全文获取类型
收费全文 | 3658篇 |
免费 | 855篇 |
国内免费 | 906篇 |
专业分类
化学 | 1248篇 |
晶体学 | 24篇 |
力学 | 475篇 |
综合类 | 169篇 |
数学 | 1757篇 |
物理学 | 1746篇 |
出版年
2024年 | 19篇 |
2023年 | 101篇 |
2022年 | 119篇 |
2021年 | 111篇 |
2020年 | 74篇 |
2019年 | 126篇 |
2018年 | 90篇 |
2017年 | 140篇 |
2016年 | 146篇 |
2015年 | 171篇 |
2014年 | 315篇 |
2013年 | 237篇 |
2012年 | 234篇 |
2011年 | 256篇 |
2010年 | 284篇 |
2009年 | 304篇 |
2008年 | 293篇 |
2007年 | 243篇 |
2006年 | 228篇 |
2005年 | 218篇 |
2004年 | 212篇 |
2003年 | 196篇 |
2002年 | 150篇 |
2001年 | 162篇 |
2000年 | 123篇 |
1999年 | 112篇 |
1998年 | 115篇 |
1997年 | 95篇 |
1996年 | 81篇 |
1995年 | 89篇 |
1994年 | 80篇 |
1993年 | 67篇 |
1992年 | 70篇 |
1991年 | 65篇 |
1990年 | 39篇 |
1989年 | 32篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 1篇 |
1959年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有5419条查询结果,搜索用时 31 毫秒
991.
992.
In this paper,we investigate the quantum correlation of coupled qubits which are initially in maximally entangled mixed states in a squeezed vacuum reservoir.We compare and analyze the effects of squeezed parameters on quantum discord and quantum concurrence.The results show that in a squeezed vacuum reservoir,the quantum discord and quantum concurrence perform with completely opposite behaviors with the change of squeezed parameters.Quantum discord survives longer with the increase of squeezed amplitude parameter,but entanglement death is faster on the contrary.The results also indicate that the classical correlation of the system is smaller than quantum discord in a vacuum reservoir,while it is bigger than quantum discord in a squeezed vacuum reservoir.The quantum discord and classical correlation are more robust than quantum concurrence in the two reservoir environments,which indicates that the entanglement actually is easily affected by decoherence and quantum discord has a stronger ability to avoid decoherence in a squeezed vacuum reservoir. 相似文献
993.
The photoluminescence (PL) characteristics of hybrid β-FeSi2/Si and pure β-FeSi2 films fabricated by pulsed laser deposition at 20 K are investigated. The intensity of the 1.54-μm PL from the former is enhanced, but the enhancement vanishes when the excitation wavelength is larger than the widened band gap of Si nanocrystal. Time-resolved PL decay measurements reveal that the lifetime of the photo-excited carriers in the hybrid β-FeSi2/Si film is longer than that in the pure β-FeSi2 film, providing evidence that the PL enhancement results from the resonant charge transfer from nanocrystalline Si to β-FeSi2. 相似文献
994.
《光学学报》2021,41(4):131-140
设计了一种基于纳米线波导和一维光子晶体纳米梁腔的模分-波分混合解复用器,该器件由波分解复用(WDM)和模分解复用(MDM)两部分组成。其中,波分解复用部分由两个一维光子晶体纳米梁腔构成,模分解复用部分采用硅基纳米线波导结构。利用三维时域有限差分法,计算分析了该混合解复用器的性能参数。结果表明,该器件可以在波长1570.0 nm和1573.2 nm处实现基模(TE_0)和一阶模(TE_1)四个信道的解复用功能,插入损耗小于0.37 dB,信道串扰小于-18.4 dB,自由光谱范围可以达到400 nm。该混合解复用器可以应用于模分-粗波分复用系统中。 相似文献
995.
996.
以混合表面活性剂为模板可控合成MCM-48和MCM-41分子筛 总被引:2,自引:0,他引:2
利用阳离子和三嵌段共聚物混合表面活性剂为模板,在水热条件、碱性介质中可控合成出MCM-48和MCM-41分子筛。在固定P123(聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物):TEOS(正硅酸乙酯)(物质的量的比)为0.01875的体系中,调节CTAB(十六烷基三甲基溴化铵)∶TEOS(正硅酸乙酯)物质的量比值m,当m在0.12~0.13范围合成出MCM-48分子筛;当m在0.04~0.08范围合成出MCM-41分子筛。通过XRD,TEM,N2物理吸附,IR等方法进行了表征。结果表明:聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物(P123)的加入可以更大程度地降低合成介孔材料所需阳离子表面活性剂的用量;可控合成的介孔材料具有高比表面积、高度有序的孔道结构、较集中的孔径分布。 相似文献
997.
研究了几种纤维素混合醚酯的制备及其高压静电场纺丝性能,分析了溶剂组成、溶液浓度、分子量、酯化基团对成纤性和纤维直径的影响。结果表明:在非均相条件下,经过碱化、醚化与酯化,得到不同结构的纤维素混合醚酯HPMCP、HPMCT与HPMCAS,均可实现静电纺丝;在甲醇/二氯甲烷=1∶4的溶剂体系中易得到表面光滑纤维;在溶剂组成一定条件下,溶液仅在一定浓度范围可纺,且浓度越低、纺丝电压越高,纺丝平均直径越小;当溶剂组成、溶液浓度一定时,分子量对其溶液纺丝的可纺性有直接影响,HPMCAS仅重均分子量达到7.2×104才能获得表面光滑纺丝纤维;在溶剂组成、溶液浓度和分子量一定的条件下,相邻酰基间距离越小,酸性越强,溶液电导率越大,丝越细。 相似文献
998.
Mixed ammonium-transition metal salts with formula of (NH4)xMyHzPMo12O40 (M = Ni2+, Co2+ or Fe 3+) denoted as MPMo12 have been investigated for the oxidation of propane, with molecular oxygen, at temperature range between 380℃ and 420℃ after in-situ pre-treatment performed at two heating rate of 5 or 9℃/min. They were characterized by BET method, XRD, UV-Vis and IR techniques. The catalysts were found to be active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-t... 相似文献
999.
XPS study of potassium-promoted molybdenum carbides for mixed alcohols synthesis via CO hydrogenation 下载免费PDF全文
The X-ray photoelectron spectroscopy (XPS) was used to investigate the surface characteristic of potassium-promoted or un-promoted both β-Mo_2C and α-MoC_(1-x) pretreated by syngas at different temperatures, and the promotional effect of potassium on the catalytic performance was also studied. XPS results revealed that the content of surface Mo and its valence distribution between β-Mo_2C and α-MoC_(1-x) were quite different. Promoted by potassium, the remarkable changes were observed for surface composition and valence of Mo distribution over β-Mo_2C. Potassium had strong electronic effect on β-Mo_2C, which led to a higher Mo~(4+) content. On the contrary, potassium had little electronic effect on α-MoC_(1-x), and K-Mo interaction was weak. Therefore, Mo~0 and Mo~(2+) became the dominant species on the catalyst surface, and the Mo~(4+) content showed almost no increase as the pretreatment temperature enhanced. In terms of catalytic performance of molybdenum carbides, the increase in Mo~0 most likely explained the increase in hydrocarbon selectivity, yet Mo~(4+) might be responsible for the alcohols synthesis. 相似文献
1000.
Oxidative dehydrogenation of propane under steady-state and transient regimes over alumina-supported catalysts prepared from mixed V_2W_4O_(19)~(4-) hexametalate precursors 下载免费PDF全文
Sébastien Paul Elise Berrier Marcia Cristina Kaezer Frana Jean-Guillaume Eon 《天然气化学杂志》2010,19(2):123-133
An integrated approach combining the development of an innovative catalyst and the research of a set of adequate operating conditions for the propane oxidative dehydrogenation (ODH) is described. The experimental set-up, specially designed for steady-state and transient studies is presented. The preparation method, the characterization and the performances in steady-state and transient regimes of catalysts based on V_2W_4O_(19)~(4-) Lindqvist isopolyanion used as a precursor and supported on alumina are reported. The influence of the preparation method of the catalyst and the role of water in the feed gas are more particularly discussed. 相似文献