氧分压对磁控溅射制备ZnO薄膜的结构及光学特性的影响

采用射频反应磁控溅射法在玻璃衬底上成功制备出具有c轴高择优取向的ZnO薄膜,利用X射线衍射及紫外-可见吸收和透射光谱研究了氧分压变化对ZnO薄膜的微观结构及光吸收特性的影响。结果表明,当工作气压恒定时,用射频反应磁控溅射制备的ZnO薄膜的生长行为主要取决于成膜空间中氧的密度,合适的氧分压能够提高ZnO薄膜的结晶质量;薄膜在可见光区的平均透过率达到90%以上,且随着氧分压的增大,薄膜的光学带隙发生了一定程度的变化。采用量子限域模型对薄膜的光学带隙作了相应的理论计算,计算结果与对样品吸收谱所作的拟合结果符合较好,二者的变化趋势完全一致,表明ZnO纳米晶粒较小时,薄膜光学带隙的变化与量子限域效应有很大关系。     

磁控溅射制备ZnO薄膜的结构及发光特性研究

采用射频反应磁控溅射法在玻璃衬底上制备出具有c轴高择优取向的ZnO薄膜,利用X射线衍射、扫描探针显微镜及荧光分光光度法研究了生长温度对ZnO薄膜微观结构及光致发光特性的影响。结果表明,合适的衬底温度有利于提高ZnO薄膜的结晶质量;在室温下测量样品的光致发光谱(PL),观察到波长位于400 nm左右的紫光、446 nm左右的蓝色发光峰及502 nm左右微弱的绿光峰,随衬底温度升高,样品的PL谱中紫光及蓝光强度逐渐增大,同时,绿光峰的强度也表现出一定程度的增强。经分析得出紫光应是激子发光所致,而锌填隙则是引起蓝光发射的主要原因,502 nm左右的绿光峰应该是氧的深能级缺陷造成的。此外,还测量了样品的吸收谱,并结合样品吸收谱的拟合结果对光致发光机理的分析作了进一步的验证。     

Engineering of electronic and optical properties of ZnO thin films via Cu doping

ZnO thin films doped with different Cu concentrations are fabricated by reactive magnetron sputtering technique. XRD analysis indicates that the crystal quality of the ZnO:Cu film can be enhanced by a moderate level of Cu-doping in the sputtering process. The results of XPS spectra of zinc, oxygen, and copper elements show that Cu-doping has an evident and complicated effect on the chemical state of oxygen, but little effect on those of zinc and copper. Interestingly, further investigation of the optical properties of ZnO:Cu samples shows that the transmittance spectra exhibit both red shift and blue shift with the increase of Cu doping, in contrast to the simple monotonic behavior of the Burstein–Moss effect. Analysis reveals that this is due to the competition between oxygen vacancies and intrinsic and surface states of oxygen in the sample. Our result may suggest an effective way of tuning the bandgap of ZnO samples.     

光拍频法测光速实验的改进

光速的测定是物理学中一个十分重要的课题,文章介绍光拍法测光速原理,结合现有实验仪器,对原有光拍频法测光速的公式加以变换,光速测量的精度有了很大提高。     

Tunable second-order sideband effects in hybrid optomechanical cavity assisted with a Bose—Einstein condensate

We theoretically investigated a second-order optomechanical-induced transparency (OMIT) process of a hybrid optomechanical system (COMS), which a Bose—Einstein condensate (BEC) in the presence of atom—atom interaction trapped inside a cavity with a moving end mirror. The advantage of this hybrid COMS over a bare COMS is that the frequency of the second mode is controlled by the s-wave scattering interaction. Based on the traditional linearization approximation, we derive analytical solutions for the output transmission intensity of the probe field and the dimensionless amplitude of the second-order sideband (SS). The numerical results show that the transmission intensity of the probe field and the dimensionless amplitude of the SS can be controlled by the s-wave scattering frequency. Furthermore, the control field intensities, the effective detuning, the effective coupling strength of the cavity field with the Bogoliubov mode are used to control the transmission intensity of the probe field and the dimensionless amplitude of the SS.     

退火温度对Zn0.93Fe0.07O薄膜微结构和铁磁性能的影响

用射频磁控溅射方法在硅片上制备了Zn0.93Fe0.07O薄膜,并在空气中用不同温度进行热处理,利用X射线衍射仪和扫描电子显微镜对其微结构、表面和断面形貌进行测试.结果表明,薄膜沿c轴方向择优生长,呈六角纤锌矿结构,空气中450℃退火的样品XRD谱中出现最强的(002)衍射峰,晶粒尺寸变大,薄膜结晶和取向明显变好.用振动样品强磁计对样品铁磁特性进行测试,发现当退火温度的升高时,饱和磁化强度有所增加,并经分析认为这可能是薄膜中晶粒间的晶界缺陷引起的.     

圆钢管型钢再生混凝土组合柱滞回性能非线性有限元分析

基于圆钢管型钢再生混凝土组合柱低周反复荷载试验研究,采用OpenSees软件对该组合柱进行了滞回性能数值分析,获取了组合柱的滞回曲线及抗震性能指标,并与试验结果进行了比较,验证了组合柱数值模型的合理性。在此基础上,对组合柱的滞回性能开展了参数影响分析。结果表明：再生骨料取代率从0增大到100%,组合柱的峰值荷载下降了7.78%,延性略有降低;提高再生混凝土强度、型钢强度及圆钢管强度,对于提升组合柱的承载力及刚度是有利的,但却使组合柱的脆性增大;随着轴压比的增大,组合柱的承载力呈现先上升后下降的趋势,而延性逐渐变差;型钢配钢率从5.54%增至9.99%,组合柱的峰值荷载提高了24.34%,但对于改善组合柱的延性不明显;增大钢管壁厚对组合柱的承载力和延性均是有利的。