应用化学"113"人才培养体系的探索

In order to bridge the gap between the supply and the demand of talent cultivation, the existing talent cultivation system of applied chemistry specialty is reformed and a new "113" talent cultivation system is guided by Outcome-Based Education (OBE) education. The advanced engineering education mode is adopted to provide students with an engineering education based on the background environment of the conceptual-design-implementation-operation (CDIO) process. The characteristic "three modernizations" education mechanism, namely, cooperative education, family training and personalized guidance, are implemented. By building a new system of "113" talents training, an engineering talent training environment is formed, which takes the family as a unit, the enterprise as the background, and the project as the carrier. The problem of separating the supply from the demand of talents training for applied chemistry specialty will be fundamentally solved.     

儿童多动症与微量元素关系的探讨

为了探讨儿童多动症与微量元素的关系，测定了７２例多动症患儿头发中的六种元素Ｚｎ、Ｃｕ、Ｐｂ、Ｃｒ、Ｆｅ、Ｃａ含量，并将其与正常儿童进行比较，结果表明：多动症组Ｃｕ显著低于正常组，Ｐ〈０．０１，多动症组Ｚｎ显著低于正常组，Ｐ〈０．０５，多动症组Ｐｂ显著高于正常组，Ｐ〈０．０５。提示调整患儿体内微量元素平衡可作为治疗儿童多动症的辅助方法。     

Conformational Studies on Pentagastrin by 2D NMR and Restrained Molecular Dynamics

The present study uses 2D NMR to assign all resonance lines of pentagastrin completely. From 2D NOESY and coupling constants J_HNα, interproton distance and torsion angle Φ restraints were obtained. Based on them, the model of conformation for pentagastrin was proposed by restrained molecular dynamics calculation. It is shown that the C-terminal part of pentagastrin forms a Δ turn with a weak H-bond between the CO of Met and the NH of Phe. A strong H-bond between indole NH of Trp and β-carboxyl group of Asp stablizes the folded form in DMSO, which may result in a significant increase in the population of a favorable conformation for interaction with receptor.     

Network synchronization under periodic coupling of both positive and negative values

The European Physical Journal B - We show that all the Bose–Einstein (BE) condensations of Bose and Fermi systems can be formulated using the common ‘boson’ operator (valid below...     

The Structure and Catalytic Properties of MoVTeNbO Catalysts Modified by Adding Cr,Fe, Ce and W

Cr, Fe, Ce and W doped MoVTeNbO M2 phase catalysts were synthesized and used in the selective oxidation of propylene to acrylic acid (AA). Results show that the introduction of Cr, Fe, Ce and W substantially affects the physicochemical properties and catalytic performance of MoVTeNbO-based catalysts. Un-doped catalyst consists of M2 phase and TeO₂, while Cr, Fe, Ce and W-doped catalysts are mainly composed of M2 and MoO₃. It is indicated that doping of Cr, Fe, Ce and W can restrain the formation of TeO₂, but favour the formation of MoO₃. Un-doped, Cr and W-doped catalysts display irregular-shaped particles morphology, while Fe and Ce-doped catalysts display nanosheets morphology. In addition, the valence of superficial elements of catalysts changed greatly with the doping elements. For catalytic performance, in addition to Cr, the propylene conversion of the catalyst decreases obviously with doping of other elements, probably due to the drastically reduced specific surface area with doping of Fe, Ce and W. The existence of Cr and Ce can increase the selectivity to AA at all test temperatures (360–440 ℃), while Fe and W-doped catalysts only show higher selectivity than the un-doped one at high temperature of 420 and 440 ℃. It is illustrated that the catalysts with redox ability at relatively low temperature is more favorable for the selectivity to AA. Among them, Cr-doped catalyst shows the highest selectivity (85.3%) and yield (63.5%) of AA at test temperature of 380 ℃, which are 15.3 and 7.5% higher than that of un-doped catalyst, respectively.

Graphic Abstract

The M2 phase MoVTeNbO catalysts doped with Cr, Fe, Ce and W have been synthesized. It is demonstrated that the addition of Cr improves the stability of Te⁴⁺, and Cr-doped M2 phase shows excellent catalytic performance in the selective oxidation of propylene to acrylic acid.

     

中国高速列车研发与展望

十几年来, 以高速列车为代表的高速铁路装备在长期技术积累和自主研发的基础上,经过引进消化吸收再创新、自主提升创新、全面创新和持续创新,成功研制了多代先进的高速列车产品. 通过不断的技术创新,突破了高速列车系列关键技术, 形成了自主研发能力,不断提升高速列车的安全性、可靠性、经济性、环保性及智能化.我国高速列车的运行速度、综合舒适度、安全性、可靠性、节能环保等各项综合性能指标优良,部分指标达到国际领先水平.论文系统回顾了我国和谐号动车组、复兴号动车组、城际动车组、前沿动车组产品的发展成就及主要技术突破,分析了高速列车研发过程中面临的复杂环境适应性、大系统复杂耦合作用、安全可靠设计、智能化应用等关键技术挑战,系统概述了高速列车故障预测与健康管理技术、车体轻量化技术、被动安全防护技术、碳纤维复合材料应用、气动外形设计技术、高速转向架技术、噪声控制技术、牵引制动技术等关键技术的研究进展及主要技术突破, 并展望了高速列车动力学技术、结构安全技术、被动安全防护技术、流固耦合技术、牵引制动技术、智能控制安全技术、故障预测与健康管理技术、综合节能技术等关键技术的未来发展方向.      

有机化学科研渗透教学法的尝试

有机化学涉及的有机反应类型繁多,反应机理复杂,理论性强,难以理解和掌握。而大学有机化学的教学模式基本以教师为中心,以课堂讲授为主,这在某种程度上束缚了学生的创造思维和积极性。融入科研的有机化学教学法的尝试,可以破解有机化学授课的困惑,调动了学生对有机化学的兴趣及精准掌握。科研渗透的教学可以拓宽学生知识视野,激发学习兴趣,实现理论联系科研、实际生产,能够加强学生对有机化学知识的掌握。     

基于新工科理念的应用化学专业创新创业能力培养体系建设

To adapt to the needs of the development of new technology and new business forms, enhance the students' ability of innovation knowledge transformation and innovation and entrepreneurship, and promote the technological development and industrial upgrading of Liaoning Province and fine chemical industry, our university has established an innovation and entrepreneurship training system to meet the requirements of emerging engineering talents training, according to the professional advantages, regional characteristics and the social needs. The orientation of applied chemistry major, personnel training objectives, teaching mode, platform construction, innovation and entrepreneurship education have been systematically designed and comprehensively reformed, and some achievements and experiences have been achieved.