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应用薄层循环伏安法研究了硝基苯/水两相界面间,且有共同离子四丁基铵TBA+存在于两相中,在有机相中的四氰化二甲基苯醌(TCNQ)与水相中的K4Fe(CN)6之间发生的反向电子转移反应。在直径为0.64cm的裂解石墨电极上用2μL硝基苯溶液使之自然扩散在电极表面形成薄层的有机相,并以此作为工作电极。对电极为铂丝(0.5mm),参比电极为Ag/AgCl电极,均置于总体积为2mL的水相中。由于共同离子TBA+的诱导,在硝基苯/水界面间,在已氧化的TCNQ+阳离子(在有机相中)与[Fe(CN)6]4-阴离子(在水相中)之间发生了反向电子转移反应。试验证明:在一定条件下,通过改变两相中共同离子的浓度,可使一些不能发生的两相界面的电子转移反应得以发生;这类电子转移反应系受界面电位差所控制。此外,还测得了在恒定的共同离子浓度比值的条件下,此两相界面电子转移反应的表观速率常数(k)为0.135cm.s-1.mol-1。 相似文献
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GULI Mi-na CHEN Yu-ning LI Xiao-tian . Solar Energy Center Renewable Energy School North China Electric Power University Beijing P. R. China . Key Laboratory of Automobile Materials of Ministry of Education College of Materials Science Engineering Jilin University Changchun 《高等学校化学研究》2011,(3):350-353
Mesoporous titanium dioxide spheres were synthesized by a convenient solvothermal method at room temperature with tetraethyl titanate as a precursor. Investigation by means of X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), and N2 adsorption-desorption isotherms confirms that the sample has a mesostructure with a higher specific surface area and shows that the mesoporous TiO2 spheres have a diameter of 2 μm, the average pore size is about 5.9 nm, and the BET... 相似文献
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Mi-na Jiang~ Yan-ling Xu~ Laboratory of Nonlinear Analysis Department of Mathematics Central China Normal University Wuhan China Department of Information Computer Science College of Science Huazhong Agriculture University Wuhan China 《应用数学学报(英文版)》2005,21(1):31-42
We investigate the asymptotic behavior of solutions of the initial-boundary value problem for the generalized BBM-Burgers equation u_t f(u)_x=u_(xx) u_(xx) on the half line with the conditions u(0, t)=, u-, u(∞,t)=u_ and, u_-相似文献
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