动力学模型。     

基于医用纱布负载的二氧化锰纳米颗粒用于亚甲蓝染料的去除

以医用纱布(medical gauze,MG)同时作为模板和还原剂,通过原位氧化还原反应,简便地制备了MG负载的MnO₂纳米颗粒(MnO₂ NPs/MG),并对其形貌、成分进行表征。结果表明,MnO₂ NPs均匀地分散于MG纤维表面。结合MnO₂纳米材料的吸附性能和MG复合材料的操作便捷性,将MnO₂ NPs/MG进一步应用于亚甲蓝染料的去除。结果表明,在中性条件下,通过简单的浸泡搅拌,MnO₂ NPs/MG对亚甲蓝的去除率可达85.09%,并且可以通过增大吸附材料用量与染料初始浓度的比例提高去除率。等温吸附和动力学研究证明,MnO₂ NPs/MG对亚甲蓝的吸附符合Langmuir吸附等温模型和拟二级动力学模型。     

Laser induced self-propagating high-temperature synthesis of TiNi alloy

TiNi alloy, especially porous TiNi, a good biocompatible material, can be made by laser induced self-propagating high-temperature synthesis (SHS). A 40-W CO2 laser was used to ignite the powders of Ti and Ni, and TiNi intermetallic compound was synthesized by SHS in a reaction kettle of stainless steel. High-speed photography, X-ray diffraction, and scanning electron microscopy were used to investigate and analyze the reaction process, phase composing, and microstructure of the product, respectively. The influence factors on the reaction process and the product were discussed. The results indicate that laser induced SHS is an efficient, energy-saving method; The phase ingredient of the product consists of TiNi, Ti2Ni, and Ni3Ti. With the increase of the preparing pressure of the sample, the reacting rate decreases; With the increase of the laser power and the preheating temperature, the reacting rate increases. Under the condition of 30℃/min, the synthesis reaction had been carried out consistently and     

多璧碳管/聚中性红修饰电极的制备及对鸟嘌呤和腺嘌呤的应用研究

结合纳米材料的电催化特性和中性红聚合物薄膜的分子识别能力, 以玻碳电极为基体制备了多壁碳管/聚中性红(MWNT/PNR)修饰电极, 并用表面扫描电镜和循环伏安法进行了表征. 实验表明, 该修饰电极对腺嘌呤(A)和鸟嘌呤(G)都表现出了良好的电催化性能. 在最佳条件下, 用示差脉冲伏安法对A和G进行了测定, 其氧化峰电流于A和G的浓度分别在0.01～4 μmol/L和0.01～8 μmol/L范围内呈良好的线性关系, 检测限均为5×10-9 mol/L (S/N=3). 该修饰电极可以用来同时测定DNA中的A和G.     

磷铝分子筛的制备与应用进展

综述了近三年来磷铝分子筛最新的研究进展,包括磷铝分子筛水热法、溶剂热、离子热制备的合成进展,相比传统方式的制备,制备方法有所创新,条件有所优化,成本有所降低,制备出来的结构和形貌也与以往不同。然后分类总结了磷铝分子筛作为催化剂应用,相比以往磷铝分子筛可催化的化学反应变多,制备出来的改性或介孔磷铝分子筛的催化活性变强和使用寿命边长,最后对其的发展前景作了评述。