Ultrahigh Loading Copper Single Atom Catalyst for Palladium-free Wacker Oxidation

Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by ¹⁸O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts.     

A Closed‐Loop Control Strategy for Producing Nitrile Rubber of Uniform Chemical Composition in a Semibatch Reactor: A Simulation Study

To improve the quality of industrial nitrile rubbers, the copolymer chemical composition, p_A(t), should ideally be kept constant along the reaction. This work proposes a closed‐loop control strategy for the semibatch operation of the reactor with the aim of regulating p_A(t) within a reduced range of variability. The proposed strategy is evaluated by simulating a mathematical model of the process. To this effect, a simplified mathematical model of the reaction is first derived and then utilized to obtain a suboptimal control law and a soft‐sensor that estimates the polymerization rates. The suboptimal control law is compensated by adding a term proportional to errors in p_A(t). The simulated example considers the production of the low‐composition AJLT grade, with the copolymerization reaction represented by a detailed mathematical model adjusted to an industrial plant. Due to the high performance of the soft‐sensor, the simulation results suggest that the proposed closed‐loop strategy is efficient to adequately regulate p_A(t) in spite of structural and parametric uncertainties, while other quality variables remained practically unaffected.     

Sufficient Conditions for a Digraph to be Supereulerian

A (di)graph is supereulerian if it contains a spanning eulerian sub(di)graph. This property is a relaxation of hamiltonicity. Inspired by this analogy with hamiltonian cycles and by similar results in supereulerian graph theory, we analyze a number of sufficient Ore type conditions for a digraph to be supereulerian. Furthermore, we study the following conjecture due to Thomassé and the first author: if the arc‐connectivity of a digraph is not smaller than its independence number, then the digraph is supereulerian. As a support for this conjecture we prove it for digraphs that are semicomplete multipartite or quasitransitive and verify the analogous statement for undirected graphs.     

On a class of Riemann surfaces

It is considered the class of Riemann surfaces with dimT1 = 0, where T1 is a subclass of exact harmonic forms which is one of the factors in the orthogonal decomposition of the spaceΩH of harmonic forms of the surface, namely The surfaces in the class OHD and the class of planar surfaces satisfy dimT1 = 0. A.Pfluger posed the question whether there might exist other surfaces outside those two classes. Here it is shown that in the case of finite genus g, we should look for a surface S with dimT1 = 0 among the surfaces of the form Sg\K , where Sg is a closed surface of genus g and K a compact set of positive harmonic measure with perfect components and very irregular boundary.     

交换L*-环

我们证明一个交换整环或交换局部环是一个L*-环当且仅当它是一个O*-环.文中还证明了一些一般性的条件使之一个交换环不是L*.     

Multilinear Calderón-Zygmund Operators and Their Commutators with BMO Functions in Herz-Morrey Spaces with Variable Smoothness and Integrability

In this paper, we obtain that multilinear Calderón-Zygmund operators and their commutators with BMO functions are bounded on products of Herz-Morrey spaces with variable smoothness and integrability. The vector-valued setting of multilinear Calderón-Zygmund operators is also considered.     

On the non-commutative fractional Wishart process

We investigate the process of eigenvalues of a fractional Wishart process defined by $N=B^{?}B$, where B is the matrix fractional Brownian motion recently studied in [18]. Using stochastic calculus with respect to the Young integral we show that, with probability one, the eigenvalues do not collide at any time. When the matrix process B has entries given by independent fractional Brownian motions with Hurst parameter $H\in (1/2,1)$, we derive a stochastic differential equation in the Malliavin calculus sense for the eigenvalues of the corresponding fractional Wishart process. Finally, a functional limit theorem for the empirical measure-valued process of eigenvalues of a fractional Wishart process is obtained. The limit is characterized and referred to as the non-commutative fractional Wishart process, which constitutes the family of fractional dilations of the free Poisson distribution.     

Burden in Henselian valued fields

In the spirit of the Ax-Kochen-Ershov principle, we show that in certain cases the burden of a Henselian valued field can be computed in terms of the burden of its residue field and that of its value group. To do so, we first see that the burden of such a field is equal to the burden of its leading term structure. These results are generalisations of Chernikov and Simon's work in [11].     

压电材料平面应力状态的直线裂纹问题一般解

研究了含直线裂纹系的压电材料平面应力问题单个裂纹和双裂纹问题的封闭解答表明，在裂纹尖端，应力、电场强度和电位移有１／２阶的奇异性并与前人结果比较了产生电场奇异性的物理因素