Improvement in flow-sheet of extraction chromatography for trivalent minor actinides recovery

Journal of Radioanalytical and Nuclear Chemistry - Extraction chromatography flow-sheet employing octyl(phenyl)-N,N-diisobutylcarbonoylmethylphosphine oxide and bis(2-ethylhexyl) hydrogen phosphate...     

A weak approach to finite elasticity

On the ground of four axioms we define thekinematics of perfectly elastic bodies and in particular the notion ofweak deformations of a perfectly elastic body. Weak deformations turn out to agree withweak diffeomorphisms introduced in [10], a class of rectifiable currents which enjoys good closure and compactness properties. Defining thedynamics of perfectly elastic bodies in terms of twoconstitutive conditions on the stored energy function, we can therefore prove existence of stable equilibrium weak deformations for mixed boundary value problems, which moreover satisfy equilibrium and conservation equations.This work has been partially supported by the Ministero dell'Universitá e della Ricerca Scientifica, by C.N.R. contract n. 91.01343.CT01, by the European Research Project GADGET, and by Grant n.11957 of the zech Acad. of Sciences.This article was processed by the author using the LaT_EX style filepljour1 from Springer-Verlag.     

Dynamical scaling analysis using the Lillie Number for vitrification of deeply supercooled glycerol

Thermal response was measured for a deeply supercooled glycerol specimen by applying calorimetric temperature scanning rate spectroscopy, cooling the specimen from liquid at a slow constant cooling rate until glass transition was observed. The effective fraction of glass as a function of temperature was determined and a new definition of glass transition temperature, T_gC, as the temperature at which the effective glass fraction to be 0.5 was presented. The relation between this and the cooling rate showed the Arrhenius behavior. The effective glass fraction curves shifted linearly as a function of ln(cooling rate). When T was scaled to the Lillie Number, the glass fraction lay on a master curve, which was successfully fitted with a Kohlrausch–Williams–Watts function. The Kohlrausch exponent, the relaxation time as a function of temperature and the kinetic fragility index were determined. The results were compared with literature values.     

Anisotropic catalytic activity of the orientation controlled Nd2NiO4 + δ/YSZ hetero-epitaxial system for SOFC cathode

Electrode–electrolyte hetero-epitaxial systems for solid oxide fuel cells (SOFCs) with two different configuration of Nd₂NiO_4 + δ(110)//YSZ(100) and Nd₂NiO_4 + δ(100)//YSZ(110) were successfully fabricated by pulsed laser deposition. Thin films of Nd₂NiO_4 + δ approximately 20 nm thick were grown on a commercial single crystal of YSZ. The preferred two-dimensional diffusion paths of the oxide ions were perpendicular to the substrate for both configurations and showed oxygen reduction capability different from each other. This opens up new research direction focusing on the details of anisotropic catalytic activity of SOFC cathode depending on the crystalline surface.     

On Polynomial Solutions of Generalized Moisil-Théodoresco Systems and Hodge-de Rham Systems

The aim of the paper is to study relations between polynomial solutions of generalized Moisil-Théodoresco (GMT) systems and polynomial solutions of Hodge-de Rham systems and, using these relations, to describe polynomial solutions of GMT systems. We decompose the space of homogeneous solutions of GMT system of a given homogeneity into irreducible pieces under the action of the group O(m) and we characterize individual pieces by their highest weights and we compute their dimensions.     

A synchronized particle image velocimetry and infrared thermography technique applied to an acoustic streaming flow

Subsurface coherent structures and surface temperatures are investigated using simultaneous measurements of particle image velocimetry (PIV) and infrared (IR) thermography. Results for coherent structures from acoustic streaming and associated heating transfer in a rectangular tank with an acoustic horn mounted horizontally at the sidewall are presented. An observed vortex pair develops and propagates in the direction along the centerline of the horn. From the PIV velocity field data, distinct kinematic regions are found with the Lagrangian coherent structure (LCS) method. The implications of this analysis with respect to heat transfer and related sonochemical applications are discussed.