Properties of large-scale TIDs observed in Central China

This paper investigates the large scale travelling ionospheric disturbances (LSTIDs) using the observation data of an HF Doppler array located in Central China. The data observed in a high solar activity year (year 1989) are analyzed to obtain the main propagation parameters of LSTIDs such as period, horizontal phase velocity and propagating direction. Results are outlined as follows: Most of the LSTIDs propagate southward; others tend to propagate northward, mostly in summer; dispersion of most LSTIDs is matched with that of Lamb pseudomode, while others have the dispersion of long period gravity wave mode. The horizontal phase velocities of these two modes are about 220 and 450 m/s respectively. The analysis shows that LSTIDs are strongly pertinent to solar activity and space magnetic storms; thus the results presented here are significant for the research of ionospheric weather in mid-low latitude region.     

2,3,8,9-四氢吡啶并[2,3-d:6,5-d’]二嘧啶-4,6-二酮衍生物的合成

以丙二腈、原羧酸三乙酯、吡啶为起始原料经环化、氨解,然后与酮在甲醇钠催化下反应得到了2,3,8,9-四氢吡啶并[2,3-d:6,5-d’]二嘧啶-4,6-二酮衍生物.目标产物的结构经IR,NMR,ESI和元素分析确证.     

Low latitude ionospheric effects near longitude 120°E during the great geomagnetic storm of July 2000

A great geomagnetic storm occurred on July 15/16, 2000 with a minimum value of about -300 nT in Dst index. Collecting digisonde data from ionospheric stations at Chungli, Wuhan, Kokubunji and Anyang, the ionospheric responses at the low latitudes near longitude 120(E during this storm are analyzed in this paper. There was a strong negative phase storm at low latitudes on July 16. The G-condition in the ionograms was clearly seen on the early first day after the commencement of geomagnetic storm. Those were considered to be caused by the storm-induced increase in the concentration ratios of neutral molecular O2 or N2 to atom O. On July 17 and some days thereafter, a positive phase storm appeared. In addition, anomalous equatorial ionization anomaly (EIA) inhibitions and developments were observed on July 16 and 17. There were also prominent nighttime enhancements in foF2 during these days, and the diurnal variation of foF2 was less clear than before.     

柱状金属锂沉积物:电解液添加剂的影响

二次电池的能量密度已成为推动电动汽车和便携式电子产品技术向前发展的重要指标。使用石墨负极的锂离子电池正接近其理论能量密度的天花板,但仍难以满足高端储能设备的需求。金属锂负极因其极高的理论比容量和极低的电极电位,受到了广泛关注。然而,锂沉积过程中枝晶的生长会导致电池安全性差等问题。电解液对金属锂的沉积有着至关重要的影响。本文设计了一种独特的电解槽体系来进行柱状锂的沉积,研究了不同电解液体系(1mol·L^-1LiPF6-碳酸乙烯酯/碳酸二乙酯(EC/DEC,体积比为1:1)、1 mol·L^-1 LiPF6-氟代碳酸乙烯酯(FEC,体积分数5%)-EC/DEC (体积比为1:1))对金属锂沉积的影响。对两种电解液中金属锂沉积物长径比的研究表明,电解液的组分可以显著地影响金属锂的沉积形貌,在加入氟代碳酸乙烯酯(FEC)添加剂之后,柱状锂的直径从0.3–0.6μm增加到0.7–1.3μm,长径比从12.5下降到5.6。长径比的降低有助于减小金属锂和电解液的反应面积,提高金属锂负极的利用率和循环寿命。通过考察循环后锂片的表面化学性质,发现FEC的分解增加了锂表面固态电解质界面层中氟化锂(LiF)组分的比例,提高了界面层中锂离子的扩散速率,减少了锂的成核位点,从而给予锂核更大的生长空间,降低了沉积出的柱状锂的长径比。     

基于局部高盐界面润湿策略构筑的固态金属锂软包电池

固态金属锂电池因其优异的安全性和高的理论能量密度被认为是最具前景的下一代储能电池体系之一。随着以硫化物为代表的高离子导率电解质被逐渐开发,金属锂与固态电解质界面成为限制固态电池应用的主要瓶颈。金属锂/电解质的固固界面存在着界面接触差、界面电荷传输阻力高等问题。本文以固态金属锂软包电池为研究对象,通过由1,1,2,2-四氟乙基-2,2,3,3-四氟丙基醚、乙二醇二甲醚与双三氟磺酰亚胺锂组成的局部高盐液态电解液(HFE-DME LiTFSI)对金属锂/固态电解质界面进行润湿,增加金属锂与固态电解质之间的离子接触,降低离子传输阻力,从而提高锂离子在界面的传输能力。在30 mm×30 mm Li|Li4Ti5O12(LTO)固态软包电池中,通过3.0μL·cm^?2 HFE-DME LiTFSI局部高盐液态电解液润湿金属锂与固态电解质界面,软包电池的界面电阻从4366Ω·cm^?2降低到了64Ω·cm^?2。在0.1C与0.5C倍率下,LTO的放电比容量分别达到107与96 mAh·g^?1。同时,Li-S固态软包电池在0.01C及0.02C下,比容量也达到了1100与932 mAh·g^?1。     

The sudden increase in ionospheric total electron content caused by the very intense solar flare on July 14, 2000

The present paper studies the sudden increase in total electron content (SITEC) on the ionosphere caused by the very intense solar flare on July 14, 2000. According to the well-known Chapman theory of ionization, we derive the relationship between the temporal variation rate, of the total electron content (TEC) and the flare parameters. It is shown that is proportional to the effective flare radiation flux, If, and inversely proportional to the Chapman function, ch(χ), of the zenith angle χ. TEC data observed by the GPS networks located in China, Southeast Asia and Australia during the very intense solar flare on July 14, 2000 are used to statistically investigate the relation between the observed and ch(χ). The analyses show that the two quantities are inversely proportional to each other, as the theory predicted. The present work shows that GPS observation is a powerful tool for studying solar flare effects on the ionosphere, I.e. The sudden ionospheric disturbances (SIDs). Because of its advantages of high precision, large geographical distribution and good temporal resolution, GPS TEC observation may reveal quantitatively the process of ionospheric disturbances caused by solar flares. Therefore, our results are of significance in the space weather research.     

各向异性磁化等离子体的SO-FDTD算法

给出了一种新的计算各向异性磁化色散介质的有限差分(FDTD)算法，称为移位算子FDTD(SO-FDTD)算法，它利用算子之间的移位递推关系，将一类色散介质的包含介电常数的表达式写成有理分式函数形式，进而导出FDTD中一系列相关量之间的关系.通过计算各向异性等离子体平板对电磁波的反射系数和透射系数，验证了该算法的高效性和高精度，与JEC算法相比，可使计算效率提高数倍. 关键词： 磁化等离子体 电磁波 FDTD方法 各向异性