纳米酶

纳米酶(Nanozymes)是由我国科学家首次提出的新概念,它是一类具有生物催化功能的纳米材料,能够基于特定的纳米结构催化天然酶的底物并作为酶的代替品。自2007年首次报道以来,全球已有来自于55个国家的420多个研究机构证实了纳米酶的普遍规律。纳米酶的发现第一次揭示纳米材料蕴含一种独特的纳米效应——类酶催化效应。纳米酶作为一种新材料,既有纳米材料本身的理化性质,又有类似酶的催化功能,兼具天然酶与人工酶的优势于一身。其中,纳米结构不仅赋予纳米酶高效催化功能,而且使纳米酶比天然酶稳定,易于规模化生产。另外,纳米酶独特的多酶活性将为设计廉价、稳定、各种各样全新的催化级联反应提供功能分子。纳米酶是多学科交叉融合的典范,2022年被IUPAC评为十大化学新兴技术。在全球从事化学、酶学、材料学、生物学、医学、理论计算等多领域科学家的共同推进下,如今纳米酶已经成为新的研究热点。我国科学家在这一新兴领域一直发挥着引领作用,解析了纳米酶的构-效关系,将其催化活性提高了约1万倍,实现了超越天然酶的理性设计,创造了全球首个纳米酶产品,出版了纳米酶学英文专著,发布纳米酶术语及中国/国际标准化。更可喜的是,纳...     

Micro-track structure analysis for 100 MeV Si ions in CR-39 by using atomic force microscopy

To analyze the micro-track structure of heavy ions in a polymer material,parameters including bulk etch rate,track etch rate,etch rate ratio,and track core size were measured.The pieces of CR-39 were exposed to 100 MeV Si ions with normal incidence and were etched in 6.25N NaOH solution at 70 C.Bulk etch rate was read out by a profilemeter after several hours of etching.The other parameters were obtained by using an atomic force microscope(AFM)after a short time of etching.We have measured the second etch pits and minute etch pits to obtain the track growth curve and three dimension track structures to track the core size and etch rate measurements.The local dose of the track core was calculated by theδ-ray theory.In our study,we figure out that the bulk etch rate Vb=(1.58±0.022)μm/h,the track etch rate Vt=(2.90±0.529)μm/h,the etch rate ratio V=1.84±0.031,and the track core radii r≈4.65 nm.In the meantime,we find that the micro-track development violates the traditional track-growth model.For this reason,a scenario is carried out to provide an explanation.