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基于医用纱布负载的二氧化锰纳米颗粒用于亚甲蓝染料的去除
引用本文:王琦,吴佳娜,武文斌,张亚铃,张继鑫,杨晋宇,王千慧,李生玲,张翠红,丁莉峰,牛宇岚.基于医用纱布负载的二氧化锰纳米颗粒用于亚甲蓝染料的去除[J].无机化学学报,2013,29(18).
作者姓名:王琦  吴佳娜  武文斌  张亚铃  张继鑫  杨晋宇  王千慧  李生玲  张翠红  丁莉峰  牛宇岚
作者单位:太原工业学院化学与化工系, 太原 030008;太原工业学院环境与安全工程系, 太原 030008
基金项目:山西省大学生创新创业训练计划项目(No.S202214101027)、 太原工业学院引进人才科研资助项目(No.2022KJ058)、 山西省高等学校科技创新项目(No.2021L535)和山西省 1331项目资助。
摘    要:以医用纱布(medical gauze,MG)同时作为模板和还原剂,通过原位氧化还原反应,简便地制备了MG负载的MnO2纳米颗粒(MnO2 NPs/MG),并对其形貌、成分进行表征。结果表明,MnO2 NPs均匀地分散于MG纤维表面。结合MnO2纳米材料的吸附性能和MG复合材料的操作便捷性,将MnO2 NPs/MG进一步应用于亚甲蓝染料的去除。结果表明,在中性条件下,通过简单的浸泡搅拌,MnO2 NPs/MG对亚甲蓝的去除率可达85.09%,并且可以通过增大吸附材料用量与染料初始浓度的比例提高去除率。等温吸附和动力学研究证明,MnO2 NPs/MG对亚甲蓝的吸附符合Langmuir吸附等温模型和拟二级动力学模型。

关 键 词:医用纱布  二氧化锰纳米颗粒  亚甲蓝  去除
收稿时间:2023/2/21 0:00:00
修稿时间:2023/6/19 0:00:00

Medical gauze templated manganese dioxide nanoparticles for methylene blue decontamination
WANG Qi,WU Jia-N,WU Wen-Bin,ZHANG Ya-Ling,ZHANG Ji-Xin,YANG Jin-Yu,WANG Qian-Hui,LI Sheng-Ling,ZHANG Cui-Hong,DING Li-Feng,NIU Yu-Lan.Medical gauze templated manganese dioxide nanoparticles for methylene blue decontamination[J].Chinese Journal of Inorganic Chemistry,2013,29(18).
Authors:WANG Qi  WU Jia-N  WU Wen-Bin  ZHANG Ya-Ling  ZHANG Ji-Xin  YANG Jin-Yu  WANG Qian-Hui  LI Sheng-Ling  ZHANG Cui-Hong  DING Li-Feng  NIU Yu-Lan
Institution:Chemistry & Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, 030008, China;Department of Environment and Safety Engineering, Taiyuan Institute of Technology, Taiyuan, 030008, China
Abstract:Using medical gauze (MG) as both template and reductant, MG templated manganese dioxide nanoparticle (MnO2 NPs/MG) was facilely synthesized through an in situ redox reaction. The morphology and composition were characterized. MnO2 NPs were evenly loaded and dispersed on the surface of MG fibers. Combing the adsorption property of MnO2 NPs with ease of operation of MG, MnO2 NPs/MG were further applied to the removal of methylene blue. The results indicated that, by simple soaking and stirring under neutral conditions, the removal efficiency can reach 85.09%, and it can be improved by increasing the ratio of adsorption material dosage to the initial amount of dye. Through isothermal adsorption and kinetic studies, it was proved that the adsorption of methylene blue by MnO2 NPs/MG conformed to Langmuir adsorption isothermal model and pseudo-second-order kinetic model.
Keywords:medical gauze  MnO2 nanoparticles  methylene blue  removal
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