全文获取类型
收费全文 | 1882篇 |
免费 | 308篇 |
国内免费 | 151篇 |
专业分类
化学 | 1294篇 |
晶体学 | 25篇 |
力学 | 137篇 |
综合类 | 12篇 |
数学 | 172篇 |
物理学 | 701篇 |
出版年
2023年 | 33篇 |
2022年 | 42篇 |
2021年 | 65篇 |
2020年 | 70篇 |
2019年 | 54篇 |
2018年 | 70篇 |
2017年 | 66篇 |
2016年 | 92篇 |
2015年 | 109篇 |
2014年 | 116篇 |
2013年 | 151篇 |
2012年 | 183篇 |
2011年 | 196篇 |
2010年 | 112篇 |
2009年 | 123篇 |
2008年 | 125篇 |
2007年 | 120篇 |
2006年 | 100篇 |
2005年 | 75篇 |
2004年 | 40篇 |
2003年 | 33篇 |
2002年 | 34篇 |
2001年 | 31篇 |
2000年 | 34篇 |
1999年 | 30篇 |
1998年 | 24篇 |
1997年 | 24篇 |
1996年 | 32篇 |
1995年 | 15篇 |
1994年 | 18篇 |
1993年 | 12篇 |
1992年 | 7篇 |
1991年 | 15篇 |
1990年 | 24篇 |
1989年 | 16篇 |
1988年 | 11篇 |
1987年 | 11篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1976年 | 2篇 |
1957年 | 1篇 |
1942年 | 1篇 |
1941年 | 1篇 |
1936年 | 4篇 |
1930年 | 2篇 |
1929年 | 1篇 |
1927年 | 1篇 |
1923年 | 1篇 |
排序方式: 共有2341条查询结果,搜索用时 15 毫秒
81.
Xu-Feng Tan Li-Yong Yuan Chang-Ming Nie Kui Lui Zhi-Fang Chai Wei-Qun Shi 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):281-288
Electrochemical behaviors of U(VI) in 1-butyl-3-methylimidazolium chloride (C4MimCl) with various water contents investigated by chronopotentiometry and cyclic voltammetry. The electrochemical reduction of U(VI) was identified to follow two processes: a lower valence intermediate U(V) was initially formed at the potential of ca. ?0.2 V(vs. Ag wire). Then, further deposition of UO2 was followed at around ?0.8 V. Little amount of water (1–4 wt%) in C4MimCl, however, has an effect on the U(VI) reduction by changing the current density of the redox reaction and the diffusion coefficient of U(VI) in C4MimCl. The deposited product by potentiostatic electrolysis on the surface of stainless steel electrode was characterized by the scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) methods. Although the electrodeposited black film was amorphous, the electrochemical reduced product of U(VI) can be still confirmed to be UO2 by XRD after the crystallization of the amorphous deposits at 1,073 K in nitrogen atmosphere. 相似文献
82.
83.
利用溶胶-凝胶法,采用三种酸性金属氧化物(氧化铌、氧化钨和氧化钼)对锰铈复合氧化物催化剂进行了改性. 测试了催化剂的氮氧化物选择性催化还原(SCR)活性,以筛选对应不同温度窗口的合适酸性氧化物改性剂. 同时评价了催化剂的NO氧化和NH3氧化活性. 利用X射线衍射、BET比表面积测试、H2程序升温还原、NH3/NOx程序升温脱附和NH3/NOx吸附红外光谱等手段对催化剂进行了表征. MnOx-CeO2催化剂表现出良好的低温(100-150 ℃)活性. 酸性金属氧化物的添加削弱了催化剂的氧化还原特性,从而抑制了NH3的活化和NO2辅助的快速SCR反应. 与此同时,相对高温(250-350 ℃)区NH3的氧化也受到了抑制,B酸和L酸上的NH3吸附得以增强. 因此,催化剂的SCR脱硝温度窗口向高温移动,改性效果Nb2O5 < WO3 < MoO3. 相似文献
84.
Network polymers in a rubber or a gel often contain non-uniform chain lengths. By means of dynamic Monte Carlo simulations of polymer mixtures with various compositions of two chain lengths, we investigated how the factor of polydispersity influences their strain-induced crystal nucleation. Under a high temperature and a high strain rate, the stretching of both polymers revealed that crystal nucleation is mainly accelerated by the presence of short-chain polymers; nevertheless, both polymers join together in the nucleation process. Further analysis proved that crystal nucleation is initiated from those highly stretched short segments, which are rich on the short-chain polymers. 相似文献
85.
Shijun Wang Linyong Song Pengpeng Chen Yifeng Zhou Wangyan Nie 《Colloid and polymer science》2014,292(10):2465-2473
To investigate the effect of surface functionality on the morphology of polymer/silica composite, poly(styrene-alt-maleic anhydride) (SMA) spheres prepared via precipitation polymerization method was employed. In water/ethanol solution, diethanolamine (DEA) was used to catalyze the hydrolysis reaction of tetraethoxysilane (TEOS), and rambutan-like poly(styrene-alt-maleic anhydride)/silica (SMA/SiO2) microspheres were synthesized through in situ sol–gel process. The obtained structure and morphology were characterized by FTIR, NMR, TEM, SEM, and TGA. The results showed that the hydrolyzed SMA chains on the surface was crucial to the nucleation and growth of silica, and the morphologies of SMA/SiO2 composite microspheres can be controlled by the amount of DEA and the ratio of SMA/TEOS. In addition, the SMA/SiO2 microspheres were used to prepare hierarchical structure of SMA/SiO2/Ag particles, which were utilized for the construction of surface-enhanced Raman scattering substrate (SERS). 相似文献
86.
Nonlinear Dynamics - Hysteresis is an inherent characteristic of piezoelectric materials that can be determined by not only the historical input but also the input signal frequency. Hysteresis... 相似文献
87.
利用中子飞行时间技术和BC501A液体闪烁探测器的粒子分辨特性,测量了0°方向、20 MeV氘束轰击厚金属铍靶反应产生的中子源能谱,测量的中子能谱范围为0.7~25.0 MeV。在60°方向放置芪晶体闪烁探测器,由刻度好的BC501A液体闪烁探测器归一校正后,用于中子源强度监测。利用Be(d, n) 反应中子源,采用单粒子灵敏度标定方法,实验标定了0.75~15.75 MeV能量范围内的薄膜闪烁探测器中子能量响应曲线,实验结果与蒙特卡罗模拟计算结果在8%的不确定度范围内一致。 相似文献
88.
89.
We consider sequences of functions that have in some sense a universal distribution of limit points of zeros in the complex
plane. In particular, we prove that functions having universal approximation properties on compact sets with connected complement
automatically have such a universal distribution of limit points. Moreover, in the case of sequences of derivatives, we show
connections between this kind of universality and some rather old results of Edrei/MacLane and Pólya. Finally, we show the
lineability of the set what we call Jentzsch-universal power series. 相似文献
90.
Yi-you Nie Ming-huang Sang Yuan-hua Li Jun-chang Liu 《International Journal of Theoretical Physics》2011,50(5):1367-1371
We propose a scheme for splitting an arbitrary two-qubit state among three parties by using a six-qubit cluster-class state
as a quantum channel. Based on two Bell-state measurements (BSMs) and a two-qubit projective measurement, any one of the two
agents can reconstruct the original state if he/she collaborates with the other one, whilst individual agent obtains no information. 相似文献