Temperature-dependent photoluminescence of CuInS2 quantum dots

Temperature-dependent photoluminescence (PL) spectroscopy of CuInS₂ core and CuInS₂/ZnS core–shell quantum dots (QDs) was studied for understanding the influence of a ZnS shell on the PL mechanism. The PL quantum yield and lifetime of CuInS₂ core QDs were significantly enhanced after the QD surface was coated with the ZnS shell. The temperature dependences of the PL energy, linewidth, and intensity for the core and core–shell QDs were studied in the temperature range from 92 to 287 K. The temperature-dependent shifts of 98 meV and 35 meV for the PL energies of the QDs were much larger than those of the excitons in their bulk semiconductors. It was surprisingly found that the core and core–shell QDs exhibited a similar temperature dependence of the PL intensity. The PL in the CuInS₂/ZnS core–shell QDs was suggested to originate from recombination of many kinds of defect-related emission centers in the interior of the cores.     

分光光度法测定铁合金中的磷

以含磷较低的铁合金作底液,以钼酸铵为显色剂,用磷钼蓝光度法测定铁合金中的磷。磷钼蓝的摩尔吸光系数为7.8×10~5L/(mol·cm),与磷钼黄光度法、氟化钠-氯化亚锡还原磷钼蓝光度法相比,测定灵敏度有不同程度的提高。该方法用于实际样品分析,结果准确、可靠。     

杆件撤除对平面刚架影响的实用计算法

基于短阵位移法,提出了用于分析杆件撤除对平面刚架结构影响的简化计算方法,与以往不同,本法仅将杆件撤除视为在原结构上曾加荷载工况,因此无需重建况体刚度矩阵即可用于分析杆件撤除对结构的影响,本法的计算速度比矩位移法快很多,算例表明,两种方法的计算结果一致。     

一种天然气直接转化制乙烯的新过程

Many routes for the direct conversion of methane have been explored to utilize a bundant natural gas resources.     

非线性自然弯扭闭口薄壁复合梁的广义变分原理

对复合材料自然弯扭闭口薄壁细长梁在小应变、大位移和大转动的情况作了研究,建立了两端边界均为完全约束的该梁大变形弹性理论的非完全广义变分原理的泛函。由泛函驻值条件可以导出所给问题的平衡方程及全部边界条件。上述方法可方便地推广到其它各种不完全约束边界的情况。此外,利用上述结果还可以得到该梁在小位移理论中的基本方程和有关公式。     

丙三醇对水溶液中血红蛋白构象的影响——荧光猝灭和动态光散射研究

利用荧光猝灭法和动态光散射法测定丙三醇-水混合溶剂中血红蛋白(Hb)与联苯胺的结合距离和Hb的流体动力学半径, 并通过分析Hb荧光光谱和吸收光谱的变化, 探讨丙三醇与蛋白质分子在水溶液中相互作用的机理及其对蛋白质构象的影响. 结果表明, 丙三醇-水混合溶剂中Hb通过优先水化作用形成更紧密的构象, 溶剂体系的氢键形成能力下降对稳定蛋白质的构象有重要的影响, 丙三醇浓度较高的混合溶剂中氢键网络发生崩塌, 导致蛋白质构象产生进一步的折叠. 实验显示, 尽管Hb在丙三醇-水混合溶剂中保持较完整的血红素疏水空穴结构, 但是血红素疏水空穴以外肽段的构象发生显著变化, 并对血红蛋白的聚集状态造成一定的影响.     

新课程背景下如何在初中化学教学中渗透人文教育

“在化学教学中渗透人文精神”已有不少老师发表过教研成果。新的课程改革给教师和学生带来了很多契机。本文结合实例从多方面探讨在初中化学教学中渗透人文教育的一些新尝试。     

A Study on Microwave Induced Plasma Ionization Detector for Gas Chromatograph

Among various ionization detectors for gas chromatography(GC), the most promising one is perhaps the nonradioactive ionization detector which makes use of a microwave induced plasma(MIP). The use of MIP for gas chromatography was first studied by McCormack, et al. in 1965, Freeman developed a photoionization detector utilizing helium microwave discharge. In 1971, we developed a microwave     

DEHYDROGENATIVE COUPLING OF METHANE UNDER PULSE CORONA PLASMA OVER A MnO|?/|?-A12O3 CATALYST

Pulse corona plasma was used as an activation method fordehydrogenative coupling of methane at the normal temperature and under' the normal pressure. The exprimental results showed that a great enhancement in the selectivity to C2 was achieved by the combination of pulse corona plasma with a y-Mn2OO3/Y-A12O3 catalyst. The distribution of C2 hydrocarbons was mainly affected by the power input and the nature of the catalyst. In addition, the gas stream direction exerted an influence upon the C2 yield, especially at higher power input.     

铜锆中间合金中铜、锆含量的联合测定

研究了铜锆中间合金中铜、锆的测定方法。试样经高氯酸、硝酸分解后,采用电解法测定铜:分离铜后的电解液,经盐酸处理后以二甲酚橙为指示剂,用EDTA标准溶液滴定测定锆。该方法简便,具有良好的精密度和准确度,相对标准偏差分别为铜0.19％。锆0.15％。