对-三氰基乙烯基-N,N-二烷基苯胺的分子内光致电荷分离

本文以对-三氰基乙烯基-N,N-二烷基苯胺为模型化合物,开展共轭π电子体系分子内光致电子转移及电荷分离的研究。通过吸收光谱和荧光光谱探讨了这类分子的电荷分离作用以及在DMSO-H_2O中的簇集作用。     

A PICARD TYPE THEOREM AND BLOCH LAW

Ａ ＰＩＣＡＲＤ ＴＹＰＥ ＴＨＥＯＲＥＭ ＡＮＤ ＢＬＯＣＨ ＬＡＷ ￥ＹＥＹＡＳＨＥＮＧＡｂｓｔｒａｃｔ：Ａｐｉｃａｒｄｔｙｐｅｔｈｅｏｒｅｍｉｓｐｒｏｖｅｄ，ａｎｄａｃｏｕｎｔｅｒｅｘａｍｐｌｅｉｓｇｉｖｅｎｔｏｓｈｏｗｔｈａｔｔｈｅＢｏｌｃｈ...     

钴（Ⅱ）—丁二酮单肟烟酰腙—亚硝酸盐体系的伏安行为及其应用

在氨性介质中(pH=9.0),钴(Ⅱ)-丁二酮单肟烟酰腙(DMNH)-亚硝酸盐体系可产生灵敏度很高的催化波。从体系的伏安行为可知,吸附于汞电极上的是混配的配盐NH_4[Co(Ⅱ)(DMNH)·(NO_2)_2],在-1.0 V(相对SCE)处,Co(Ⅱ)被还原至Co(0),DMNH被还原成自由基,由于NO_2~-的存在,自由基可参与再生反应而形成催化波。羟氨的存在可使产生催化波的最佳pH值移至8.2.用此体系进行了生物样品中钴的测定,其检出限为1×10~(-10)mol/L。     

Nonlinear Dynamics Approach to the Correlation Analysis of Protein Sequences

To clarify the randomness of protein sequences,we make a detailed analysis of a set of typical protein sequences representing each fold by using the nonlinear prediction method developed in nonlinear dynamics theory.No deterministic structures are found in these protein sequences and this implies that they behave as random chains.We also explain the controversial results obtained in previous investigations.     

R~(2,1)中线性Weingarten曲面的Bcklund变换(英文)

本文对三维Minkowski空间R~(2,1)中具有性质K-2mH+m~2-l~2=0或H=constant的类时曲面定义了一个Darboux线汇,同时得到了相应的Bcklund变换。     

Two New Ionone Derivatives from Rhododendron przewalskii Maxim

Two new ionone derivatives,named rhododendrone and rhododendronside,were isolated from the alcohoilc extract of the aerial parts of Rhododendron przwalskii Maxim.Their structures were elucidated on the basis of spectroscopic analysis.