Synthesis,Photo-physical Properties and Cell Imaging of Meso-2,6-dichlorophenyl Boron-dipyrromethene Derivatives

The meso-2,6-dichlorophenyl boron-dipyrromethene(BODIPY) derivative 1 was synthesized and characterized by single-crystal X-ray diffraction analysis, 1 H NMR and Esi-HRMS. Compound 1 crystallizes in monoclinic, space group P21/n with a = 8.717(4), b = 20.938(9), c = 12.402(6) ?, β = 98.660(7)°, V = 2237.7(17) ?3, D3 c = 1.333 Mg/cm, F(000) = 936, μ = 0.319 –mm1, Z = 4, the final R = 0.0537 and wR = 0.1556 for 5064 observed reflections with I 2ζ(I). Its photophysical properties were investigated by fluorescence and UV-Vis spectrum. 1 shows high fluorescence quantum yield in different solvents and poor solvent effect. In addition, compound 1 has high values of initial decomposition temperature(298 ℃). Moreover, cell imaging experiments showed 1 is promising for further bioimaging applications.     

基于金纳米粒子增强有机-无机杂化钙钛矿放大自发辐射

有机-无机杂化钙钛矿作为激光的增益介质时,存在室温时纳秒脉冲或连续激光作用下的光泵浦器件不稳定、难以实现电泵浦激光等问题.通过将金纳米粒子水溶液和PEDOT∶PSS溶液共混的方法,将20nm尺寸的金纳米粒子掺杂至光泵浦平面波导器件的界面层PEDOT∶PSS中,掺杂了金纳米粒子的平面波导器件(以CH_3NH_3PbBr_3为增益介质)的放大自发辐射绝对强度相对于没掺杂金纳米粒子的器件提升了5.5倍.实验结果表明,金纳米粒子的引入,一方面提升了CH3NH3PbBr3薄膜的吸收,增加了粒子反转数目,另一方面加快了激发态激子的辐射跃迁速率.仿真分析表明,金纳米粒子的近场和远场复合表面等离激元可有效耦合增益介质光吸收/发射主区域,从而提高了平面波导器件的放大自发辐射性能.研究结果可为高效泵浦激光的实现提供参考.     

ZnS与SiO_2材料的短脉冲激光热损伤特性比较

对SiO2和ZnS这两种常用的红外光学材料在红外短脉冲激光辐照下的热损伤特性进行了研究,分析了相同激光辐照条件下两种材料的热效应,另外也针对同种材料不同辐照条件下的热效应进行比较。分析结果表明:红外激光作用下,SiO2材料的表面温升快于ZnS材料,而在材料内部,则后者快于前者。脉冲辐照结束时SiO2材料的表面峰值温度高于ZnS材料,但ZnS材料产生温升的深度大于SiO2材料。由于能量更为集中,材料在皮秒激光作用下温升高于纳秒激光作用下的温升。若材料的峰值温度达到熔点,则激光的单脉冲能量随脉冲宽度的减小呈非线性减小趋势,且变化率越来越大。     

光子晶体光纤中超连续谱的研究进展与应用

利用光子晶体光纤(photonic crystal fiber,PCF)产生超连续光谱是目前光通信光电子器件领域的一个研究热点,文章系统地介绍了石英光子晶体光纤和非石英软玻璃光子晶体光纤中产生超连续谱的理论和实验研究成果.对于石英光子晶体光纤主要介绍了实芯光子晶体光纤、空芯填充光子晶体光纤和锥形光子晶体光纤产生超连续谱的研究成果,分类介绍了其超连续谱产生的特点.对于非石英光子晶体光纤主要介绍了某些铅硅酸盐玻璃和亚碲酸盐玻璃光子晶体光纤超连续谱产生的特点.最后介绍了超连续谱的应用和发展前景.     

绝缘衬底上硅表面载流子的超快动力学研究

利用800 nm波长的飞秒抽运探测技术测量r具有不同单晶硅薄膜厚度的绝缘衬底上硅(SOI)皮秒瞬态反射率变化,并通过基于受激载流子密度和温度变化过程建立的反射率模型讨论了SOI表面载流子的超快动力学过程.研究表明,表面复合速度(SRV)是影响载流子动力学响应的主要因素,且薄膜厚度越小表面复合速度就越大,对应的表面态密度可达到1013cm-2 .对于较小的SRV,受激载流子的超快响应决定了瞬念反射率变化;而对于较大的SRV,晶格温升对瞬态反射率变化的贞献变得显著,使得反射率在更短的时间内恢复并超过初始值.     

Wave breaking in tapered holey fibers

We numerically study the propagation of 1-ps laser pulse in three tapered holey fibers (THFs).The curvature indices of the concave,linear,and convex tapers are 2.0,1.0,and 0.5,respectively.The central wavelength,located in the normal dispersion regime,is 800 nm.The nonlinear coefficient of the THFs increases from the initial 0.095 m-1· W-1 to the final 0.349 m-1·W-1.Wave breaking accompanied by oscillatory structures occurs near pulse edges,and sidelobes appear in the pulse spectrum.With the increase in propagation distance z,the pulse shape becomes broader and the pulse spectrum flattens.A concave THF is advantageous to the generation of wave breaking and enables easier achievement of super flat spectra at short lengths.     

化学气相沉积法制备氧化镓纳米线

β-Ga2O3纳米线是一种新型具有强发光特性的宽带隙半导体材料,作为探测器性能稳定巨可靠,近年来受到了极大的关注.本文主要采用化学气相沉积法(CVD),以Ag纳米颗粒为催化剂,在Si(100)衬底上生长了β-Ga2O3纳米线,经EDS、SEM、TEM等技术表征,证明其大部分遵循VLS生长机理,少许遵循VS机制.其中遵循 VLS 生长机制的β-Ga2O3纳米线更细更长,其形貌均匀一致,长度约为230～260 μm,直径约为150～180 nm,巨Ag颗粒皆在纳米线顶部.     

中红外高保偏硫系玻璃双芯光子晶体光纤耦合特性研究

设计了一种中红外硫系玻璃双芯光子晶体光纤,利用多极法和模式耦合基本理论研究了这种光纤的耦合特性.数值模拟发现,空气孔间距Λ = 5.4 μm,空气孔半径为r = 1.35 μm,空气填充率d/Λ = 0.5的光纤,在归一化波长λ/Λ = 2.04 μm处双折射可以达到0.551×10^-2,在归一化波长λ/Λ = 0.93 μm处x偏振方向的耦合长度为145.32 μm,y偏振方向的耦合长 关键词： 双芯光子晶体光纤 硫系玻璃 双折射 耦合长度     

Nonvolatile two-color holographic recording in near-stoichiometric lithium niobate crystals gated by incoherent ultraviolet light

Nonvolatile two-color holographic recording gated by incoherent ultraviolet （UV） light centered at 365 nm is investigated in near-stoichiometric lithium niobate crystals. The influence of thermal treatment on the two-color recording is studied. The results show that thermal reduction tends to improve the two-color recording performance, whereas thermal oxidation degrades the two-color recording. With an incoherent 0.2-W/cm2 UV gating light and a 0.25-W/cm2 semiconductor recording laser at 780 nm, a two-color recording sensitivity of 4 × 10^-3 cm/J and a recording dynamic range characterized by M/# of 0.12 are achieved in a 2.2-mm thermally reduced near-stoichiometric lithium niobate crystal. We attribute the improvement to the prolonged lifetime of small polarons and the increased absorption at the gating wavelength due to thermal reduction.     

基于TMS320C6711的光纤陀螺闭环数字信号处理系统的开发

提出了一种以TI公司的TMS320C6711处理器为基础的有工程意义的闭环光纤陀螺信号处理方案。介绍了闭环光纤陀螺系统的原理和检测方法。对ADC和DAC的选择进行了理论分析,对闭环光纤陀螺数字处理系统的硬件和软件进行了设计。使用了高效的McBSP口与外围ADC,DAC通信,利用JATG口实时监控DSP的工作过程,并升级了程序。针对陀螺系统所要求的实时性开发了能够满足精度要求的高效数字滤波算法。