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Pore structure of the porous polydivinylbenzene microspheres is controlled by the degreeof crosslinkage and the diluent used. It is proved by chromatographic results that the higher thedegree of crosslinkage is, the more the micellar pores will be formed, and the nature as wellas the quantity of the diluent determine the real pore structure. Among the structural para-meters of the microspheres, the size and the pore diameter affect the performance in HPLCmostly. The linear sample capacity of the microspheres in 1--2 order of magnitude larger thanthat of the Silica-ODS. According to this result, it could be confirmed that the solute mole-cules penetrate deeply into the skeleton of the polymer network. Based on the polymeric struc-ture with the same chemical composition but different in pore structure, the contribution tothe retention of several organic compounds by Henry's and/or adsorption coefficient has beenstudied. The results obtained show that Henry's coefficient is approximately 80% of thetotal contribution, i. e. dissolution mechanism plays the main role in the chromatographicprocess, especially in case of polar compounds. The experimental result that the chroma-tographic separation relatively slightly depends upon the sueface area of the polymer isanother ovidence. It is better to define this kind of polymeric stationary phase as a sorbentrather than an adsorbent. From the point of view of dissolution mechanism, it is suggestedthat a homogeneous porous polymeric stationary phase constructed with chemically rigid ske-letal structure and sufficiently thin bulk polymeric phase inside the microspheres should bean ideal packing for chromatography. 相似文献
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聚二乙烯苯多孔微球的孔结构受控于交联度及稀释剂,从色谱方法证明交联度高对形成微束孔有利,而稀释剂的质和量则决定真孔的性质。微球的结构参数中以微球的尺寸及孔径对高效液相色谱性能影响较大。微球的试样线性容量比十八烷基硅氧烷键合硅胶大1—2个数量级,说明溶质分子是扩散进入到高分子骨架中的。文中以化学组成相同、孔结构不同的聚二乙烯苯微球为基础,研究了溶解及吸附对几种有机化合物的保留值的贡献,对极性溶质来说,溶解系数约占总贡献的80%。从许多实验结果也说明此类固定相的比表面对色谱的分离度贡献不大。因此称此种固定相为吸着剂较称之为吸附剂更好。可以设想,具有刚性骨架的高分子组成、高分子本体相又足够薄的均匀多孔微球将是一种较理想的固定相。 相似文献
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