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The Fourier transform far infrared spectra of oxalate hydrates of whole rare-earth series except Pm and Sc are investigated in the range of 100-400 cm~(-1). The assignment of vibrational frequencies is made on the basis of normal coordinate analysis using our NORVIB program. The model used for the hghter elements of the lanthanide series (La to Eu) is based on the crystal structure of Nd_2(C_2O_4)_3. 10H_2O, in which each lanthanide ion is surrounded by nine O atoms, six from three oxalate ions and three from Water molecules.The model adopted for the heavier elements of the lanthanide series (Gd to Lu) and Ytterbium is based on the crystal structure of Yb_2(C_2O_4)_3· 6H_2O, in which each ion is surrounded by eight atoms, six from three oxalate ions and two from water molecules. The variation of the metal-ligand frequencies and force constants with the atomic numbers of lanthanides is plotted and discussed. 相似文献
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BANASZUK ANDRZEJ; KOCI=CKI MACIEJ; PRZYLUSKI K. MACIEJ 《IMA Journal of Mathematical Control and Information》1996,13(1):41-61
Some results concerning the problem of duality between observationand control for implicit linear discrete-time systems are presented.It is not assumed that the considered systems are regular. Inthis case, some new concepts of observability and controllabilityturn out to be necessary for studying the problem of duality. 相似文献
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In this paper we propose an object grammar decomposition for the classes of columnconvex,
and directed column-convex polyominoes. As a consequence, we obtain the enumeration
of such classes according to the semi-perimeter, thus giving a natural explanation of the fact that
the generating functions of both the classes are algebraic.AMS Subject Classification: 05A15. 相似文献
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For a given sequence n1 < n2 < ... of integers satisfying
and for a given convergent sequence of
complex numbers {aj}, it was shown in [4] that there is
a uniformly-almost-even function
assuming the values
f(nj) = aj.
For the proof, Gelfands theory of commutative
Banach algebras and Tietzes extension theorem were used. In [3]
an incomplete proof [by elementary means] of this result was
given.1)The aim of this note is to give some results which can be proved by the
method from [3].1)The first-named author is grateful to the second author for pointing out a missing case in the above-mentioned proof.Received: 7 November 2002 相似文献
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Fangyuan?Tian Hongji?LiEmail author Mingji?LiEmail author Cuiping?Li Yingjie?Lei Baohe?Yang 《Mikrochimica acta》2017,184(6):1611-1619
The authors describe a voltammetric sensor for simultaneous determination of dopamine (DA), uric acid (UA), L-tyrosine (Tyr), and the diuretic drug hydrochlorothiazide (HCTZ). The assay is based on the use of graphene nanowalls deposited on a tantalum substrate. The nanowalls are characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy, and cyclic voltammetry. The nanowalls are vertically grown on the substrate by direct-current arc plasma jet chemical vapor deposition. The modified electrode is shown to enable simultaneous differential pulse voltammetric determination of DA, UA, Tyr, and HCTZ. The graphene nanowalls display a large specific surface, high conductivity, and a large number of catalytically active sites for oxidation of analytes. Simultaneous detection is performed best at a pH value of 7.0 and at peak potentials of 0.124 V (vs. SCE) for DA, 0.256 V for UA, 0.536 V for Tyr and 0.708 V for HCTZ. The respective detection limits are 0.04 μM, 0.1 μM, 0.6 μM and 0.4 μM. The results show that this graphene wall modified electrode is a promising tool for the design of sensitive, selective, and stable sensors. 相似文献