基于自由基配体的Dy(Ⅲ)配合物的设计、合成、结构及磁性

以氮氧自由基为配体,合成了2例未见文献报道的氮氧自由基-稀土配合物[Dy（hfac）₃（NIT-C₃H₅）（H₂O）]与[Dy（hfac）₃（NIT-C₃H₅）]_n（hfac=六氟乙酰丙酮,NIT-C₃H₅=2-环丙烷基-4,4,5,5-四甲基-2-咪唑啉-3-氧化-1-氧基自由基）。单晶结构分析表明配合物1为单核结构,单斜晶系P2₁/c空间群;配合物2为一维结构,单斜晶系P2₁/c空间群。交流磁化率测试结果表明配合物2虚部表现出频率依赖,这表明配合物2是单链磁体。     

Characterization of inner layer thickness change of a composite circular tube using nonlinear circumferential guided wave:A feasibility study

The feasibility of using the nonlinear effect of primary circumferential guided wave (CGW) propagation for characterizing the change of inner layer thickness of a composite circular tube (CCT) has been investigated. An appropriate mode pair of the fundamental and double-frequency CGWs (DFCGWs) has been selected to enable the second harmonics of primary wave mode in the given CCT to accumulate along the circumferential direction. When changes in the inner layer thickness (described as the equivalent inner layer thickness) take place, the corresponding nonlinear CGW measurements are conducted. It is found that there is a direct correlation between change of equivalent inner layer thickness of the CCT and the relative acoustic nonlinearity parameter (Δβ) measured with CGWs propagating through one full circumference, and that the effect of second-harmonic generation (SHG) is very sensitive to change in the inner layer thickness. The experimental result obtained demonstrates the feasibility for quantitatively assessing the change of equivalent inner layer thickness in CCTs using the effect of SHG by primary CGW propagation.     

How Does van der Waals Confinement Enhance Phonon Transport?

We study the mechanism of van der Waals(vdW)interactions on phonon transport in atomic scale,which would boost developments in heat management and energy conversion.Commonly,the vdW interactions are regarded as a hindrance in phonon transport.Here we propose that the vdW confinement can enhance phonon transport.Through molecular dynamics simulations,it is realized that the vdW confinement is able to make more than two-fold enhancement on thermal conductivity of both polyethylene single chain and graphene nanoribbon.The quantitative analyses of morphology,local vdW potential energy and dynamical properties are carried out to reveal the underlying physical mechanism.It is found that the confined vdW potential barriers reduce the atomic thermal displacement magnitudes,leading to less phonon scattering and facilitating thermal transport.Our study offers a new strategy to modulate the phonon transport.     

用于储罐底板缺陷检测的超声兰姆波模式研究

从超声兰姆波的声场方程出发,得到板材表面离面位移(法向位移)为零的条件,即当超声兰姆波的相速度等于板材介质的纵波声速时,在板材表面的离面位移为零。在给定适当频厚积的条件下,分别数值模拟了仅有切向位移而无离面位移的A1、S1、A2和S2兰姆波模式在有液体负载的单层钢板中的传播情形。结果表明:离面位移为零的S2模式频散较小且对板中缺陷更为敏感。     

Ca2Li2BiV3O12∶Eu3+荧光粉的制备和发光性能

采用高温固相法成功合成了一种可用于白光LED的Ca₂Li₂BiV₃O₁₂∶Eu³⁺新型红色荧光粉,使用X射线衍射仪和荧光分光光度计对合成样品进行了表征,研究了合成温度和Eu³⁺含量对合成样品相组成和发光性能的影响。结果表明,采用高温固相法在650~700 ℃能合成纯度较高、结晶度好的Ca₂Li₂BiV₃O₁₂∶Eu³⁺荧光粉,合成样品激发带覆盖200~400 nm,发射光谱的线状发射峰可归属于Eu³⁺的⁵D₀→⁷F_J(J= 1, 2, 3,4)特征锐线发射,Eu³⁺摩尔分数为14%时荧光粉的发光强度最大。     

A novel superjunction MOSFET with improved ruggedness under unclamped inductive switching

The ruggedness of a superjunction metal–oxide semiconductor field-effect transistor (MOSFET) under unclamped inductive switching conditions is improved by optimizing the avalanche current path. Inserting a P-island with relatively high doping concentration into the P-column, the avalanche breakdown point is localized. In addition, a trench type P+ contact is designed to shorten the current path. As a consequence, the avalanche current path is located away from the N+ source/P-body junction and the activation of the parasitic transistor can be effectively avoided. To verify the proposed structural mechanism, a two-dimensional (2D) numerical simulation is performed to describe its static and on-state avalanche behaviours, and a method of mixed-mode device and circuit simulation is used to predict its performances under realistic unclamped inductive switching. Simulation shows that the proposed structure can endure a remarkably higher avalanche energy compared with a conventional superjunction MOSFET.     

Synthesis and Structure of E-2-(2,4,6-tri tert butylphenylphosphinyl)-2-〔N-(tert-butyldimethylsilyl)-N-(p-chrolophenyl)〕amino-1-(2,4,6-tri tert-butyl-phenyl)phosphacthylene

1　INTRODUCTIONItwaswellknown thatelementsofthesecondary and higherrow are in generaldifficulty to form multiplebondsin which apπ hybridized stateisinvolved〔1〕.Thus,simple compounds containing multiple phosphorus carbon bonds,such as methyl dynephosphine( HC≡P) 〔2 - 3〕 and methylenephosphine( H2 C=PH〔4〕,are notstableat room temperature.Three methods to stabilize compounds containing double ormultiple bond involving phosphorusatom in the pπ hybridized state are often used.The f…     

基于半导体泵浦倍频绿光激光器的探究性实验设计

为探究在谐振腔中倍频晶体位置对绿光激光器输出功率的影响，利用半导体泵浦固体激光实验仪设计了腔内和腔外倍频绿光的探究性实验。分析了绿光倍频效率与基频光束的功率密度及光斑半径之间的关系，分别测量了磷酸钛氧钾(KTP)倍频晶体位于谐振腔內部和外部不同位置时，532 nm倍频绿光的输出功率。其中在腔外倍频实验中，分别设计了腔外不加透镜时KTP晶体位于腔外不同位置，以及加上透镜时KTP晶体位于聚焦位置两种实验方案。同时，在实验中引导学生利用谐振腔理论和高斯光束传输理论等激光原理计算1 064 nm基频光在腔内外不同位置的光斑半径，分析了KTP晶体在不同位置时532 nm倍频光输出功率出现差别的原因，以及利用透镜聚焦提高激光功率密度以达到提高倍频效率的方法。     

Site-specifically Hydrolytic Cleavage of Oxidized Insulin B Chain With Cu(II) Ion

Selectively chemical cleavage of peptides and proteins is one of the most important reactions in both chemical and biochemical processes. Over the past decade, the interaction of palladium(II) complexes with methionine, cysteine and histidine-containing peptides and proteins and the hydrolytic cleavage of the corresponding amide bond by Pd(II) complexes have been extensively studied1-13. However, reports concerning the directly selective hydrolysis of peptides and proteins with other simple …