全文获取类型
收费全文 | 8897篇 |
免费 | 1715篇 |
国内免费 | 4200篇 |
专业分类
化学 | 9142篇 |
晶体学 | 149篇 |
力学 | 318篇 |
综合类 | 212篇 |
数学 | 234篇 |
物理学 | 4757篇 |
出版年
2024年 | 74篇 |
2023年 | 251篇 |
2022年 | 286篇 |
2021年 | 305篇 |
2020年 | 250篇 |
2019年 | 337篇 |
2018年 | 214篇 |
2017年 | 312篇 |
2016年 | 370篇 |
2015年 | 376篇 |
2014年 | 687篇 |
2013年 | 569篇 |
2012年 | 648篇 |
2011年 | 637篇 |
2010年 | 607篇 |
2009年 | 688篇 |
2008年 | 780篇 |
2007年 | 672篇 |
2006年 | 710篇 |
2005年 | 568篇 |
2004年 | 601篇 |
2003年 | 525篇 |
2002年 | 498篇 |
2001年 | 444篇 |
2000年 | 337篇 |
1999年 | 370篇 |
1998年 | 287篇 |
1997年 | 286篇 |
1996年 | 285篇 |
1995年 | 310篇 |
1994年 | 246篇 |
1993年 | 231篇 |
1992年 | 248篇 |
1991年 | 207篇 |
1990年 | 206篇 |
1989年 | 183篇 |
1988年 | 71篇 |
1987年 | 39篇 |
1986年 | 35篇 |
1985年 | 18篇 |
1984年 | 16篇 |
1983年 | 21篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
Laser-diode excited intense upconversion luminescence of Er^3+ in bismuth-lead-germanate glasses 下载免费PDF全文
We have investigated infrared-to-visible upconversion luminescence of Er^3+ in bismuth-lead-germanate glasses. The UV cutoff wavelength is shortened while its lifetime is increased almost linearly, with PbF2 substituting for PbO in the bismuth-lead germanate glasses. Three emissions centred at around 529, 545 and 657 nm are clearly observed, which are identified as originating from the ^2H11/2→^4 I15/2,^4S3/2→^4 I15/2 and ^4 F9/2 →^4 I15/2 transitions, respectively. It is noted that all the upconversion emission intensities increase with PbF2 concentration increasing. The ratio between the intensities of red and green emissions increases with the increasing of PbF2 content. Energy transfer processes and nonradiative phonon-assisted decays account for the populations of the ^2 H11/2,^4 S3/2 and ^4F 9/2 levels. The quadratic dependence of fluorescence on excitation laser power confirms a two-photon process to contribute to the upconversion emissions. 相似文献
982.
We present an experimentally feasible one-step discrimination scheme on Bell bases with trapped ions, and then generalize it to the case of N-ion Greenberger-Horne-Zeilinger (GHZ) bases. In the scheme, all the orthogonal and complete N-ion GHZ internal states can be exactly discriminated only by one step, and thus it takes very short time. Moreover, the scheme is insensitive to thermal motion and dose not require the individual addressing of the ions. The Bell-state and GHZ-state one-step discrimination scheme can be widely used in quantum information processing based on ion-trap set-up. 相似文献
983.
Investigation on improving characteristics of two-cell SBS system with CCl4/C2H5OH liquid mixture 下载免费PDF全文
In order to improve the performance of the two-cell stimulated Brillouin scattering (SBS) system, this paper proposes the methods of using mixtures, which require amplifier media to have small absorption rate, and generator media to have high optical breakdown threshold and Brillouin frequency shift equal to that of the amplification media. The characteristics of the two-cell SBS system are studied experimentally by using CCl4 as amplifier medium and CCl4, C2H5OH and CCl4/C2H5OH liquid mixture as generator medium pumped by Nd:YAG Q-switched laser. The obtained results show that liquid mixture in generator cell improves the power load ability, phase conjugation fidelity, energy reflectivity (ER) and ER stability. 相似文献
984.
Synthesis and characterization of Ca2Sn1-xCexO4 with blue luminescence originating from Ce^4+ charge transfer transition 下载免费PDF全文
Ce^4+-doped Ca2SnO4 with a one-dimensional structure, which emits bright blue light, is prepared by using a solid-state reaction method. The x-ray diffraction results show that the Ce^4+ ions doped in Ca2SnO4 occupy the Sn^4+ sites. The excitation and emission spectra of Ca2Sn1-xCexO4 appear to have broad bands with peaks at - 268nm and -442nm, respectively. A long excited-state lifetime (-83μs) for the emission from Ca2Sn1-xCexO4 suggests that the luminescence originates from a ligand-to-metal Ce^4+ charge transfer (CT). The luminescent properties of Ca2Snl_xCexO4 have been compared with those of Sr2CeO4, which is the only material reported so far to show Ce^4+ CT luminescence. More interestingly, it is observed that the emission intensity of Ca2Sn1-xCexO4 with a small doping concentration (x - 0.03) is comparable to that of Sr2CeO4 in which the concentration of active centre is 100%. 相似文献
985.
用全相对论多组态自洽场方法,计算了高离化类铥铋原子BiXV的1s、2s、2p-、2p、3s、3p-、3p、3d-、3d、4s、4p-、4p、4d-、4d、4f-、4f、5s、5p-、5p、5d-、5d、5f-、5f、5g-、5g、6s、6p-、6p、6d-、6d、6f-、6f、6g-、6g、7s、7p-、7p、7d-、7d、7f-、7f、7g-、7g、8s、8p-、8p、8d-、8d轨道的2249个精细结构能级和辐射寿命以及其他各种跃迁参数.能级和波长的计算值和实验值符合得好.另外还发现了一些辐射寿命较长的亚稳态能级. 相似文献
986.
采用射频反应磁控溅射法在玻璃衬底上成功制备出具有c轴高择优取向的ZnO薄膜,利用X射线衍射及紫外-可见吸收和透射光谱研究了氧分压变化对ZnO薄膜的微观结构及光吸收特性的影响。结果表明,当工作气压恒定时,用射频反应磁控溅射制备的ZnO薄膜的生长行为主要取决于成膜空间中氧的密度,合适的氧分压能够提高ZnO薄膜的结晶质量;薄膜在可见光区的平均透过率达到90%以上,且随着氧分压的增大,薄膜的光学带隙发生了一定程度的变化。采用量子限域模型对薄膜的光学带隙作了相应的理论计算,计算结果与对样品吸收谱所作的拟合结果符合较好,二者的变化趋势完全一致,表明ZnO纳米晶粒较小时,薄膜光学带隙的变化与量子限域效应有很大关系。 相似文献
987.
988.
通过测试掺铒铋酸盐玻璃43Bi2O3-xB2O3-(57-x)SiO2(x=10,20,30,40,50mol%)中Er^3+离子的吸收光谱、荧光光谱、荧光寿命及荧光强度,结合Judd—Ofelt和McCumber理论,对玻璃中Er^3+离子光谱性质随玻璃组分的依赖关系进行了系统研究.研究结果显示,掺铒铋酸盐玻璃具有较其它玻璃优异的光谱性质.随着玻璃中组分B2O3含量的增加,强度参量Ω6、荧光半高宽和能级^4I15/2→^4I13/2间自发辐射跃迁几率相应增加,而荧光寿命、荧光强度和受激发射峰值截面相应减小,带宽品质因子(σe^pcak×FWHM)在组分B2O3含量30mol%时达到最大. 相似文献
989.
We present a method by which to determine the bulk viscosity of water from pulse duration measurements of stimulated Brillouin scattering (SBS). Beginning from a common model of Brillouin scattering, the bulk viscosity is shown to play an important role in Brillouin linewidth determination. Pulse durations of SBS back-reflected optical pulses are measured over the temperature range of 5-40℃. SBS linewidths are de- termined via Fourier transformation of the time-domain results, and the bulk viscosity of water is measured and derived from the obtained values. Our results show that the proposed method for measurement of pulse durations is an effective approach for determining bulk viscosity. The method can be easily extended to determine bulk viscosities of other Newtonian liquids. 相似文献
990.
The watermiscible room temperature ionic liquid 1butyl3methylimidazolium tetrafluorob orate ([bmim] [BF4]) is a model system for studying the interactions between ionic liquid and water molecules. In this work the orientational structure of the low concentrated aqueous solution of [bmim] [BF4] at the air/liquid interface was investigated by sum frequency gener ation vibrational spectroscopy. It has been found that at very low concentrations, the butyl chain exhibited a significant gauche defect, indicating a disordered conformation; and the cation ring oriented with a fairly small tilting angle at the surface. When the concentration increased, the cation ring tended to lie flat at the surface, and the gauche defects of the butyl chain decreased due to the intermolecular chainchain interactions and the consequent more ordered interfacial molecular arrangement. Additionally, the antisymmetric stretching mode in the PPP and SPS spectra exhibited a peak shift, showing that there exists more than one kind of orientation or chemical environment for the butyl CH3 group. These results may shed new light on understanding the surface behavior of watermiscible ionic liquids as well as the imidazolium based surfactants. 相似文献