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排序方式: 共有101条查询结果,搜索用时 15 毫秒
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Saulius Armalis Inga Krikŝĉiuniene Erika Kubiliene Nii-Kotey Djane Kuria Ndungu Lennart Mathiasson 《International journal of environmental analytical chemistry》2013,93(1-4):233-242
Abstract The performance of a flow-through mercury coated reticulated vitreous carbon (RVC) electrode in the potentiometric stripping analysis (PSA) of trace metals has been examined. A wall-jet glassy carbon cell was used for the comparative experiments. Experimental parameters influencing the stripping signals have been optimised in order to use the stripping analysis after the preconcentration and matrix isolation by supported liquid membrane (SLM) technique. The SLM with di-2-ethylhexyl-phosphoric acid (DEHPA) as the extractant in the membrane liquid for proton driven transport of trace metals across the membrane has been chosen. Results presented for lead determination in river water demonstrate the analytical advantages of coupled technique SLM-PSA. 相似文献
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利用便携式拉曼光谱仪建立了一个快速筛查与检测谷物中真菌毒素脱氧雪腐镰刀菌烯醇(DON)的表面增强拉曼散射(SERS)方法。首先利用实验室前期开发的方法制备了具有高活性的水凝胶SERS芯片。该SERS芯片是将预先制备的高SERS活性的单层碳基点(CDs)包裹的银纳米颗粒团聚体(a-AgNPs/CDs)与聚乙烯醇(PVA)水溶液混合均匀后,再利用循环冷冻-解冻的物理交联法制备而成的。实验优化了影响水凝胶SERS芯片对DON的SERS响应的实验条件,包括溶剂、浸泡温度和浸泡时间。在最佳的SERS检测条件下(溶剂为水-乙醇(1:1, v/v),浸泡温度为40 ℃,浸泡时间为5 min), DON的线性响应范围为1~10000 μg/kg(相关系数(R2)=0.9967),检出限(LOD)为0.14 μg/kg,表明该SERS基底具有较高的灵敏度。得益于水凝胶特殊的孔径结构,实际样品基质中常见的糖、蛋白质、油脂、色素等干扰物质都被阻隔在水凝胶外。因此,在复杂样品检测中仅需要简单的提取,而不需要复杂的分离处理。将该方法用于小麦粉中DON的检测,所得回收率为97.3%~103%,相对标准偏差为4.2%~5.0%。实验结果表明所建立的检测DON的SERS方法具有响应范围宽、灵敏度高、重复性好、响应迅速、操作简单、抗干扰能力强等优点,这说明本实验室所构建的水凝胶SERS芯片在粮食中生物毒素的快速筛查与检测方面具有良好的应用潜力。 相似文献
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采用傅里叶模方法,分析了单点金刚石铣削后KDP晶体表面小尺度波纹的周期和幅值对单层增透膜折射率、厚度以及透射率的影响。研究表明:膜层最佳折射率在1.22左右,在此折射率条件下,保证透射率大于99%的单层增透膜的理想厚度范围应为180~220 nm,并且折射率和膜厚值的选取基本不受晶体表面小尺度波纹周期和幅值的影响。若只考虑SPDT法加工后KDP晶体表面小尺度波纹周期和幅值的实际范围,透射率基本不受波纹周期的影响,但却会随波纹幅值的增大而加速下降。理想镀膜条件下透射率最大值大于99%,并且通常在99.67%~99.94%之间。 相似文献
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Case 5, Level 1 of the international HYDROCOIN groundwater flow modeling project is an example of idealized flow over a salt dome. The groundwater flow is strongly coupled to solute transport since density variations in this example are large (20%).Several independent teams simulated this problem using different models. Results obtained by different codes can be contradictory. We develop a new numerical model based on the mixed hybrid finite elements approximation for flow, which provides a good approximation of the velocity, and the discontinuous finite elements approximation to solve the advection equation, which gives a good approximation of concentration even when the dispersion tensor is very small. We use the new numerical model to simulate the salt dome flow problem.In this paper we study the effect of molecular diffusion and we compare linear and nonlinear dispersion equations. We show the importance of the discretization of the boundary condition on the extent of recirculation and the final salt distribution. We study also the salt dome flow problem with a more realistic dispersion (very small dispersion tensor). Our results are different to prior works with regard to the magnitude of recirculation and the final concentration distribution. In all cases, we obtain recirculation in the lower part of the domain, even for only dispersive fluxes at the boundary. When the dispersion tensor becomes very small, the magnitude of recirculation is small. Swept forward displacement could be reproduced by using finite difference method to compute the dispersive fluxes instead of mixed hybrid finite elements. 相似文献
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Arash Bahrami Asghar Nosier 《International Journal of Solids and Structures》2007,44(25-26):8119-8142
Within the elasticity formulation the most general displacement field for hygrothermal problems of long laminated composite plates is presented. The equivalent single-layer theories are then employed to determine the global deformation parameters appearing in the displacement fields of general cross-ply, symmetric, and antisymmetric angle-ply laminates under thermal and hygroscopic loadings. Reddy’s layerwise theory is subsequently used to determine the local deformation parameters of various displacement fields. An elasticity solution is also developed in order to validate the efficiency and accuracy of the layerwise theory in predicting the interlaminar normal and shear stress distributions. Finally, various numerical results are presented for edge-effect problems of several cross-ply, symmetric, and antisymmetric angle-ply laminates subjected to uniform hygrothermal loads. All results indicate high stress gradients of interlaminar normal and shear stresses near the edges of laminates. 相似文献
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Graphene is scientifically and commercially important because of its unique molecular structure which is monoatomic in thickness, rigorously two-dimensional and highly conjugated. Consequently, graphene exhibits exceptional electrical, optical, thermal and mechanical properties. Herein, we critically discuss the surface modification of graphene, the specific advantages that graphene-based materials can provide over other materials in sensor research and their related chemical and electrochemical properties. Furthermore, we describe the latest developments in the use of these materials for sensing technology, including chemical sensors and biosensors and their applications in security, environmental safety and diseases detection and diagnosis. 相似文献
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