均匀沉淀法制备Co(OH)2及其超电容特性

以氯化钴为原料、氨水(28wt%)为沉淀剂采用均匀沉淀法成功地合成了Co(OH)₂。X-射线衍射(XRD)、扫描电镜(SEM)测试表明，表面活性剂Tween-80的加入使所制备的α-Co(OH)₂呈现出类似花朵的形貌;循环伏安、恒电流充放电、交流阻抗和循环寿命等电化学测试表明，该材料的电化学性能也得到一定的提高，其单电极比电容可达到370 F·g^-1。     

锂离子二次电池电解质材料LiPF6的制备及表征

0引言 液态锂离子电池自1990年开发成功以来,由于具有比能量高、工作电压高、应用温度范围宽、自放电率低、循环寿命长、无污染、安全性能好等许多独特的优势[1],所以其发展前景十分广阔.目前液态锂离子二次电池中开发使用的无机阴离子导电盐主要有LiClO4、LiPF6、LiAsF6等,但LiClO4为强氧化剂,使用不安全而不宜用于电池,LiAsF6虽然性能颇佳,但有毒且价格较贵,故也不宜广泛使用.LiPF6被认为是目前较合适的电解质[1],但其制备困难,价格较贵,且目前报道的合成方法也多是以HF为介质[2～5].本文作者以PF5和LiF为原料在CH3CN溶剂中简单有效地合成了高纯LiPF6,并通过在手套箱中制样的方法对目标产物进行了红外、热重和X射线衍射分析,给出了LiPF6的红外光谱图、热重分析数据和X射线衍射图.     

Wigner function for the generalized excited pair coherent state

This paper introduces the generalized excited pair coherent state （GEPCS）. Using the entangled state 〈η〉 representation of Wigner operator, it obtains the Wigner function for the GEPCS. In the ρ-γ phase space, the variations of the Wigner function distributions with the parameters q, α, k and l are discussed. The tomogram of the GEPCS is calculated with the help of the Radon transform between the Wigner operator and the projection operator of the entangled state ｜η1, η2, τ1, τ2｜. The entangled states ｜η〉 and ｜η1, η2, τ1, τ2〉 provide two good representative space for studying the Wigner functions and tomograms of various two-mode correlated quantum states.     

量子比特的普适远程翻转和克隆

提出一种把量子隐形传态、最佳普适量子比特翻转和最佳普适量子克隆三者结合起来的量子比特普适远程翻转和克隆方案.当发送者和处于不同地点的三个接收者共享一个特定的四粒子纠缠态作为量子信道时,通过发送者的Bell基测量、经典通信和各个接收者的局域幺正变换,一个接收者能够以2/3的最佳保真度得到一份原未知量子比特的正交补态,另外两个接收者能够分别以5/6的最佳保真度得到原未知量子比特的一份拷贝.此方案用较少的量子纠缠资源同时完成了未知量子比特的普适远程翻转和克隆,且其保真度分别达到了最佳.实现此方案的关键在于构造出发送者和接收者共享的特定四粒子纠缠态作为量子信道,分析了此特殊四粒子态内在的纠缠结构.     

新的奇偶非线性相干态及其非经典性质

构造出了一种新的奇偶非线性相干态, 并借助于数值计算方法研究了它们的压缩、振幅平方压缩、反聚束和相位概率分布等非经典性质. 结果表明, 与通常的奇偶相干态和非线性奇偶相干态不同, 在参数|λ|的不同取值范围内, 新的奇偶非线性相干态在Y₁和Y₂两个方向均可呈现振幅平方压缩效应, 而压缩效应仅在偶非线性相干态的X₂方向上呈现, 反聚束效应仅在奇非线性相干态中呈现. 另外, 通过研究新的奇偶非线性相干态相位概率分布, 发现新的奇偶非线性相干态具有完全不同的量子干涉特性. 关键词： 新的奇偶非线性相干态 压缩效应 反聚束 相位概率分布     

双奇核142Pm高自旋态能级纲图

利用能量为75—95MeV19F束流,通过反应¹²⁸Te(¹⁹F,5nγ)¹⁴²Pm研究了双奇核¹⁴²Pm的高自旋态能级结构.实验中进行了γ射线的激发函数、γ射线单谱和γγ符合测量.建立了激发能达7030.0keV的¹⁴²Pm的能级纲图,其中包括新发现的25条γ射线和13个新能级.基于实验测量的γ跃迁各向异性度,建议了¹⁴²Pm能级的自旋值.     

Six-step synthesis of Leonurine and toxicity study on zebrafish

Leonurine (1), an important ingredient in leonurus sibiricus L., can be used for some gynecological disease. We have developed a concise and efficient synthetic route of Leonurine, which can be optimized for mass production. Commercially available compound 6 and 2,3-dihydrofuran (7) were used as starting materials. And the toxicity study on zebrafish shows that Leonurine would promote the hatching of zebrafish embryos at low concentration and result in acute death or chronic lethal toxicity at high concentration.     

Synthesis of fully substituted polyhydroxylated pyrrolizidines via Cope-House cyclization

Total synthesis of the proposed structure of (-)-hyacinthacine C(5) and its epimers at C6 and C7 is described. A key step of the synthesis was the construction of the bicyclic pyrrolizidine system by means of a nucleophilic addition of a dithiane to a cyclic nitrone followed by a Cope-House cyclization.     

Investigation of add-back effects in a segmented Clover detector

The resolution and the summing characteristics of an EXOGAM segmented Clover germanium detector has been studied for use it in y spectroscopic experiments. The measurements have been performed with standard radioactive sources of ^152Eu, ^133Ba and β-delayed γ-rays from 176Ir decay. The data analytic results, realized by software, are presented in this paper.     

Number-Phase Quantization and Deriving Energy-Level Gap of Two LC Circuits with Mutual-Inductance

For two LC circuits with mutual-inductance, we introduce a new quantization scheme in the context of number- phase quantization through the standard Lagrangian formalism. The commutative relation between the charge operator and the magnetic flux operator is derived. Then we use the Heisenberg equation of motion to obtain the current and voltage equation across the inductance and capacity. The results clearly show how the current and voltage in a single LC circuit are affected by the circuit parameters and inductance coupling coettlcient. In addition, adopting invariant eigen-operator method the energy-level gap of the dynamic Hamiltonian which describes two LC circuits with mutual-inductance is obtained.