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本文测量了纯铌酸锂和高掺镁铌酸锂晶体的低温红外光谱,观察了OH-吸收峰的温度依赖特性.研究发现纯铌酸锂的OH-振动吸收峰基本不随温度而变化,而高掺镁铌酸锂晶体的OH-振动吸收峰的主峰峰位随温度的降低向高波数方向移动.通过分析两种晶体中不同的缺陷模型以及H+在晶格中的占位,我们提出高掺镁铌酸锂晶体中的H+紧邻高电性杂质缺陷(MgNb)3-分布,直接参与缺陷集团,完全不同于纯铌酸锂晶体中H+的分布情形,这造成了高掺镁铌酸锂晶体中OH-振动吸收峰随温度的变化.而集团内部缺陷之间相互作用随温度降低而增强的趋势是OH-振动吸收峰右移的主要原因. 相似文献
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光伏微流体操控技术利用非均匀光伏电荷场对流体目标的静电作用来实现非接触操控。近年来,基于铌酸锂的光伏微流体操控技术逐渐引起人们的关注,并有望成为铌酸锂基生物光子芯片微流体操控功能的关键支撑技术。与传统的全电微流体操控和光镊操控相比,铌酸锂基光伏微流体操控不需要外部电源供电,不需要复杂电极的制备,所需操控光强低,作用范围广,因此可以最大程度地避免外界对内部生物环境的污染和干扰。本文介绍了铌酸锂基光伏微流体操控的理论基础,系统阐述了铌酸锂基光伏微流体操控的近期研究进展。 相似文献
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##正##In this paper,the temporary UV-light-induced absorption in LiNbO_3:Fe,Co crystal is investigated for different UV intensities.It is found that the sensitizing process in LiNbO_3:Fe,Co can be considered as a combination of two sub-processes with different time constants.Based on the lattice structure and the photochromic mechanism of the material,the two sub-processes are suggested to arise from electron transfer from O~(2-) to Fe~(3+) through two paths with different distances.The two-colour recording experiment in LiNbO_3:Fe,Co is also preformed by using UV and green light as gating and writing beams respectively.High sensitivity is obtained in the recording,which is considered as the consequence of direct charge transfer from O~(2-) to Fe~(3+). 相似文献
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This paper reports that OHabsorption bands of lithium niobate crystal have been measured at room temperature, and the band shape depending on the crystal composition has been observed. The OHabsorption bands are fitted with three Lorentzian peaks by varying position, halfwidth, and height. Nearly constant peak positions (3468, 3481 and 3490 cm-1) are obtained for all samples. It shows that the height and area of the decomposed peaks vary with the Li composition in a complex way. However, the combinations of these fitting parameters show a linear dependence on the composition up to nearly 50 mol%, which is very useful for the composition determination in a wide range. The linear relationships between the parameter combinations and Li composition are also presented quantitatively. In addition, the explanations were given for the excellent composition linearity of parameter combinations. 相似文献
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