LED用荧光粉Sr(S_(1-x)Se_x)∶Eu~(2 )的合成和光谱性质研究

采用高温固相法合成了Sr(S1-xSex)系列硫属化合物掺Eu2 荧光粉。XRD表明荧光粉的组成为单相,而且体系Sr(S1-xSex)∶0.005Eu2 中晶胞参数随着组成的变化呈现良好的线性关系,遵守韦加定律。漫反射光谱与激发光谱吻合,说明荧光粉吸收的能量能够有效地激发发光中心而发光,激发光谱中较低能量区域覆盖了400~500nm的光谱范围,与蓝光LED芯片的发射光匹配。发射光谱呈现的是Eu2 离子的5d→4f特征跃迁发射带,当x由0增加到1.0的过程中,发射峰值波长由617nm逐渐蓝移到571nm。不同基质中掺杂的Eu2 离子的荧光寿命均为微秒数量级,与Eu2 离子的4f65d1→4f7跃迁相符合。将荧光粉封装在发蓝色光(λ=460nm)的GaN芯片上制作了LED器件,测量了器件的发光强度、色纯度和色坐标等参数。Sr(S1-xSex)∶Eu2 系列硫属化合物掺铕荧光粉能够有效地被GaN芯片发出的蓝色光激发,发出从橙色到红色的可见光,是一类较好的LED用荧光粉。     

石墨炉原子吸收法直接测定啤酒中铝

采用高速枪弹射击猪单后肢软组织，观察伤后远离原发伤道的血管内皮细胞的形态学变化，为远达效应的血流扰动学说提供实验资料。动物伤后６ｈ解剖，大体见双肺下叶、左室后壁以及大脑的痛、腹侧面均有不同程度的血管破裂、出血，或毛细血管充血。光镜见猪主动脉弓内皮细胞有水肿，或脱落呈“鞋钵样”垂直悬吊在血管腔内；连续切片见内皮层有剥脱现象。     

气相色谱法测定柑桔中甲基托布津残留量

本文根据甲基托布津在一定温度下,分解放出含硫化合物的特点,建立了用气相色谱法直接测定甲基托布津残留量的方法。用丙酮提取样品,二氯甲烷液液分配净化,用带FPD气相色谱仪检测。在5～30ng范围内呈良好的线性关系。方法最低检测浓度为0.02ppm,回收率为87.3～98.2%,变异系数为2.0%。     

Electrochemically modified piezoelectric crystal biosensor for detection of Staphylococcus aureus

Electropolymerized o-phenylenediamine film is used as a functional coating for the immobilization of anti-S. aureus antibody on the surface of a gold-plated piezoelectric crystal, and this piezoelectric immunosensor is applied to detect S. aureus. The frequency shift (F = F20s - F380s, Hz) between the frequency at the 20th second (after the addition of sample, F20s) and that at 380 seconds later (F380s) was introduced to construct a calibration graph, and shortening of assay time was achieved. The S. aureus concentrations in the range of 105-109 cells/mL can be detected by this system.     

两种自适应光学系统中哈特曼波前传感器与变形镜的对准误差

利用直接波前斜率法和变形镜的电压一面形响应特性，研究了常规自适应光学系统和共光路／共模块(CP／CM)自适应光学系统中哈特曼波前传感器与变形镜的对准误差。常规自适应光学系统中，可以用重新测量变形镜的影响函数以减小对准误差的影响，虽并不能消除其影响，但系统都会有很大的调整容差；共光路／共模块自适应光学系统中采用不同的双哈特曼数据处理方法，哈特曼波前传感器与变形镜的对准精度对系统校正能力影响是不同的，采用加修正因子斜率融合法和电压融合法由于在数据融合时考虑了两台哈特曼传感器与变形镜对准的差异，所以对准误差的影响与在常规自适应光学中相同，系统都会有很大的调整容差，而采用直接斜率融合法的共光路／共模块系统由于是建立在两台哈特曼传感器完全一致的假设基础上，所以对对准精度的要求是很高的。分析过程中给出了相应的数值计算结果。     

Numerical simulation of combustion stability of liquid rocket engine based on chemistry dynamics

Combustion instability of O2/kerosene, O2/kerosene/hydrogen, and O2/kerosene/hydro-gen spray flame is numerically studied. The numerical results of combustion self-oscillation are consistent with the historical experiments. Hydrogen is helpful to stabilizing oxygen/hydrocarbon combustion. High gas injecting velocity of the coaxial injector would increase the combustion stability. Contrary to the former expectation, the most sensitive region for combustion instability is not where the heat releases most intensely but is the low-temperature premixed region near the injectors. According to the simulation, the technology steps, such as adding catalyzer to decrease the reaction activity energy, or improving the injector design to reduce the premixed low temperature region, would improve the combustion stability.     

Novel Role of Carbon Dioxide as a Selective Agent in Palladium-Catalyzed Cyclotrimerization of Alkynes

Carbon dioxide was found as a selective agent to promote the palladium-catalyzed cyclotrimerization of alkynes in water. Both aryl and alkylacetylenes afforded the corresponding cyclotrimerization products regioselectively in high yields using PdCl2, CuCl2, and CO2 as the catalytic system. However, tert-butylacetylene bearing a bulky group gave a dimerization product. Mechanism of this reaction was also discussed.     

氧化叔胺树脂的合成及其对苯酚的吸附性能研究

将D301树脂的叔胺基氧化，合成了大孔交联氧化叔胺树脂．比较D301树脂与氧化叔胺树脂对正己烷溶液中和水溶液苯酚的吸附性能，发现氧化叔胺树脂对苯酚的吸附量比D301树脂的有明显的增加．为弄清吸附量增加的原因，根据氧化叔胺树脂对正己烷溶液中苯酚的吸附等温线，利用热力学函数关系计算了等量吸附焓、吸附Gibbs自由能和吸附熵，发现叔胺树脂氧化后，与苯酚的相互作用和吸附的自发倾向增强，但吸附过程仍为氢键吸附．     

CENTRAL LIMIT THEOREMS FOR A BRANCHING RANDOM WALK WITH A RANDOM ENVIRONMENT IN TIME

We consider a branching random walk with a random environment in time, in which the offspring distribution of a particle of generation n and the distribution of the displacements of its children depend on an environment indexed by the time n. The environment is supposed to be independent and identically distributed. For AR, let Zn(A) be the number of particles of generation n located in A. We show central limit theorems for the counting measure Zn(·) with appropriate normalization.     

Amplified spontaneous emission and power amplification in high-power DF laser systems

Amplified spontaneous emission （ASE） always occurs in high-power DF laser systems with master oscillator-power amplifier （MOPA） configuration. ASE not only reduces the energy extraction efficiency of the laser system, but also negatively influences its heat management. The interaction between the ASE flux and the coherent laser flux, as well as the effect of ASE on cuboid DF amplifiers, is studied using a finite difference method and an iterative arithmetic. In addition, the influence of ASE on coherent laser amplification is discussed in detail.