首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   26948篇
  免费   4622篇
  国内免费   3485篇
化学   19456篇
晶体学   315篇
力学   1544篇
综合类   195篇
数学   3545篇
物理学   10000篇
  2024年   32篇
  2023年   586篇
  2022年   628篇
  2021年   935篇
  2020年   1255篇
  2019年   1172篇
  2018年   981篇
  2017年   971篇
  2016年   1350篇
  2015年   1317篇
  2014年   1539篇
  2013年   2072篇
  2012年   2367篇
  2011年   2519篇
  2010年   1773篇
  2009年   1569篇
  2008年   1805篇
  2007年   1543篇
  2006年   1383篇
  2005年   1217篇
  2004年   954篇
  2003年   835篇
  2002年   941篇
  2001年   721篇
  2000年   592篇
  1999年   560篇
  1998年   443篇
  1997年   410篇
  1996年   416篇
  1995年   392篇
  1994年   325篇
  1993年   237篇
  1992年   219篇
  1991年   204篇
  1990年   159篇
  1989年   141篇
  1988年   82篇
  1987年   78篇
  1986年   93篇
  1985年   81篇
  1984年   50篇
  1983年   39篇
  1982年   22篇
  1981年   20篇
  1980年   8篇
  1979年   3篇
  1977年   2篇
  1975年   2篇
  1959年   2篇
  1957年   7篇
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
1.
2.
The designs of efficient and inexpensive Pt-based catalysts for methanol oxidation reaction (MOR) are essential to boost the commercialization of direct methanol fuel cells. Here, the highly catalytic performance PtFe alloys supported on multiwalled carbon nanotubes (MWCNTs) decorating nitrogen-doped carbon (NC) have been successfully prepared via co-engineering of the surface composition and electronic structure. The Pt1Fe3@NC/MWCNTs catalyst with moderate Fe3+ feeding content (0.86 mA/mgPt) exhibits 2.26-fold enhancement in MOR mass activity compared to pristine Pt/C catalyst (0.38 mA/mgPt). Furthermore, the CO oxidation initial potential of Pt1Fe3@NC/MWCNTs catalyst is lower relative to Pt/C catalyst (0.71 V and 0.80 V). Benefited from the optimal surface compositions, the anti-corrosion ability of MWCNT, strong electron interaction between PtFe alloys and MWCNTs and the N-doped carbon (NC) layer, the Pt1Fe3@NC/MWCNTs catalyst presents an improved MOR performance and anti-CO poisoning ability. This study would open up new perspective for designing efficient electrocatalysts for the DMFCs field.  相似文献   
3.
A graphic sequence π =(d1, d2,..., dn) is said to be forcibly k-edge-connected if every realization of π is k-edge-connected. In this paper, we obtain a new sufficient degree condition for π to be forcibly k-edgeconnected. We also show that this new sufficient degree condition implies a strongest monotone degree condition for π to be forcibly 2-edge-connected and a conjecture about a strongest monotone degree condition for π to be forcibly 3-edge-connected due to...  相似文献   
4.
Hu  Duo-Duo  Gao  Qian  Dai  Jing-Cheng  Cui  Ru  Li  Yuan-Bo  Li  Yuan-Ming  Zhou  Xiao-Guo  Bian  Kang-Jie  Wu  Bing-Bing  Zhang  Kai-Fan  Wang  Xi-Sheng  Li  Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,...  相似文献   
5.
Gao  Zhigen  Guo  Jianhua  Ma  Yanyuan 《中国科学 数学(英文版)》2021,64(8):1905-1916
Science China Mathematics - Linear factor models are familiar tools used in many fields. Several pioneering literatures established foundational theoretical results of the quasi-maximum likelihood...  相似文献   
6.
Journal of Mathematical Chemistry - The analytical solutions of an asymmetric double well potential $$V(x)=a\, x^2-b\, x^3+c\, x^4$$ are found to be a triconfluent Heun function $$H_{T}(\alpha ,...  相似文献   
7.
8.
In the paper, the authors establish several integral representations for the generating functions of the large and little Schröder numbers and for the large and little Schröder numbers.  相似文献   
9.
10.
Cinnamaldehyde (CA), an active ingredient isolated from the traditional Chinese medicine Cortex Cinnamomi, has a wide range of bioactivities. To clarify the distribution characteristics of CA, a selective and sensitive method utilizing gas chromatography–mass spetrometry was initially developed for simultaneously determining the concentration of CA and its metabolite cinnamyl alcohol in rat tissues. Selected ion masses of m/z 131, 105 and 92 were chosen, and separation of the analytes was performed on a DB‐5 ms (30 m × 0.25 mm, 0.25 µm, thickness) capillary column by gas chromatography–mass spectrometry. The calibration curves demonstrated good linearity and reproducibility over the range of 20–2000 and 20–4000 ng/mL for various tissue samples. Recoveries ranged from 86.8 to 107.5%, while intra‐ and interday relative standard deviations were all <11.3%. The analysis method was successfully applied in tissue distribution studies for CA and cinnamyl alcohol. As CA and cinnamyl alcohol may inter‐convert to one another, simultaneous determination of both analytes provides a comparative and accurate data for tissue study. The concentrations of CA and cinnamyl alcohol remaining in spleen were the highest among the main organs, including heart, liver, spleen, lung, kidney and brain. In addition, there was no long‐term accumulation of CA in rat tissues. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号