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采用Monte Carlo模拟方法研究了疏水-亲水-疏水(H-P-H)型ABC三嵌段共聚物在B嵌段的选择性溶剂中的自组装行为. 模拟结果表明, 通过调节A嵌段和C嵌段的疏水性和二者之间的不相容性, 体系中可以形成多种形貌各异的胶束. 根据胶束中疏水核结构的特点, 这些胶束大体上可以被分为多核型胶束和多间隔型胶束两种类型. 通过增强疏水嵌段的疏水性或降低A嵌段和C嵌段间的不相容性, H-P-H型ABC三嵌段共聚物胶束能够发生从多核型胶束向多间隔型胶束的转变. 进一步分析胶束中聚合物的链构象等微观结构信息发现, A嵌段和C嵌段间的排斥作用和疏水作用之间存在竞争关系, 而这种竞争关系是影响体系中形成多核型胶束还是多间隔型胶束的决定性因素. 相似文献
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探究了溶液中不同温度以及不同溶液成分(I-的引入)对金纳米四足体(GNTPs)重塑过程的影响,表明了GNTPs的重塑机制为Ostwald熟化,即弱结合的表面Au原子在高凸曲率区域溶解和在凹区域重新沉积。这种重塑过程可以随时通过镀银薄层在几秒内阻止,GNTPs的形貌可以在最大程度上得到很好的稳定,从而也可以防止其光学性质的演变。在此基础上,通过紫外可见近红外(UV-Vis-NIR)吸收光谱和基于同步辐射的小角X射线散射(SAXS)进一步研究了GNTPs/Ag的稳定性,并通过表面增强拉曼散射(SERS)光谱证实了GNTPs/Ag的光学响应。 相似文献
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A 40-Gb/s optical time division multiplexing (OTDM) return-to-zero (RZ) transmission experiments including a dynamic polarization mode dispersion (PMD) compensation was reported. The dynamic PMD compensator is made up of two-stage four degrees of freedom (DOF). The first stage adopts polarization controller and fixed time-delayed line. The second stage is variable differential group delay (DGD) element. The PMD monitoring technique is based on degree of polarization (DOP) as error signal. A novel practical adaptive optimization algorithm was introduced in dynamic adaptive PMD compensation. The experimental results show that the performance of the PMD compensator is excellent for 40-Gb/s RZ transmission systems with the large DGD. With this compensator, a significant improvement of system performance can be achieved in the eye pattern of a received signal. The first-order compensating ability of the compensator is greater than 30 ps. The second-order compensating ability is greater than 200 ps2. The first 相似文献
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Abstract. The trace representation of the dual of quaternary Goethals code δ(m) is given . It isproved that the shortened code of δ(m) is cyclic and its generators are shown. 相似文献
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为了讨论二元Reed-Muller码的 Z4 线性, 文献中先后介绍了两类 Z4 线性码, 分别记为ZRM}(r, m)与QRM}(r, m), 它们在Gray映射下的二元像记为ZRM}(r, m)与 QRM}(r, m) . 该文系统地讨论了这两类 Z4 线性码. 计算了ZRM}(r, m)与QRM}(r, m)的类型, 证明当3≤r≤m-1时, ZRM}(r, m)是二元线性码, 而QRM}(r, m)是非线性的; 并且, 由QRM}(r, m)张成的二元线性码恰是ZRM}(r, m). 最后, 对于非线性码QRM}(r, m), 讨论了它的秩与核. 相似文献