Highly sensitive digital optical sensor with large measurement range based on the dual-microring resonator with waveguide-coupled feedback

We propose a novel high-performance digital optical sensor based on the Mach-Zehnder interferential effect and the dual-microring resonators with the waveguide-coupled feedback. The simulation results show that the sensitivity of the sensor can be orders of magnitude higher than that of aconventional sensor, and high quality factor is not critical in it. Moreover, by optimizing the length of the feedback waveguide to be equal to the perimeter of the ring, the measurement range of the proposed sensor is twice as much as that of the conventional sensor in the weak coupling case.     

Segregation of alloying atoms at a tilt symmetric grain boundary in tungsten and their strengthening and embrittling effects

We investigate the segregation behavior of alloying atoms （Sr, Th, In, Cd, Ag, Sc, Au, Zn, Cu, Mn, Cr, and Ti） near Z3 （ 111 ） [1]-0] tilt symmetric grain boundary （GB） in tungsten and their effects on the intergranular embrittlement by performing first-principles calculations. The calculated segregation energies suggest that Ag, Au, Cd, In, Sc, Sr, Th, and Ti prefer to occupy the site in the mirror plane of the GB, while Cu, Cr, Mn, and Zn intend to locate at the first layer nearby the GB core. The calculated strengthening energies predict Sr, Th, In, Cd, Ag, Sc, Au, Ti, and Zn act as embrittlers while Cu, Cr, and Mn act as cohesion enhancers. The correlation of the alloying atom＇s metal radius with strengthening energy is strong enough to predict the strengthening and embrittling behavior of alloying atoms; that is, the alloying atom with larger metal radius than W acts as an embrittler and the one with smaller metal radius acts as a cohesion enhancer.     

高酸位多级孔超稳Y型沸石的制备及催化性能

以表面活性剂十六烷基三甲基溴化铵(CTABr)为模板剂,在水热体系对水蒸气处理后的超稳Y型(USY)沸石进行晶化处理,获得高酸量和高水热稳定性的USY-c-w样品。利用X射线衍射、扫描电子显微镜、透射电子显微镜、固态核磁共振、N₂吸附-脱附、NH₃-程序升温脱附、傅里叶变换红外光谱及吡啶红外对所制备催化剂的物化性质进行详细表征。选用1,3,5-三异丙苯(TIPB)催化裂化作为探针反应,研究制备的催化剂的催化性能,并与工业USY沸石进行对比。结果表明,再次水热晶化后,样品的硅铝骨架局部重构,非骨架铝重新进入沸石骨架,合成样品的硅铝比(n_Si/n_Al)由10降至3.0;再晶化后的USY沸石,不仅具有丰富的介孔结构,并且具有更多的弱酸和中强酸位点。在TIPB裂解反应中,再晶化后的USY沸石表现出比原样品更优异的催化性能。     

磁性Co/TiB2室温高效催化氨硼烷产氢及串联降解有机污染物

通过熔盐法制备TiB₂载体,并采用简单的沉淀-沉积法制备了Co/TiB₂磁性可回收纳米催化剂,用于室温催化氨硼烷（NH₃BH₃）溶液产氢及串联降解对硝基苯酚（4-NP）及偶氮染料酸性橙7（AO7）、酸性红1（AR1）和甲基橙（MO）等有机污染物。采用X射线衍射、扫描电子显微镜、透射电子显微镜、X射线光电子能谱、振动样品磁强计等表征方法对催化剂的微观形貌和结构等进行分析。结果表明,Co纳米粒子均匀地分布在TiB₂载体表面,晶粒尺寸约为40 nm,并且被TiB₂载体包覆,具有典型的金属-载体强相互作用。Co/TiB₂表现出优异的室温催化NH₃BH₃溶液产氢活性,产氢速率为565.8 mol_H2·mol_cat^-1·h^-1。在串联降解有机污染物反应中,Co/TiB₂在7 min内催化4-NP氨基化的转化率接近100%,反应速率常数高达0.72 min^-1;降解AO7的反应速率常数在3种偶氮染料中最高（0.34 min^-1）。通过EPR-DMPO（EPR=电子顺磁共振,DMPO=5,5-二甲基-1-吡咯啉-N-氧化物）自由基捕获实验检测出Co/TiB₂+NH₃BH₃催化体系中产生大量的氢自由基（·H）。得益于·H的强还原性,Co/TiB₂+NH₃BH₃催化体系能够将4-NP氨基化为具有更高价值的对氨基苯酚（4-AP）,同时能够还原偶氮染料分子中的显色基团偶氮基（—N=N—）。     

低温晶化对B-ZSM-5和Ti-ZSM-5物化性能的影响

 以改进方法合成的B-ZSM-5分子筛为母体,采用气固相法合成了Ti-ZSM-5分子筛,并以XRD,FT-IR,UV-Vis,XRF,SEM,ICP-AES和MAS NMR等手段对B-ZSM-5和Ti-ZSM-5进行了表征,考察了Ti-ZSM-5对苯酚羟基化反应的催化性能. 结果表明,合成B-ZSM-5时的前期低温晶化有助于晶粒的减小; 以其为母体制备的Ti-ZSM-5对苯酚羟基化反应具有优异的催化性能. 在n(PhOH)/n(H2O2)=3,n(Me2CO)/n(PhOH)=2.7,m(cat)/m(PhOH)=5%,T=353 K和t=6 h的反应条件下,苯酚转化率可达20%以上.     

金属/介质/金属光栅结构强化吸收特性

本文从电磁场理论出发,研究了单层光栅的金属/介质/金属结构的共振,利用严格耦合波方法计算了金属/介质/金属光栅结构表面的光谱特性,利用金属/介质/金属膜层结构的色散关系和等效LC回路模型两种理论对金属/介质/金属光栅结构表面的共振现象进行研究,讨论了几何参数对金属/介质/金属光栅结构共振的影响,结果表明单层光栅的金属/介质/金属结构的共振由金属/介质界面上的表面等离子极化之间的耦合产生。     

基于水平集方法的二维Stokes多工况流动的拓扑优化

本文采用水平集方法进行了多工况条件下Stokes流动问题的拓扑优化,研究了进出口边界变化对流体拓扑优化结果的影响。在拓扑优化过程中,采用无需样条参数化的重新网格划分方法来实现物理场和水平集类方程交替求解。以最小能量耗散为目标,通过对三工况条件下流动通道的拓扑优化设计,表明多工况条件下的流动拓扑优化比单工况条件下获得的拓扑优化设计结果更为合理。     

������Ϊֱ�ߵĴ�������ϵ

介绍了在已知环形轴对称等离子体平衡位形的条件下,建立磁力线为直线的坐标系的方法。该坐标系被广泛应用于托卡马克等离子体的磁流体稳定性和动理论物理问题的理论分析,但文献中对坐标系建立方法却很少有介绍。结合几类托卡马克位形和球形环位形,对该类坐标系的特征进行了分析。     

Current Density-Dependent Thermal Stability of ZnSe Nanowire in M-S-M NanostructureD

Due to semiconductor nanowire （NW） having a very tiny diameter, the electronic devices based on metal-semiconductor NW-metal （M-S-M） nanostruc- ture can carry a very large current density com- pared to electronics based on bulk semiconductors. A small mass of a NW also means a small heat capacitance. In this case, any small energy trans- fer from the current-carry electrons to local ionic or/and lattice vibrations in NWs may cause a sub- stantial self-heating of the NWs. Thus thermal insta- bility of NWs in M-S-M nanostructure due to Joule heating has become a fundamentally and technolog- ically important issue concerning the performance of semiconductor NW-based nanoelectronics and has at- tracted a lot of attention. The failure behaviors of various semiconductor and metallic NWs inves- tigated by in situ transmission electron microscopy （TEM） and confocal micro-Raman spectroscopy re- spectively have confirmed semiconductor NWs includ- ing Si, Ge, GaN, ZnO, Sn02, Ti02, ZnSe and ZnTe NWs electrically broken by thermal evaporation due to Joule heating and metallic NWs electrically de- stroyed by electromigration. Electron-phonon in- teraction that transfers energy from conduction elec- trons to the ions in the material causes Joule heating. Electromigration due to the transfer of the momentum of conduction electrons to the ions causes migration of atoms in the material when high current density flows through a circuit. The different failure mechanisms of these NWs are significantly materials-dependent due to the difference of their chemical and physical prop- erties and have a very close relation with the param- eters governing the electron transport mechanism at the metal-semiconductor （M-S） nanocontact such as Schottky barrier and bias polarity .     

在同位旋SU(2)不变耦合模型中研究 p pbar -> n nbar 核子反应的重整化无穷阶链图效应

本文采用描述中性及荷电 pion 介子（pion0,pion+,pion-）与核子-反核子强相互作用的同位旋SU(2)不变耦合模型,计算出在pion0 及 pion+, pion- 重整化链图传播下 p pbar -> n nbar 核子反应微分截面的“精确”解析结果;并且将此结果与在 pion0 及 pion+, pion- 树图传播下的微分截面作了对比分析,得到相应的辐射修正重要信息。本文完成的工作对进一步深入研究三种荷电状态 pion 介子与核子-反核子强相互作用的同位旋SU(2)不变耦合模型以及深入理论探讨质子-反质子对撞实验,都将提供某些理论研究的参考价值。