C.I.颜料红177中间体的制备工艺改进

本文较为系统地研究了铜粉催化剂加入方式对C.I.颜料红177中间体4,4'-二氨基-1,1'-二蒽醌-3,3'-二磺酸(DAS)合成过程中的乌尔曼偶联反应速率的影响规律。 研究结果表明,在55 ℃较佳反应温度下,先加入与溴氨酸钠质量比为2:5的铜粉,反应一段时间后再加入与溴氨酸钠的质量比为1:5的铜粉,与一次性加入与溴氨酸钠的质量比为3:5的铜粉相比较,综合反应时间可节省2~3 h。 另外,对于DAS中混有的铜盐,采取在制备过程中加入柠檬酸的方法予以去除,此举可提高DAS的纯度。 当铜粉与柠檬酸的质量比为6:1时,可使DAS中铜盐的含量小于0.001%。 此外还探究了蒸馏后滤液的剩余量对DAS收率的影响,结果表明,滤液的剩余量在20 mL时,DAS的收率在95%以上。 基于本文的研究结果提出,欲进一步提高该反应的收率,需要寻找更高效的催化剂。     

A biomass carbon material with microtubule bundling and natural O-doping derived from goldenberry calyx and its electrochemical performance in supercapacitor

A promising biomass carbon material,manufactured by the carbonation of Physalis peruviana L.calyx at 700℃,is presented in this wo rk.Morphology characterization shows that the carbon material possesses long microtubule bundling and above 30%natural O-atom component on the surface.After KOH chemical etching,the materials maintain the oxygen content but exhibit more micropores and higher specific surface area up to 1732.6 m^2/g.Using as an electrode material for supercapacitor,the active carbon material exhibits high specific capacitance up to 339.7 F/g at 0.5 A/g in 3 mol/L KOH aqueous solution through three-electrode system.The active carbon material also exhibits excellent cycling stability(97%retention)by 10,000 cycles at 10 A/g.The outstanding electrochemical performances are attributing to the unique long microtubule bundling with much more pores and the abundant Oelement on the surface.This biomass carbon material with excellent electrochemical properties could be a useful material for multiple applications.     

铜单晶拉伸试样表面滑移带痕迹的晶体塑性分析

采用建立在晶体塑性理论基础上的晶体塑性有限变形计算方法,针对铜单晶试样单轴拉伸过程中晶体滑移在试样表面留下的滑移带痕迹进行了数值研究.作者利用三维有限元模拟不同取向铜单晶试样的拉伸变形,通过晶体塑性滑移面与试样表面交线的几何分析,得到了试样在不同晶向拉伸下不同滑移系启动造成的试样表面滑移痕迹,并对数值计算的试样表面滑移...     

基于J-C本构模型的Comp.B炸药落锤冲击数值模拟

为研究Comp.B炸药在惯性冲击下的力学响应特性, 基于Johnson-Cook本构模型, 对 点火前的Comp.B炸药大落锤(400kg)冲击实验进行了数值模拟. 在不同应力加载条件下模 拟计算得到了用状态方程和不用状态方程的$\sigma$-$t$曲线, 对比应力峰值、应 力上升时间等主要力学参数, 结果表明考虑了状态方程的数值模 拟结果与实验吻合最好, 可以很好地模拟炸药惯性冲击下的力学响应.     

有向图的边割(X,Y)中｜X｜和｜Y｜的下界与有向图的极大性和超级性

在已有的极大边连通、超级边连通、极大局部边连通有向图概念的基础上,提出超级局部边连通有向图的概念,对一般的、二部的、基础图的团数至多为p的有向图、定向图分别给出｜(X,Y)｜＜δ(D)的边割(X,Y)、非平凡的最小边割(X,Y)中｜X｜和｜Y｜的下界,据此分别得到极大边连通、超级边连通有向图的最小度条件.类似地分别得到...     

具线性退化特征场对角型方程组Goursat问题的奇性形成机制

For an inhomogeneous quasilinear hyperbolic system of diagonal form, under the assumptions that the system is linearly degenerate and the C^1 norm of the boundary data is bounded, we show that the mechanism of the formation of singularities of C^1 classical solution to the Goursat problem with C^1 compatibility conditions at the origin must be an ODE type. The similar result is also obtained for the weakly discontinuous solution with C^0 compatibility conditions at the origin.     

基于傅里叶级数展开式的有效期权定价方法

A novel option pricing method based on Fourier-cosine series expansion was proposed by Fang and Oosterlee. Developing their idea, three new option pricing methods based on Fourier, Fourier-cosine and Fourier-sine series expansions are presented in this paper, which are more efficient when the option prices are calculated with many strike prices. A series of numerical experiments under different exp-L~vy models are also given to compare these new methods with the Fang and Oosterlee＇s method and other methods.     

奇异微分方程的广义Sturm--Liouville边值问题正解的存在性

By employing the fixed point theorem of cone expansion and compression of norm type, we investigate the existence of positive solutions of generalized Sturm-Liouville boundary value problems for a nonlinear singular differential equation with a parameter. Some sufficient conditions for the existence of positive solutions are established. In the last section, an example is presented to illustrate the applications of our main results.     

交换环上矩阵代数的局部化导子

Let R be a commutative ring with identity, Nn（R） the matrix algebra consisting of all n × n strictly upper triangular matrices over R. Several types of proper local derivations of Nn（R） （n ≤ 4） are constructed, based on which all local derivations of Nn（R） （n ≤ 4） are characterized when R is a domain.     

涉及微分多项式的亚纯函数分担值问题

This paper is devoted to studying the relationship between meromorphic functions f（z） and g（z） when their differential polynomials satisfy sharing condition weaker than sharing one value IM.