固相萃取-超高效液相色谱串联质谱法测定水中13种苯胺类化合物

建立了固相萃取-超高效液相色谱串联质谱法测定水中13种苯胺类化合物。样品通过HC-C₁₈固相萃取小柱富集，洗脱后加入内标苯胺-D5进行氮吹浓缩，经HSS T3色谱柱(150 mm×2.1 mm,1.8μm)分离，采用多反应监测扫描模式，以内标法定量。13种苯胺类化合物在0.1～100μg/L(其中3-硝基苯胺为0.2～200μg/L)范围内与特征离子的色谱峰面积线性关系良好，相关系数均大于0.995，方法检出限为0.001～0.006μg/L，平均加标回收率为67.3%～117%，测定结果的相对标准偏差为3.77%～16.9%(n=6)。该法操作简单、稳定性好，能够满足实际水体中13种苯胺类化合物大批量样品分析的需求。     

全光纤化的被动式亚纳秒脉冲Yb光纤激光器研究

报道了一种可以被动式产生高峰值功率亚纳秒脉冲的全光纤化的新型Yb光纤激光器.通过在15m长度的Yb增益光纤和一对光纤光栅对组成的线性谐振腔内直接熔接一段特殊掺杂的Bi/Cr共掺石英光纤,在975nm的半导体激光器连续抽运下,实现了高重复频率的高峰值功率亚纳秒短脉冲激光输出.实验结果表明,输出激光的重复频率与吸收的抽运光...     

两区复振幅光瞳滤波器的优化设计研究

现在设计的超分辨光瞳滤波器大多是对光瞳函数进行设计和优化,本文在此基础上,设计了一种新的光瞳函数,具有此函数的超分辨光瞳滤波器,给设计参量b一确定的值,调节参量a或者固定参量a,调节参量b,均可以在一定程度上实现较好的横向超分辨,且具有比较高的斯特尔比,当a=2.1,b=-0.7时,轴向光强值在一段范围内变化缓慢,扩展...     

MICROSTRUCTURAL CHARACTERIZATION OF SPIN—VALVE MULTILAYERS BY X—RAY ANOMALYOUS DIFFRACTION TECHNIQUE

It is impossible to directly analyze the microstructure of spin-valve multilayers based on Ni,F,Cu and Mn by a conventional X-ray diffraction technique because the lattice parameter and atomic sattering factor sof them are very close.To solve this problem, we use an x-ray anomalous diffraction technique to characterize the microstructures of the [Ni80Fe20/Fe50Mn50]15 and [Ni80Fe20/Cu]15 superlattice systems.The results show that more diffraction peaks and higher internsity in the reflectivety profile are observed when the incident energy is close to the absorption edge of the lighter element(Mn) in [Ni80Fe20/Fe50Mn50]15 multilayer systems and to the absorption edge of the heavier element (Cu) in the [Ni80Fe20/Cu]15 multilayer systems.The interface and periodic structure of [Ni80F20/Fe50Mn50]15 are more perfect than that of the [Ni80Fe20/Cu]15 superlattices.The above results are disussed in this paper.     

铯饱和吸收光谱装置的简化设计及谱线的观测

介绍了一种铯原子饱和吸收光谱的简化装置。采用两镜腔型结构替代常规的四镜腔饱和吸收光谱装置，观测到稳定的铯原子D2线的超精细谱线，为激光频率稳定于铯原子的吸收峰奠定了较好的基础。并对简化后的实验方案与常规的饱和吸收光谱方案进行了比较。     

教"归纳与猜想"的三个数学史例

新课程标准注重数学史的教育,在系列3安排一个<数学史选讲>专题,<标准>对数学史的教育作了如下论述:……     

Superlinearly convergent affine scaling interior trust-region method for linear constrained LC<Superscript>1</Superscript> minimization

We extend the classical affine scaling interior trust region algorithm for the linear constrained smooth minimization problem to the nonsmooth case where the gradient of objective function is only locally Lipschitzian. We propose and analyze a new affine scaling trust-region method in association with nonmonotonic interior backtracking line search technique for solving the linear constrained LC1 optimization where the second-order derivative of the objective function is explicitly required to be locally Lipschitzian. The general trust region subproblem in the proposed algorithm is defined by minimizing an augmented affine scaling quadratic model which requires both first and second order information of the objective function subject only to an affine scaling ellipsoidal constraint in a null subspace of the augmented equality constraints. The global convergence and fast local convergence rate of the proposed algorithm are established under some reasonable conditions where twice smoothness of the objective function is not required. Applications of the algorithm to some nonsmooth optimization problems are discussed.     

浅谈对珠心算教练师的培训要点及方式方法

珠心算教练师国家职业标准的公布施行，使我们工作在一线的广大教练师倍感欣慰，这么多年的辛勤工作得到了国家有关部门的认可，也使我们珠算心算协会的工作跨上了一个新台阶。如何使珠心算事业稳定发展，加强对珠心算教练师的培训和管理成为各级珠算心算协会当前及今后一段时期的一项重要工作。     

二元超晶格弹性应力的能带理论计算

根据量子能带理论 ,采用经验赝势方法 ,对 (Pb) n/ (Bi) n,(Al) n/ (As) n 的假想简立方二元超晶格结构的弹性应力进行了计算 .结果表明弹性应力随超晶格周期λ的增加而迅速升高至一定大小后趋于稳定 ,且只有在周期较小时才同过渡金属氮化物超晶格硬度随周期的变化的趋势定性一致 ,为超晶格硬度随周期的变化提供了一种可能的解释