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本文测量了纯铌酸锂和高掺镁铌酸锂晶体的低温红外光谱,观察了OH-吸收峰的温度依赖特性.研究发现纯铌酸锂的OH-振动吸收峰基本不随温度而变化,而高掺镁铌酸锂晶体的OH-振动吸收峰的主峰峰位随温度的降低向高波数方向移动.通过分析两种晶体中不同的缺陷模型以及H+在晶格中的占位,我们提出高掺镁铌酸锂晶体中的H+紧邻高电性杂质缺陷(MgNb)3-分布,直接参与缺陷集团,完全不同于纯铌酸锂晶体中H+的分布情形,这造成了高掺镁铌酸锂晶体中OH-振动吸收峰随温度的变化.而集团内部缺陷之间相互作用随温度降低而增强的趋势是OH-振动吸收峰右移的主要原因. 相似文献
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This paper investigates the infrared absorption spectra of oxygen-related complexes in silicon crystals irradiated with
electron (1.5~MeV) at 360~K. Two groups of samples with low [Oi]=6.9× 1017~cm-3 and high [ Oi]=1.06× 1018~cm-3 were used. We found that the
concentration of the VO pairs have different behaviour to the
annealing temperature in different concentration of oxygen specimen,
it is hardly changed in the higher concentration of oxygen specimen. It
was also found that the concentration of VO2 in lower concentration
of oxygen specimen gets to maximum at 450~℃ and then
dissapears at 500~℃, accompanied with the appearing of
VO3. For both kinds of specimens, the concentration of VO3
reachs to maximum at 550~℃ and does not disappear
completely at 600~℃. 相似文献
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##正##In this paper,the temporary UV-light-induced absorption in LiNbO_3:Fe,Co crystal is investigated for different UV intensities.It is found that the sensitizing process in LiNbO_3:Fe,Co can be considered as a combination of two sub-processes with different time constants.Based on the lattice structure and the photochromic mechanism of the material,the two sub-processes are suggested to arise from electron transfer from O~(2-) to Fe~(3+) through two paths with different distances.The two-colour recording experiment in LiNbO_3:Fe,Co is also preformed by using UV and green light as gating and writing beams respectively.High sensitivity is obtained in the recording,which is considered as the consequence of direct charge transfer from O~(2-) to Fe~(3+). 相似文献
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基于ABX3晶体结构材料的新型钙钛矿太阳能电池具有光电转换效率高、可溶液加工以及低温工艺兼容等优势。与此同时,利用钙钛矿材料合成方法简单、带隙可调以及膜厚和透过率可控等优点制备的半透明钙钛矿太阳能电池为薄膜光伏的发展带来了新的契机,在建筑集成光伏和叠层光伏等领域应用前景广阔。开发高效且高稳定的半透明钙钛矿太阳能电池已成为目前光伏领域的研究重点。本文系统综述了半透明钙钛矿太阳能电池的各功能层(钙钛矿光活性层、电荷传输层和电极)材料选择、光学特性调控、电学特性优化以及制备工艺调控等技术策略,同时提出了对半透明钙钛矿太阳能电池未来发展的一些展望。 相似文献
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The effects of fast neutron irradiation on oxygen atoms in
Czochralski silicon (CZ-Si) are investigated systemically by using
Fourier transform infrared (FTIR) spectrometer and positron
annihilation technique (PAT). Through isochronal annealing, it is
found that the trend of variation in interstitial oxygen
concentration ([Oi]) in fast neutrons irradiated CZ-Si
fluctuates largely with temperature increasing, especially between
500 and 700℃. After the CZ-Si is annealed at 600℃, the
V4 appearing as three-dimensional vacancy clusters causes the
formation of the molecule-like oxygen clusters, and more importantly
these dimers with small binding energies (0.1--1.0eV) can diffuse
into the Si lattices more easily than single oxygen atoms, thereby
leading to the strong oxygen agglomerations. When the CZ-Si is
annealed at temperature increasing up to 700℃, three-dimensional
vacancy clusters disappear and the oxygen agglomerations decompose
into single oxygen atoms (O) at interstitial sites. Results from
FTIR spectrometer and PAT provide an insight into the nature of the
[Oi] at temperatures between 500 and 700℃. It turns out
that the large fluctuation of [Oi] after short-time
annealing from 500 to 700℃ results from the transformation of
fast neutron irradiation defects. 相似文献
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光伏微流体操控技术利用非均匀光伏电荷场对流体目标的静电作用来实现非接触操控。近年来,基于铌酸锂的光伏微流体操控技术逐渐引起人们的关注,并有望成为铌酸锂基生物光子芯片微流体操控功能的关键支撑技术。与传统的全电微流体操控和光镊操控相比,铌酸锂基光伏微流体操控不需要外部电源供电,不需要复杂电极的制备,所需操控光强低,作用范围广,因此可以最大程度地避免外界对内部生物环境的污染和干扰。本文介绍了铌酸锂基光伏微流体操控的理论基础,系统阐述了铌酸锂基光伏微流体操控的近期研究进展。 相似文献