3,3—二甲基环己基甲基酮的合成

研究1-(3,3-二甲基环己基)乙醇(3)在铜系催化剂作用下进行液相脱氢反应生成3,3-二甲基环己基甲基酮(4)。在适宜的条件下,催化剂与(3)的重量比为1～2:100;反应温度170～180℃;反应时间20～25小时。(3)的转化率达97%,(4)的选择性为100%。     

电毛细管曲线的全自动测绘

本文在JP-1A型示波极谱仪与苹果Ⅱ微型计算机联用的基础上,开发了自动测绘电毛细管曲线的功能。     

由自共轭线性微分算子所确定的函数类在Lq(T)中的相对宽度

得到了使等式Kn(K2(Pr),MK2(Pr),L2(T))=dn(K2(Pr),L2(T))成立的最小M值,并计算了Kn(K2(Pr),K2(Pr),Lq(T))的渐近阶,其中Kn(.,.,Lq(T))和dn(.,Lq(T)),1≤q≤∞,分别代表Kolmogorov意义下在Lq(T)中的相对宽度和宽度,K2(Pr)表示定义在[-π,π]上由自共轭线性微分算子所确定的光滑函数类.     

第二代H1抗组胺类药物——依巴斯汀

概述了近年来国内外依巴斯汀的研究及生产状况,对其合成路线进行了较深入的介绍,同时展望了依巴斯汀在医药领域的发展前景.     

关于Orlicz空间的-乘积问题

§1 引言与反例 王声望教授在中详细讨论了两个Orlicz空间的⊙-乘积问题。他在该文最后写道,对于-乘积问题“本文§1到§3的全部结论都是正确的,甚至在定理的叙述与证明的方法上都基本相同。”文§1的四个定理已总结在吴从炘,王廷辅的最新专著第三章§3.2中。我们将这四个定理逐一移植到-乘积问题时,发现只有前三个定理是可以按的说明移植的,即以下三个命题正确:     

~(128)Ba激发态的观测

通过反应~(120)Sn(~(12)C,4nγ)~(128)Ba,用在束γ测量方法研究了~(128)Be的激发态。从935.0keVγ射线确认了第二个12~ 态,但它仍不属于基态带。另外还新观测到224.8keV和632.7 keV的带间跃迁,并确认它们是由负宇称带向基态带的跃迁。     

氧化镁担载的[PPN]_2[Ru_3(CO)_9CCO]作为C_2含氧化合物模型的表面金属有机化学的研究

用原位红外光谱法研究了负载于MgO表面上的〔PPN〕_2〔Ru_3(CO)_9CCO〕簇合物。发现表面物类同MgO的抽空脱水温度有很大关系。在573K以下脱水的氧化镁上〔PPN〕_2〔Ru_3-(CO)_9CCO〕吸附后,其v_(?)=o的红外谱基本保持乙烯酮钌簇合物的原来特征,〔Ru_3(CO)_9-CCO〕~(2-)离子和表面的电荷相互作用只引起线式和桥式CO谱带的轻微位移。抽空脱水温度超过613K时,除了〔Ru_3(CO)_9CCO〕~(2-)的特征光谱外,还出现2068,2030和1999cm~(-1)新谱带,归因于Mg-OH同〔Ru_3(CO)_9CCO〕~(2-)反应部分地形成〔HRu_3(CO)_9CCO〕~-.TPD-IR研究揭示了〔Ru_3(CO)_9CCO〕~(2-)/MgO的热稳定性远大于〔PPN〕_2〔Ru_3(CO)_9CCO〕固体。在CO气氛下,〔Ru_3(CO)_9CCO〕~(2-)同CH_3I很易反应,v_(?)=o谱带的变化说明反应后有乙酰基生成,v_(?)=o谱带出现在1635cm~(-1)。这种含乙酰基的三钌化合物〔Ru_3(CO)_9CC(O)CH_3〕~-对CO+H_2合成C_2含氧物的机理研究,可能有模型化合物的意义。     

Prototype studies on the forward MWDC tracking array of the external target experiment at HIRFL-CSR

A prototype of the forward tracking array consisting of three multiwire drift chambers (MWDC) for the external target experiment (CEE) at the Heavy Ion Research Facility at the Lanzhou -Cooling Storage Ring (HIRFL-CSR) has been assembled and tested using cosmic rays. The signals from the anode wires are amplified and fed to a Flash-ADC to deliver the drift time and charge integration. The performances of the array prototype are investigated under various high voltages. For the tracking performances, after the space-time relation (STR) calibration and the detector displacement correction, the standard deviation of 223 μm of the residue is obtained. The performances of the forward MWDCs tracking array meets the requirements of CEE in design.     

Unique Charge Storage Characteristics of FEP//THV//FEP Sandwich Electret Membrane Polarized by Thermally Charging Technology

Nowadays, electrets have been widely applied in acoustic electric sensors such as microphones and other actuators due to its lasting and stable electrostatic field. Recently, research has focus on the application of micro-electro-mechanical systems （MEMS）, especially on electret generator for energy harvesting,where vibration energy can be changed into electrical energy by relative displacement between two electret layers when vibrating. Many kinds of configurations for the electret generator have been proposed, in which the theoretical power output is proportional to the surface charge density of the electret. Therefore, it is crucial to develop a new novel electret with an extremely high surface charge density and long-term stability for electret generators with large power output.