Surface of room temperature ionic liquid [bmim][PF6] studied by polarization- and experimental configuration-dependent sum frequency generation vibrational spectroscopy

Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface.     

Surface modification of polyolefin separators for lithium ion batteries to reduce thermal shrinkage without thickness increase

Surface chemical modification of polyolefin separators for lithium ion batteries is attempted to reduce the thermal shrinkage, which is important for the battery energy density. In this study, we grafted organic/inorganic hybrid crosslinked networks on the separators, simply by grafting polymerization and condensation reaction. The considerable silicon-oxygen crosslinked heat-resistance networks are responsible for the reduced thermal shrinkage. The strong chemical bonds between networks and separators promise enough mechanical support even at high temperature. The shrinkage at 150 C for 30 min in the mechanical direction was 38.6% and 4.6% for the pristine and present graft-modified separators, respectively. Meanwhile, the grafting organic-inorganic hybrid crosslink networks mainly occupied part of void in the internal pores of the separators, so the thicknesses of the graft-modified separators were similar with the pristine one. The half cells prepared with the modified separators exhibited almost identical electrochemical properties to those with the commercial separators, thus proving that, in order to enhance the thermal stability of lithium ion battery, this kind of grafting-modified separators may be a better alternative to conventional silica nanoparticle layers-coated polyolefin separators.     

Ratiometric mode with dyads: a breakthrough in dynamic trapping and quantification for redox regulation in living cells

Redox-based post-translational modification of protein thiols has become an attractive strategy in cellular homeostasis and cell signaling.Due to the reductive end of the redox buffer network,the vicinal dithiol-containing proteins(VDPs)maintains an appropriate oxidation-reduction state of proteins through the reversible transformation from vicinal dithiols to disulfide,which is responsible for a variety of     

Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions

We report a convenient and practical method for the preparation of nonexplosive cyclic hypervalent iodine(III) oxidants as efficient organocatalysts and reagents for various reactions using Oxone^® in aqueous solution under mild conditions at room temperature. The thus obtained 2-iodosobenzoic acids (IBAs) could be used as precursors of other cyclic organoiodine(III) derivatives by the solvolytic derivatization of the hydroxy group under mild conditions of 80 °C or lower temperature. These sequential procedures are highly reliable to selectively afford cyclic hypervalent iodine compounds in excellent yields without contamination by hazardous pentavalent iodine(III) compound.     

低温等离子体物理进展

概述了低温等离子体物理研究现状、发展及其应用     

微机械陀螺的发展现状

随着对微电子机械系统(MEMS)的深入研究和取得的进展,属于MEMS研究内容之一的微机械陀螺,在汽车工业需求的推动下,已经成为过去几十年内广泛研究和发展的主题.微机械陀螺与传统机械式陀螺、固体陀螺、光学陀螺等相比,具有成本低、尺寸小、重量轻、可靠性高等优点,其精度正不断得到提高,应用领域也随之不断扩大.本文首先简要介绍了微机械陀螺的定义及特征、性能指标、工作原理、分类以及加工技术,随后对已出现的不同类型微机械陀螺的结构、加工方式、工作原理以及性能进行了综述,最后对微机械陀螺的商业化现状以及发展趋势进行了展望.     

FINITE ELEMENTAN ALYSIS FOR THE UNSTEADY NEARSHORECIR CULATION DUE TO WAVE－CURRENT INTER－ACTION（I）──NUMERICAL MODEL

ＦＩＮＩＴＥＥＬＥＭＥＮＴＡＮＡＬＹＳＩＳＦＯＲＴＨＥＵＮＳＴＥＡＤＹＮＥＡＲＳＨＯＲＥＣＩＲＣＵＬＡＴＩＯＮＤＵＥＴＯＷＡＶＥ－ＣＵＲＲＥＮＴＩＮＴＥＲ－ＡＣＴＩＯＮ（Ｉ）——ＮＵＭＥＲＩＣＡＬＭＯＤＥＬＷｕＷｅｉ－ｘｉｏｎｇ（吴伟雄）（Ｔｏｎｇｊ...     

一种新颖的光纤应力传感器

基于模体积失配效应与微弯原理，提出了一种新颖的强度型光纤应力传感器，其传输光功率变化与应力之间近似为线性关系，重复性好，无迟滞现象     

水平井变质量流研究进展

综述了水平井筒沿管壁具有流体流入的变质量流动的最新研究 进展.内容包括:考虑油藏流体流入时井筒流动压力及产量的计算,具 有不同流入时管壁摩擦系数的经验计算公式,以及流体径向流入井筒 后流动阻力损失产生的机理分析等.重点介绍了水平井筒变质量流动 阻力系数的计算,同时文中还介绍了井筒两相变质量流动损失产生的 机理和数值模拟研究进展.     

用曲线大窗口平滑散斑条纹图的方法研究

提出一种计算条纹方向的简单算法,以及通过条纹方向图获得沿条纹方向的曲线窗口并对散斑条纹图进行曲线大窗口滤波的方法．实验表明此方法较好地消除了散斑条纹图的噪声,同时尽量减小了对条纹结构的损害．为从单幅散斑条纹图中应用条纹中心线法或全灰度法进一步提取相位场的后处理,奠定了良好的基础．