NaYF4 微晶与纳米晶中晶相对Tb3+ -Er3+ 耦合对下转换的影响

实验研究了晶相对下转换的影响。Tb³⁺ -Er³⁺ 耦合对将一个紫外光子(Tb³⁺ 的⁷F₆→⁵L₁)294 nm 剪裁成800 nm (Er³⁺ 的⁴I_9/2→⁴I_15/2) 和467 nm (Tb³⁺ 的⁵D₄→⁷F₆) 两个都能被GaAs 太阳能电池吸收的低能光子。采用水热法制备了NaYF₄六角相微晶和立方相纳米晶粒子,六角相由于具有热力学稳定性和有序的排列结构而更有利于量子剪裁过程的发生,相反在立方相结构中没有发现量子剪裁现象。分别采用294 nm 和355 nm波长的光对六角相NaYF₄进行激发,从发射光谱可以看出,下转换的实现是通过一个交叉弛豫过程完成的。实验结果表明,与熔融法相比,用水热法制备的NaYF₄ 的量子产率明显降低。     

《发光学报》征稿内容

《发光学报》是中国物理学会发光分会、中国科学院长春光学精密机械与物理研究所主办的,以发光学、凝聚态物质中的激发态过程为专业方向的综合性学术刊物。本刊适用于凝聚态物理、光学材料合成、环境保护、化学化工、国防、医药等领域的科学研究单位、高等院校、制造厂家、从事发光学与光学材料开发的研究人员、高校有关专业的师生等。刊登的主要学术内容包括:     

粉末粒度离散性对NdFeB磁性能的影响

制备了一种NdFeB永磁材料,探讨了制粉前处理方式对粉末离散性、粒径及成品NdFeB永磁体结构与性能的影响。原材料经熔炼、粗破碎后,采用高速风选和高压氢爆2种制粉前处理方式,然后采用同样的成型、烧结和回火工艺制备得到(PrNd)32.3Nb0.70Al0.60Cu0.20B1.03Fe65.17合金,并系统研究了该合金的显微结构和磁性能。结果表明:高压氢爆处理后得到的粉末粒度呈单分散性,粉末粒径较细,所制备得到的磁体样品的微观结构均匀性也较好;高压氢爆处理后制得的磁体样品剩余磁通密度比高速风选制粉方式得到的磁体样品高0.047 T,内禀矫顽力高 193.4 kAm－1,最大磁能积高24.6 kJm－３。     

Curvelet结合图像方向离散度的DSPI无损检测缺陷边缘提取

边缘提取是DSPI无损检测缺陷自动识别的基础。根据人类视觉识别的特点,提出以Curvelet多尺度几何分析为基础进行缺陷图像的边缘提取,为了对DSPI检测过程中因光照不足等原因产生的伪缺陷进行分辨,基于矢量积定义了图像的方向离散度,并与Curvelet多尺度分析方法相结合,在橡胶复合材料DSPI无损检测中进行应用。     

Ni-BaZr0.1Ce0.7Y0.2O3-δ金属-陶瓷中空纤维膜的氢渗透性能

通过将相转化法制备的Ni-BaZr_0.1Ce_0.7Y_0.2O_3-δ(BZCY)纤维膜生坯在5%H₂/95%Ar混合气体中直接烧结, 制备出了气密具有“三明治”结构的Ni-BZCY金属陶瓷中空纤维膜. 靠近内外表面是指状孔结构而中间部分是致密层. 当膜管外湿润的20%H₂/80%N₂混合气体流量是200 mL/min,膜管内高纯Ar气的流量是150 mL/min时,Ni-BZCY中空纤维膜的氢渗透率达到了0.53 μmol/cm²s.     

硫脲21A激发态扭曲几何结构的共振拉曼光谱和理论研究

获得了硫脲在水和乙腈溶液中A吸收带的共振拉曼光谱,通过B3LYP/6-311++G(3df,3pd)和RCIS/6-311++G(3df,3pd)分别对硫脲的电子跃迁和2¹A 激发态鞍点结构进行了研究．对共振拉曼光谱进行了归属,并通过含时波包理论对吸收光谱和共振拉曼光谱进行拟合,结果表明硫脲动态结构特征主要沿着：C=S伸缩振动ν₆(|△|=0.95)、H₅N₃H₆+H₈N₄H₇弯曲振动ν₅(|△|=0.19)、NCN对称伸缩振动+C=S伸缩振动+N₃H₆+H₈N₄弯曲振动ν₄(|△|=0.18)．ν₁₅倍频2ν₁₅和4ν₁₅强度主要归因于ν₁₅激发态频率的改变而不是简正模位移量的变化．对S=CN₂面外变形振动ν₁₅倍频出现的机理进行了探究,结果表明Franck-Condon区域势能面鞍点是标准A项共振拉曼散射里的二次声子机制的驱动力,导致碳原子中心的锥形化,并使硫脲在2¹A激发态发生几何结构扭曲.     

氢稀释对纳米晶硅薄膜晶化特性的影响及薄膜生长机理

以SiH4与H2作为前驱气体,采用射频等离子增强化学气相沉积技术制备了纳米晶硅薄膜.利用Raman散射和红外吸收光谱等技术,对不同氢稀释比条件下薄膜的微观结构和键合特性进行了研究.结果表明,随着氢稀释比增加,薄膜的晶化率明显提高,而氢稀释比过高时,薄膜晶化率呈现减少趋势.红外吸收光谱分析表明,纳米晶硅薄膜中氢的键合模式与薄膜的晶化特性密切相关.随着氢稀释比增加,薄膜中整体氢含量和SiH2键合密度明显减少,而在高氢稀释比条件下,氢稀释比增加导致薄膜中SiH2键合密度和整体氢含量增加.     

Modal interferometer based on tapering single-mode-multimode-single-mode fiber structure by hydrogen flame

A modal interferometer is experimentally demonstrated based on tapering a single-mode-multimode-singlemode (SMS) fiber structure heated by hydrogen flame.The interference fringe begins to form when tapering length is 19.8 mm,and becomes regular and clear when the tapering length is longer and the tapered waist diameter is smaller.Annealing process is undertaken to achieve a high extension ratio of approximately 17 dB with free spectral range of 1.5 nm when the tapering length is 33 mm and the tapered waist diameter is approximately 5μm.The temperature and axial strain dependences of the tapered SMS structure are characterized,and the measured temperature and strain coefficients are +7 pm/℃and -9.536 pm/με, respectively.     

Dual-channel phase-shifting interferometry for microscopy with second wavelength assistance

Dual-channel phase-shifting interferometry for simultaneous phase microscopy is presented. Red and blue light beams are used for microscope illumination. A 45 tilted beamsplitter replicates the object and reference waves in red light together with the object wave in blue light into two parallel beams. The two resulting quadrature phase-shifting interferograms in red light and the object waves in blue light are generated in the two channels. The two interferograms are recorded simultaneously by a color charge-coupled device (CCD) camera, and can be separated via RGB components of the recorded color patterns without crosstalk. As a result, the phase of tested specimen can be retrieved. The feasibility of the proposed method is demonstrated by test performed on a microscopic specimen.     

Research on a middle infrared and long infrared dual-band laser

We propose a continuous-wave(CW)middle infrared(MIR)and long infrared(LIR)dual-band laser for the calibration and effect research of infrared detecting and imaging systems.A total output power of 18 W is achieved by the proposed dual-band laser through one DF gain medium module and one parallel placed CO2 gain medium module using a common stable resonator and output mirror with nominal transmissivities of ～5%in the MIR band and～10%in the LIR band.Spectra of dual-band laser are acquired.The power extracting efficiency of this dual-band laser can be significantly improved,as validated by a single-band test of optimized parameters.