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Solvent and electric field dependence of the photocurrent generation in donor:acceptor blend system 下载免费PDF全文
This paper reports that the blend films of poly
(2-methoxy-5-(2'-ethyl-hexyloxy)-p-phenylene vinylene) (MEH-PPV)
and N,N'-bis(1-ethylpropyl)-3,4: 9,10-perylene bis
(tetracarboxyl diimide) (EP-PDI) with the weight ratio of 1:2.5
have been prepared by spin-coating from chloroform (CF) and
chlorobenzene (CB) solutions respectively. The absorption
spectra and the morphology of the blend films show that large
crystal-like EP-PDI aggregates are formed in film prepared from
CB solution, which corresponds to a new absorption shoulder near
590nm, while there is no shoulder around 590\,nm in the
UV--Vis absorption spectra of the blend film from CF solution.
The electric-field dependence spectra of the photocurrent
generation quantum yield of the film from CB solution shows that
at weak electric field the EP-PDI aggregates act as more
efficient sensitizers, but at strong electric field the quantum
yields become almost invariable over the entire spectral range
no matter what the state of EP-PDI, monomer or aggregate. At
strong electric field, the photocurrent generation yields of
both films from CF and CB solution saturate and their yield
spectra become spectrally similar, mentioning that at strong
electric field the photoexcitons dissociate efficiently and the
free charges are collected by the electrodes almost completely. 相似文献
2.
研究了不同比例的PVK与齐聚PPV衍生物DBVP掺杂体系的能量转移和发光特性.通过对PVK,DBVP及PVK:DBVP掺杂体系的UV-vis,PL和PLE光谱的研究,分析了PVK与DBVP之间的能量转移过程.利用PVK在体系中类似于溶剂的分散作用,制备了结构为ITO/PEDOT/PVK:DBVP/LiF/Al的电致发光器件,研究了掺杂体系的电致发光性能.结果表明,在掺杂体系的光致发光和电致发光中,PVK的发射被有效地抑制,PVK与DBVP之间发生了非常有效的能量转移,通过调节PVK与DBVP的比例,可以获得蓝色和绿色发光,同时可以改善器件的发光性能,当PVK与DBVP的重量比为1∶2时,器件的绿色发光效率达到1·06cd/A,此时发光亮度为52cd/m2. 相似文献
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4.
研究了不同溶剂对2-甲氧基-5-(2-乙基己氧基)-1,4-对苯撑乙烯(MEH-PPV):N,N′-二(1-乙基丙基)-3,4,9,10-四羧酸二亚酰胺(EP-PTC)复合膜的形貌及其对以MEH-PPV:EP-PTC复合膜为活性层的太阳电池性能的影响.结果表明:非芳香性溶剂不利于MEH-PPV与EP-PTC的相容,MEH-PPV与EP-PTC两相间形成微米尺寸(0.5—5μm)的相分离,因而以MEH-PPV:EP-PTC复合膜为活性层的太阳电池中的电荷分离效率较低,进而电池的能量转换效率较低.而芳香性溶剂有利于MEH-PPV与EP-PTC的相容,MEH-PPV与EP-PTC两相间能形成纳米尺度的相分离,因此MEH-PPV与EP-PTC两相间的界面面积明显增加,界面处的电荷分离概率明显提高.与非芳香性溶剂相比,基于芳香性溶剂的复合膜太阳电池的能量转换效率提高了20倍. 相似文献
5.
X-shape oligo(thiophene)s as donor materials for vacuum-deposited organic photovoltaic cells 下载免费PDF全文
The films of two x-shape oligo(thiophene)s, 3, 4-dibithienyl-2, 5-dithienylthiophene (7T) and 2, 5-dibithienyl-3, 4- ditrithienylthiophene (11T), which are prepared by vacuum evaporation, have been investigated as novel electron donor layers in two-layer photovoltaic cells. UV-Vis absorptions show red-shifted and broadened absorptions of the vacuumevaporated films as compared with those of the corresponding solutions and spin-coating films, which is beneficial for photovoltaic properties. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) measurements show that the vacuum-evaporated films are almost amorphous. Two-layer photovoltaic cells have been realized by the thermal evaporation of 7T and llT as donors and N, N′-bis(1-ethylpropyl)-3, 4:9,10-perylene bis(tetracarboxyl diimide) (EP- PTC) as an acceptor. An energy conversion efficiency (ECE) of 0.18% of the cell based on 7T with an irradiation of white light at 100 mw/cm^2 has been demonstrated by the measurements of current (I)- voltage (V) curves of the cells to be higher than the ECE of the reference system based on donor dihexylterthienyl (H3T) that is linear and without α, β linkage. 相似文献
6.
研究了不同溶剂对2-甲氧基-5-(2-乙基己氧基)-1,4-对苯撑乙烯(MEH-PPV): N,N′-二(1-乙基丙基)-3,4,9,10-苝四羧酸二亚酰胺(EP-PTC)复合膜的形貌及其对以MEH-PPV: EP-PTC复合膜为活性层的太阳电池性能的影响.结果表明:非芳香性溶剂不利于MEH-PPV与EP-PTC的相容,MEH-PPV与EP-PTC两相间形成微米尺寸(0.5—5 μm)的相分离,因而以MEH-PPV: EP-PTC复合膜为活性层的太阳电池中的电荷分离效率较低,进而电池的能量转换效率较低.而
关键词:
太阳电池
相分离
能量转换效率 相似文献
7.
噻吩低聚物能级结构的量子化学研究 总被引:2,自引:0,他引:2
用量子化学方法计算了系列EDOT低聚物的紫外-可见吸收光谱和前线分子轨道,得到了相应的能级结构参数.与实验值进行对比发现,计算值与实验值具有相同的变化趋势.计算结果表明,通过选择性地改变共轭主链的长度、取代基的位置和取代基的类型,可以规律性地改变化合物光谱性质和能级结构. 相似文献
8.
研究了不同比例的PVK与齐聚PPV衍生物DBVP掺杂体系的能量转移和发光特性.通过对PVK,DBVP及PVK: DBVP掺杂体系的UV-vis,PL和PLE光谱的研究,分析了PVK与DBVP之间的能量转移过程.利用PVK在体系中类似于溶剂的分散作用,制备了结构为ITO/PEDOT/PVK: DBVP/LiF/Al的电致发光器件,研究了掺杂体系的电致发光性能.结果表明,在掺杂体系的光致发光和电致发光中,PVK的发射被有效地抑制,PVK与DBVP之间发生了非常有效的能量转移,通过调节PVK与DBVP的比例,可以获得蓝色和绿色发光,同时可以改善器件的发光性能,当PVK与DBVP的重量比为1∶2时,器件的绿色发光效率达到1.06cd/A,此时发光亮度为52cd/m2. 相似文献
9.
PVK与新型D-π-A分子掺杂体系的能量转移及发光性质 总被引:1,自引:0,他引:1
通过对PVK与4种新型D-π-A分子(分别简写为CKD, TKD, PKD, NKD)掺杂体系的吸收光谱、激发光谱和光致发光光谱的研究, 分析了掺杂体系的光致发光特性和能量转移现象. 制备了结构为ITO/PEDOT/PVK∶D-π-A ω/Alq3/Al的电致发光器件, 研究了掺杂体系的电致发光性能. 研究结果表明, 通过改变D-π-A分子中不同给电子能力的电子给体, 可以调控其带隙, 进而实现对D-π-A分子发光峰位的调节; 给电子基团空间立构效应越高, 其荧光量子效率越高. 在掺杂体系的光致发光和电致发光中, PVK与D-π-A分子之间都发生了有效的能量转移, 通过调节PVK与D-π-A分子的比例, 可以调节掺杂体系的发光性能. 当TKD在PVK中的掺杂质量分数为6%时, 电致发光器件发光亮度为729.1 cd/m2时, 发光效率达到1.75 cd/A. 相似文献
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