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81.
K.D.G.I. Jayawardena Charles OpokuJames Fryar S. Ravi P. SilvaSimon J. Henley 《Applied Surface Science》2011,257(12):5274-5277
The synthesis of ZnO nanocrystals is reported using a hydrothermal chemical growth technique combined with 248 nm nanosecond excimer laser heating at fluences in the range 0-390 mJ cm−2. The effect of laser heating in controlling the morphology of the nanocrystals is investigated using optical spectroscopy and electron microscopy characterization. Laser heating is shown to allow control of the crystal morphology from nanoparticles to nanorods as well as to modify the size distributions. The results indicate that not only does the laser accelerate the growth of nanocrystals, but can also produce crystals with a narrow size distribution possibly via photothermal size selection. An initial study of electrical conduction properties of ZnO nanocrystal thin films is also discussed. 相似文献
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Anwar Latif M. Khaleeq-ur-RahmanM.S. Rafique K.A. Bhatti 《Physica B: Condensed Matter》2011,406(9):1713-1716
The microstructural morphological changes in laser irradiated targets are investigated. Nd:YAG laser (1064 nm, ∼12 ns nominal, 1.1 MW) is used to irradiate 4 N pure (99.99%) fine polished and annealed silver samples in ambient air and under vacuum ∼10−6 Torr. The laser spot size and power density at tight focus are 12 μm and 3×1011 W/cm2, respectively. SEM micrographs and X-ray diffractograms of the exposed and unexposed targets reveal the surface texture and structural changes, respectively. Amongst the ablation mechanisms involved, exfoliation and hydrodynamic sputtering are found to be dominant. Surface modifications appear in the form of craters and ripples formation. Heat is conducted non-uniformly through narrow channels at the surface. Thermal stresses induced by the laser do not disturb inter planar distance of the target. On the other hand irradiation causes significant variations in grain size and diffracted X-rays intensities. 相似文献
87.
Within the framework of effective-mass approximation, the effects of a laser field on the ground-state donor binding energy in zinc-blende (ZB) GaN/AlGaN quantum well (QW) have been investigated variationally. Numerical results show that the donor binding energy is highly dependent on QW structure parameters and Al composition in ZB GaN/AlGaN QW. The laser field effects are more noticeable on the donor binding energy of an impurity localized inside the QW with small well width and low Al composition. However, for the impurity located in the vicinity of the well edge of the QW, the donor binding energy is insensible to the variation of Al composition, well width and laser field intensity in ZB GaN/AlGaN QW. In particular, the competition effects between laser field and quantum confinement on impurity states have also been investigated in this paper. 相似文献
88.
Ba0.5Sr0.5Ti0.99Co0.01O3 (BSTC) thin films have been fabricated with pulsed laser deposition on Nb-doped SrTiO3 (STN) substrate. In Pt/BSTC/STN capacitor, we systematically investigated the capacitance, leakage current and polarization versus bias voltage characteristics, and found that curves of capacitance versus voltage and leakage current versus voltage were not symmetric, and polarization hysteresis loop exhibited large relaxation of the remnant polarization at negatively poled state. A detailed analysis of capacitance data demonstrated a difference of the built-in voltage between top Pt/BSTC interface (Vb,t=2.5 V) and bottom BSTC/STN interface (Vb,b=1.1 V). Such different built-in voltages lead to the presence of an internal electric field, which results in asymmetric electric characteristics in Pt/BSTC/STN capacitor. 相似文献
89.
SO2气体激光诱导色散荧光时间断层扫描研究 总被引:2,自引:0,他引:2
以纳秒Nd:YAG激光器的四倍频(266 nm)为激发源,利用门选通增强光学多通道光谱分析仪 (OMA),研究了SO2分子第一激发带粒子的荧光辐射与碰撞弛豫相结合的复杂退激发过程。通过对SO2分子第一激发带的激发及碰撞弛豫过程的时间断层扫描分析,可以将激光诱导色散荧光谱中以305.6 nm、337.2 nm为中心的荧光包络和以424.7 nm为中心的规则序列分别归属于B1B1、A1A2低振动能级和a3B1基振动能级到基电子态X1A1不同振动能级的荧光跃迁,由此可以确定大气污染气体SO2的诱导荧光的灵敏检测波长为425 nm;由规则序列的实验数据可以计算出SO2分子基电子态X1A1的对称振动和弯曲振动模式的基振动角频率分别为ω1= 1151.8±0.6 cm-1和ω2= 517.8±0.6 cm-1,两振动模式的非谐性常数分别为 = 8±0.6 cm-1和 = 9.2±0.6 cm-1。 相似文献
90.
利用泵浦-检测方法,在样品池条件下,研究了Cs(6D5/2)与H2反应碰撞传能过程。利用激光感应荧光(LIF)光谱技术,确定了CsH[X1Σ+(v,J)]振转能级上的布居分布,转动态分布与热统计分布基本一致.Cs激发态原子密度由激光能量吸收得到.记录A1Σ+(v',J+1)→X1Σ+(v,J)的时间分辨荧光,从荧光强度的对数值给出的直线斜率确定(v',J+1)→(v,J)的自然辐射率,结合(v,J)→(v',J+1)吸收系数的测量,得到反应生成物CsH[X1Σ+(v,J)]态的分子密度.由速率方程分析,给出反应截面(v,J),对J求和,得到(v)[10-16cm2单位]分别为(0.64±0.19)(v=0)和(0.58±0.17)(v=1). 相似文献